Effect of Homogenization Annealing on Microstructure andMechanical Properties of Mg-4Zn-4Y Alloy
摘 要
对铸态Mg-4Zn-4Y合金进行了不同温度(440,460,480℃)和不同保温时间(4~24 h)下的均匀化退火,研究了均匀化退火对合金组织及性能的影响。结果表明:铸态合金中存在α-Mg相、W相Mg3Zn3Y2、LPSO相Mg12ZnY和富钇相;随着退火温度的升高,大部分LPSO相逐渐溶入基体;随着退火保温时间的延长及退火温度的升高,富钇相含量减少,枝晶偏析得到改善;与铸态合金相比,440,460℃均匀化退火后合金的抗拉强度略微降低,断后伸长率变化较小,480℃均匀化退火后抗拉强度和断后伸长率较高,但出现烧损现象。该合金的最佳均匀化退火制度为440℃×12 h。
Abstract
As-cast Mg-4Zn-4Y alloy was treated by homogenization annealing at different temperatures (440,460,480℃) for different holding times (4-24 h), and the effects of homogenization annealing on the microstructure and properties of the alloy were studied. The results show that there were α-Mg phase, W phase Mg3Zn3Y2, LPSO phase Mg12ZnY and yttrium-rich phase in the as-cast alloy. With increasing annealing temperature, most of the LPSO phase gradually dissolved into the matrix. With increasing annealing temperature and holding time, the content of yttrium-rich phase decreased, and the dendrite segregation was reduced. Compared with the as-cast alloy, the tensile strength of the alloy after homogenization annealing at 440℃ and 460℃ decreased slightly, and the percentage elongation after fracture changed slightly. The tensile strength and percentage elongation after fracture after homogenization annealing at 480℃ were relatively high, but the burning loss occurred. The best homogenization annealing of the alloy was 440℃×12 h.
中图分类号 TG166.4 DOI 10.11973/jxgccl202301004
所属栏目 试验研究
基金项目 国家自然科学基金资助项目(51864006);广西高等学校高水平创新团队资助项目(桂教师范[2019]52号);广西自然科学基金资助项目(2018GXNSFBA281195);广西科技大学研究生教育创新计划项目(GKYC202110)
收稿日期 2021/5/27
修改稿日期 2022/6/8
网络出版日期
作者单位点击查看
备注翟传田(1995-),男,山东临沂人,硕士研究生
引用该论文: ZHAI Chuantian,SUN Youping,LI Wangzhen,HE Jiangmei,WAN Siyu. Effect of Homogenization Annealing on Microstructure andMechanical Properties of Mg-4Zn-4Y Alloy[J]. Materials for mechancial engineering, 2023, 47(1): 26~33
翟传田,孙有平,李旺珍,何江美,万斯雨. 均匀化退火对Mg-4Zn-4Y合金显微组织和力学性能的影响[J]. 机械工程材料, 2023, 47(1): 26~33
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】刘庆.镁合金塑性变形机理研究进展[J].金属学报, 2010, 46(11):1458-1472. LIU Q.Research progress on plastic deformation mechanism of Mg alloys[J].Acta Metallurgica Sinica, 2010, 46(11):1458-1472.
【2】金军兵, 王智祥, 刘雪峰, 等.均匀化处理对AZ91镁合金组织和力学性能的影响[J].金属学报, 2006, 42(10):1014-1018. JIN J B, WANG Z X, LIU X F, et al.Effect of homogenizing treatment on microstructures and mechanical properties of AZ91 magnesium alloy[J].Acta Metallurgica Sinica, 2006, 42(10):1014-1018.
【3】黎业生, 董定乾, 吴子平.稀土镁合金的研究现状及应用前景[J].轻合金加工技术, 2006, 34(4):1-6. LI Y S, DONG D Q, WU Z P.Research status and application prospects of rare earth in magnesium alloys[J].Light Alloy Fabrication Technology, 2006, 34(4):1-6.
【4】孙营, 池成忠, 李黎忱, 等.各向异性ZK60镁合金板材拉深成形过程中凸耳行为研究[J].塑性工程学报, 2017, 24(1):85-91. SUN Y, CHI C Z, LI L C, et al.Effect of anisotropic of ZK60 magnesium alloy sheet on its earing behavior during deep drawing process[J].Journal of Plasticity Engineering, 2017, 24(1):85-91.
