石墨烯增强铜基复合材料制备工艺及性能的研究进展
Research Progress on Preparation Process and Properties of Graphene Reinforced Copper Matrix Composites
摘 要
作为常用的金属材料，铜因强度较低而应用范围受限，石墨烯具有优异的综合性能，作为极具潜力的增强体而受到广泛关注。石墨烯增强铜基复合材料兼具了铜和石墨烯的优良性能而成为了重要的研究对象。介绍了石墨烯增强铜基复合材料的制备工艺与综合性能，重点讨论了各种制备工艺的特点、强化机制、构型设计，总结了针对复合界面结合弱与石墨烯分散困难这2类主要技术难点的解决途径，最后对石墨烯增强铜基复合材料的制备工艺进行了展望。
制备工艺
构型设计
强化机制
graphene reinforced copper matrix composite
preparation process
configuration design
strengthening mechanism
Abstract
As a commonly used metal material, copper is limited in its application due to its low strength. Because of its excellent comprehensive properties, graphene has attracted wide attention as a potential reinforcement. Graphene reinforced copper matrix composites combine the great properties of both copper and graphene, and have become an research hotspot. The preparation processes and comprehensive properties of graphene reinforced copper matrix composites are introduced. The characteristics of various preparation processes, strengthening mechanism and configuration design are emphatically discussed, and the improvement approaches to solve the two main technical difficulties of weak bonding of composite interface and difficult dispersion of graphene are summarized. Finally, the preparation process of graphene reinforced copper matrix composites is prospected.
中图分类号 TB333 DOI 10.11973/jxgccl202301001
所属栏目 综述
基金项目 福建省自然科学基金资助项目（2020J01454）；福州大学贵重仪器设备开放测试基金资助项目（2020T18）
收稿日期 2021/9/20
修改稿日期 2022/11/9
网络出版日期
作者单位点击查看
备注潘信诚(1996-),男,福建闽侯人,硕士研究生
引用该论文: PAN Xincheng,LIN Zhengqi,YANG Liu,DENG Liping. Research Progress on Preparation Process and Properties of Graphene Reinforced Copper Matrix Composites[J]. Materials for mechancial engineering, 2023, 47(1): 1～10
潘信诚,林政淇,杨柳,邓丽萍. 石墨烯增强铜基复合材料制备工艺及性能的研究进展[J]. 机械工程材料, 2023, 47(1): 1～10
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【12】YANG Z Y, WANG L D, SHI Z D, et al.Preparation mechanism of hierarchical layered structure of graphene/copper composite with ultrahigh tensile strength[J].Carbon, 2018, 127:329-339.
【13】WANG S Y, HAN S B, XIN G Q, et al.High-quality graphene directly grown on Cu nanoparticles for Cu-graphene nanocomposites[J].Materials & Design, 2018, 139:181-187.
【14】LI X H, YAN S J, CHEN X, et al.Microstructure and mechanical properties of graphene-reinforced copper matrix composites prepared by in situ CVD, ball-milling, and spark plasma sintering[J].Journal of Alloys and Compounds, 2020, 834:155182.
【15】ZHAO X Y, TANG J C, YU F X, et al.Preparation of graphene nanoplatelets reinforcing copper matrix composites by electrochemical deposition[J].Journal of Alloys and Compounds, 2018, 766:266-273.
【16】SONG G S, WANG Q, SUN L, et al.One-step synthesis of sandwich-type Cu/graphene/Cu ultrathin foil with enhanced property via electrochemical route[J].Materials & Design, 2020, 191:108629.
【17】ZHANG X, WAN D Q, PENG K, et al.Enhancement of thermal conductivity and mechanical properties of Cu-reduced graphene oxide composites by interface modification[J].Journal of Materials Engineering and Performance, 2019, 28(8):5165-5171.
【18】SHAO G S, LIU P, ZHANG K, et al.Mechanical properties of graphene nanoplates reinforced copper matrix composites prepared by electrostatic self-assembly and spark plasma sintering[J].Materials Science and Engineering:A, 2019, 739:329-334.
【19】CHEN F, MEI Q S, LI J Y, et al.Fabrication of graphene/copper nanocomposites via in situ delamination of graphite in copper by accumulative roll-compositing[J].Composites Part B:Engineering, 2021, 216:108850.
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【25】管振宏, 于镇洋, 乔志军, 等.化学气相沉积法制备原位生长三维石墨烯/铜基复合材料[J] .材料科学与工程学报, 2021, 39(4):575-579. GUAN Z H, YU Z Y, QIAO Z J, et al.Preparation of in-situ growth three-dimensional Cu@graphene composite by chemical vapor deposition[J].Journal of Materials Science & Engineering, 2021, 39(4):575-579.
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【27】KIM Y, LEE J, YEOM M S, et al.Strengthening effect of single-atomic-layer graphene in metal-graphene nanolayered composites[J].Nature Communications, 2013, 4:2114.
【28】ZHANG D D, XIAO H X, JIANG W, et al.Effect of graphene lateral size on the microstructure and properties of graphene/copper composites[J].International Journal of Modern Physics B, 2020, 34:2040045.
【29】LI Z, FU X D, GUO Q, et al.Graphene quality dominated interface deformation behavior of graphene-metal composite:The defective is better[J].International Journal of Plasticity, 2018, 111:253-265.
【30】CAO M, XIONG D B, TAN Z Q, et al.Aligning graphene in bulk copper:Nacre-inspired nanolaminated architecture coupled with in situ processing for enhanced mechanical properties and high electrical conductivity[J].Carbon, 2017, 117:65-74.
【31】ZHANG X, SHI C S, LIU E Z, et al.Achieving high strength and high ductility in metal matrix composites reinforced with a discontinuous three-dimensional graphene-like network[J].Nanoscale, 2017, 9(33):11929-11938.
【32】WANG J, GUO L N, LIN W M, et al.The effects of graphene content on the corrosion resistance, and electrical, thermal and mechanical properties of graphene/copper composites[J].New Carbon Materials, 2019, 34(2):161-169.
【33】TANG Y X, YANG X M, WANG R R, et al.Enhancement of the mechanical properties of graphene-copper composites with graphene-nickel hybrids[J].Materials Science and Engineering:A, 2014, 599:247-254.
【34】YOO S C, LEE J, HONG S H.Synergistic outstanding strengthening behavior of graphene/copper nanocomposites[J].Composites Part B:Engineering, 2019, 176:107235.
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