【5】KAWAMURA Y, HAYASHI K, INOUE A, et al.Rapidly solidified powder metallurgy Mg97Zn1Y2 alloys with excellent tensile yield strength above 600 MPa[J]. Materials Transactions, 2001, 42(7):1172-1176.
【6】徐志超.Mg-Zn-Y合金组织与电磁屏蔽性能研究[D].昆明:昆明理工大学, 2018. XU Z C.Study on microstructure and electromagnetic shielding Properties of Mg-Zn-Y Alloy[D].Kunming:Kunming University of Science and Technology, 2018.
【7】LI C Q, XU D K, ZENG Z R, et al.Effect of volume fraction of LPSO phases on corrosion and mechanical properties of Mg-Zn-Y alloys[J].Materials & Design, 2017, 121:430-441.
【8】XU D K, LIU L, XU Y B, et al.The influence of element Y on the mechanical properties of the as-extruded Mg-Zn-Y-Zr alloys[J].Journal of Alloys and Compounds, 2006, 426(1/2):155-161.
【9】史菲.Mg-Zn-Y(-Gd)镁合金凝固组织与性能的研究[D].哈尔滨:哈尔滨工业大学, 2015. SHI F.Research on microstructures and properties of Mg-Zn-Y (-Gd) alloys[D].Harbin:Harbin Institute of Technology, 2015.
【10】鲁若鹏.Mg-Zn-Y合金中LPSO相的调控及其对阻尼和力学性能的影响机制研究[D].重庆:重庆大学, 2015. LU R P.Microstructure evolution of LPSO phase and the corresponding damping capacities and mechanical properties in Mg-Zn-Y alloys[D].Chongqing:Chongqing University, 2015.
【11】陈先华, 刘娟, 张志华, 等.镁合金热处理的研究现状及发展趋势[J].材料导报, 2011, 25(23):142-145. CHEN X H, LIU J, ZHANG Z H, et al.Research status and development trend of heating treatment for magnesium alloy[J].Materials Review, 2011, 25(23):142-145.
【12】吕滨江, 彭建, 韩韡, 等.水冷对普通铸造Mg-Zn-Zr-Y镁合金准晶相形成的影响及铸态组织研究[J].稀有金属材料与工程, 2014, 43(7):1643-1648. LÜ B J, PENG J, HAN W, et al.Effects of water-cooling on quasicrystal formation of as-cast Mg-Zn-Zr-Y alloys and the microstructure[J].Rare Metal Materials and Engineering, 2014, 43(7):1643-1648.
【13】冯娟妮, 郭学锋, 徐春杰, 等.Mg-Zn-Y系合金的铸态组织及其相变点[J].中国稀土学报, 2006, 24(1):86-90. FENG J N, GUO X F, XU C J, et al.Microstructures and phase transition points of as-cast Mg-Zn-Y system alloys[J].Journal of the Chinese Rare Earth Society, 2006, 24(1):86-90.
【14】LUO S Q, TANG A T, PAN F S, et al.Effect of mole ratio of Y to Zn on phase constituent of Mg-Zn-Zr-Y alloys[J].Transactions of Nonferrous Metals Society of China, 2011, 21(4):795-800.
【15】张红菊, 张丁非, 潘复生.稀土Y对Mg-6Zn-1Mn合金显微组织和力学性能的影响[J].功能材料, 2016, 47(12):12014-12018. ZHANG H J, ZHANG D F, PAN F S.Effect of Y addition on the microstructure and mechanical properties of Mg-6Zn-1Mn magnesium alloy[J].Journal of Functional Materials, 2016, 47(12):12014-12018.
【16】孙有平, 周学浩, 何江美, 等.Mg-4Sn-1Zn生物镁合金均匀化处理制度研究[J].特种铸造及有色合金, 2016, 36(11):1126-1128. SUN Y P, ZHOU X H, HE J M, et al.Homogenization treatment of Mg-4Sn-1Zn bio-magnesium alloy[J].Special Casting & Nonferrous Alloys, 2016, 36(11):1126-1128.
【17】袁家伟, 李婷, 李兴刚, 等.Mg-xZn-1Mn镁合金均匀化热处理及扩散动力学研究[J].稀有金属, 2012, 36(3):373-379. YUAN J W, LI T, LI X G, et al.Homogenizing heat treatment and diffusion kinetics of Mg-xZn-1Mn magnesium alloy[J].Chinese Journal of Rare Metals, 2012, 36(3):373-379.
【18】欧阳杰, 李慧中, 姜俊, 等.AZ80A镁合金的均匀化处理及扩散动力学[J].粉末冶金材料科学与工程, 2014, 19(1):8-14. OUYANG J, LI H Z, JIANG J, et al.Homogenizing treatment and diffusion kinetics of AZ80A magnesium alloy[J].Materials Science and Engineering of Powder Metallurgy, 2014, 19(1):8-14.
【19】张诗昌, 段汉桥, 蔡启舟, 等.主要合金元素对镁合金组织和性能的影响[J].铸造, 2001, 50(6):310-315. ZHANG S C, DUAN H Q, CAI Q Z, et al.Effects of the main alloying elements on microstructure and properties of magnesium alloys[J].Foundry, 2001, 50(6):310-315.
【20】XU D K, TANG W N, LIU L, et al.Effect of W-phase on the mechanical properties of as-cast Mg-Zn-Y-Zr alloys[J].Journal of Alloys and Compounds, 2008, 461(1/2):248-252.
【21】LU R P, WANG J F, CHEN Y L, et al.Effects of heat treatment on the morphology of long-period stacking ordered phase, the corresponding damping capacities and mechanical properties of Mg-Zn-Y alloys[J].Journal of Alloys and Compounds, 2015, 639:541-546.
【22】CHENG P, ZHAO Y H, LU R P, et al.Effect of Ti addition on the microstructure and mechanical properties of cast Mg-Gd-Y-Zn alloys[J].Materials Science and Engineering:A, 2017, 708:482-491.
【2】金军兵, 王智祥, 刘雪峰, 等.均匀化处理对AZ91镁合金组织和力学性能的影响[J].金属学报, 2006, 42(10):1014-1018. JIN J B, WANG Z X, LIU X F, et al.Effect of homogenizing treatment on microstructures and mechanical properties of AZ91 magnesium alloy[J].Acta Metallurgica Sinica, 2006, 42(10):1014-1018.
【3】黎业生, 董定乾, 吴子平.稀土镁合金的研究现状及应用前景[J].轻合金加工技术, 2006, 34(4):1-6. LI Y S, DONG D Q, WU Z P.Research status and application prospects of rare earth in magnesium alloys[J].Light Alloy Fabrication Technology, 2006, 34(4):1-6.
【4】孙营, 池成忠, 李黎忱, 等.各向异性ZK60镁合金板材拉深成形过程中凸耳行为研究[J].塑性工程学报, 2017, 24(1):85-91. SUN Y, CHI C Z, LI L C, et al.Effect of anisotropic of ZK60 magnesium alloy sheet on its earing behavior during deep drawing process[J].Journal of Plasticity Engineering, 2017, 24(1):85-91.
【5】KAWAMURA Y, HAYASHI K, INOUE A, et al.Rapidly solidified powder metallurgy Mg97Zn1Y2 alloys with excellent tensile yield strength above 600 MPa[J]. Materials Transactions, 2001, 42(7):1172-1176.
【6】徐志超.Mg-Zn-Y合金组织与电磁屏蔽性能研究[D].昆明:昆明理工大学, 2018. XU Z C.Study on microstructure and electromagnetic shielding Properties of Mg-Zn-Y Alloy[D].Kunming:Kunming University of Science and Technology, 2018.
【7】LI C Q, XU D K, ZENG Z R, et al.Effect of volume fraction of LPSO phases on corrosion and mechanical properties of Mg-Zn-Y alloys[J].Materials & Design, 2017, 121:430-441.
【8】XU D K, LIU L, XU Y B, et al.The influence of element Y on the mechanical properties of the as-extruded Mg-Zn-Y-Zr alloys[J].Journal of Alloys and Compounds, 2006, 426(1/2):155-161.
【9】史菲.Mg-Zn-Y(-Gd)镁合金凝固组织与性能的研究[D].哈尔滨:哈尔滨工业大学, 2015. SHI F.Research on microstructures and properties of Mg-Zn-Y (-Gd) alloys[D].Harbin:Harbin Institute of Technology, 2015.
【10】鲁若鹏.Mg-Zn-Y合金中LPSO相的调控及其对阻尼和力学性能的影响机制研究[D].重庆:重庆大学, 2015. LU R P.Microstructure evolution of LPSO phase and the corresponding damping capacities and mechanical properties in Mg-Zn-Y alloys[D].Chongqing:Chongqing University, 2015.
【11】陈先华, 刘娟, 张志华, 等.镁合金热处理的研究现状及发展趋势[J].材料导报, 2011, 25(23):142-145. CHEN X H, LIU J, ZHANG Z H, et al.Research status and development trend of heating treatment for magnesium alloy[J].Materials Review, 2011, 25(23):142-145.
【12】吕滨江, 彭建, 韩韡, 等.水冷对普通铸造Mg-Zn-Zr-Y镁合金准晶相形成的影响及铸态组织研究[J].稀有金属材料与工程, 2014, 43(7):1643-1648. LÜ B J, PENG J, HAN W, et al.Effects of water-cooling on quasicrystal formation of as-cast Mg-Zn-Zr-Y alloys and the microstructure[J].Rare Metal Materials and Engineering, 2014, 43(7):1643-1648.
【13】冯娟妮, 郭学锋, 徐春杰, 等.Mg-Zn-Y系合金的铸态组织及其相变点[J].中国稀土学报, 2006, 24(1):86-90. FENG J N, GUO X F, XU C J, et al.Microstructures and phase transition points of as-cast Mg-Zn-Y system alloys[J].Journal of the Chinese Rare Earth Society, 2006, 24(1):86-90.
【14】LUO S Q, TANG A T, PAN F S, et al.Effect of mole ratio of Y to Zn on phase constituent of Mg-Zn-Zr-Y alloys[J].Transactions of Nonferrous Metals Society of China, 2011, 21(4):795-800.
【15】张红菊, 张丁非, 潘复生.稀土Y对Mg-6Zn-1Mn合金显微组织和力学性能的影响[J].功能材料, 2016, 47(12):12014-12018. ZHANG H J, ZHANG D F, PAN F S.Effect of Y addition on the microstructure and mechanical properties of Mg-6Zn-1Mn magnesium alloy[J].Journal of Functional Materials, 2016, 47(12):12014-12018.
【16】孙有平, 周学浩, 何江美, 等.Mg-4Sn-1Zn生物镁合金均匀化处理制度研究[J].特种铸造及有色合金, 2016, 36(11):1126-1128. SUN Y P, ZHOU X H, HE J M, et al.Homogenization treatment of Mg-4Sn-1Zn bio-magnesium alloy[J].Special Casting & Nonferrous Alloys, 2016, 36(11):1126-1128.
【17】袁家伟, 李婷, 李兴刚, 等.Mg-xZn-1Mn镁合金均匀化热处理及扩散动力学研究[J].稀有金属, 2012, 36(3):373-379. YUAN J W, LI T, LI X G, et al.Homogenizing heat treatment and diffusion kinetics of Mg-xZn-1Mn magnesium alloy[J].Chinese Journal of Rare Metals, 2012, 36(3):373-379.
【18】欧阳杰, 李慧中, 姜俊, 等.AZ80A镁合金的均匀化处理及扩散动力学[J].粉末冶金材料科学与工程, 2014, 19(1):8-14. OUYANG J, LI H Z, JIANG J, et al.Homogenizing treatment and diffusion kinetics of AZ80A magnesium alloy[J].Materials Science and Engineering of Powder Metallurgy, 2014, 19(1):8-14.
【19】张诗昌, 段汉桥, 蔡启舟, 等.主要合金元素对镁合金组织和性能的影响[J].铸造, 2001, 50(6):310-315. ZHANG S C, DUAN H Q, CAI Q Z, et al.Effects of the main alloying elements on microstructure and properties of magnesium alloys[J].Foundry, 2001, 50(6):310-315.
【20】XU D K, TANG W N, LIU L, et al.Effect of W-phase on the mechanical properties of as-cast Mg-Zn-Y-Zr alloys[J].Journal of Alloys and Compounds, 2008, 461(1/2):248-252.
【21】LU R P, WANG J F, CHEN Y L, et al.Effects of heat treatment on the morphology of long-period stacking ordered phase, the corresponding damping capacities and mechanical properties of Mg-Zn-Y alloys[J].Journal of Alloys and Compounds, 2015, 639:541-546.
【22】CHENG P, ZHAO Y H, LU R P, et al.Effect of Ti addition on the microstructure and mechanical properties of cast Mg-Gd-Y-Zn alloys[J].Materials Science and Engineering:A, 2017, 708:482-491.
相关信息