掺铜TiN涂层和离子液复合润滑体系对铜/铜摩擦副载流摩擦学性能的影响
Effect of Copper-Doped TiN Coating and Ionic Liquid Composite Lubrication Systemon Current-Carrying Tribological Properties of Copper/Copper Friction Pair
摘 要
通过多弧离子镀技术在铜基体上制备了TiN及其掺杂原子分数10%和12%铜的涂层，用1-辛基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐（OMImNTf2）和1-十二烷基-3-甲基咪唑双（三氟甲烷磺酰）亚胺盐（C12MImNTf2）2种离子液作为润滑剂，研究了涂层与离子液组成的复合润滑体系对不同电压（0.5，1 V）下铜/铜摩擦副的载流摩擦学性能的影响。结果表明：在电压相同条件下，TiN涂层与OMImNTf2复合润滑体系具有较好的协同润滑效果，TiN涂层与C12MImNTf2复合润滑体系具有较好的导电性能；在掺铜TiN涂层和2种离子液复合润滑体系下摩擦副的摩擦因数和接触电阻差别很小。当电压由0.5 V增大到1 V时，在TiN涂层、掺杂原子分数10%铜的TiN涂层与C12MImNTf2组成的复合润滑体系下摩擦副的摩擦学性能更稳定。掺杂原子分数12%铜的TiN涂层的摩擦副具有最小的摩擦因数和接触电阻。
掺铜
离子液
载流摩擦
铜/铜摩擦副
TiN coating
doping copper
ionic liquid
current-carrying friction
copper/copper friction pair
Abstract
TiN coating and TiN coatings doped with 10% and 20% (atom fraction) copper were prepared on copper substrate by multi arc ion plating. Using 1-octyl-3-methylimidazole double (trifluoromethane sulfonyl) imide salt (OMImNTf2) and 1-dodecyl-3-methylimidazole double (trifluoromethane sulfonyl) imide salt (C12MImNTf2) as the lubricant, the effect of coating and ionic liquid composite lubrication system on current-carrying tribological properties of copper/copper friction pair at different voltages (0.5,1 V) were studied. The results show that the TiN coating/OMImNTf2 composite lubrication system showed relatively good synergistic lubrication effect at the same voltage, while the TiN coating/C12MImNTf2 composite lubrication system exhibited relatively good conductivity property. The difference of friction coefficient and contact resistance of friction pair under composite lubrication system of copper-doped TiN coating and two ionic liquids was very small. When the voltage increased from 0.5 V to 1 V, the tribological properties of friction pair under composite lubrication system consisted of TiN coating,TiN coating doped with 10% copper and C12MImNTf2 was more stable. The friction pair containing TiN coating doped with 12% copper had the smallest friction coefficient and contact resistance.
中图分类号 TH117.1 DOI 10.11973/jxgccl202301013
所属栏目 材料性能及应用
基金项目 中央高校基金科研业务费资助项目（2019MS016）
收稿日期 2021/11/24
修改稿日期 2022/11/22
网络出版日期
作者单位点击查看
备注吴浩(1987-),女,湖北襄阳人,博士研究生
引用该论文: WU Hao,XIA Yanqiu,WU Lining,LIN Feihu. Effect of Copper-Doped TiN Coating and Ionic Liquid Composite Lubrication Systemon Current-Carrying Tribological Properties of Copper/Copper Friction Pair[J]. Materials for mechancial engineering, 2023, 47(1): 86～92
吴浩,夏延秋,吴礼宁,林飞虎. 掺铜TiN涂层和离子液复合润滑体系对铜/铜摩擦副载流摩擦学性能的影响[J]. 机械工程材料, 2023, 47(1): 86～92
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【2】谢博华, 鞠鹏飞, 吉利, 等.电接触材料摩擦学研究进展[J].摩擦学学报, 2019, 39(5):656-668. XIE B H, JU P F, JI L, et al.Research progress on tribology of electrical contact materials[J].Tribology, 2019, 39(5):656-668.
【3】奚恒恒, 何鹏飞, 刘世贵, 等.导电耐磨自润滑涂层的研究现状与展望[J].表面技术, 2019, 48(7):353-363. XI H H, HE P F, LIU S G, et al.Progress and prospect in the development of conductive wear resistantand self-lubricating coatings[J].Surface Technology, 2019, 48(7):353-363.
【4】LI Y, HE Y Y, WANG W, et al.Plasma nitriding of AISI 304 stainless steel in cathodic and floating electric potential:Influence on morphology, chemical characteristics and tribological behavior[J].Journal of Materials Engineering and Performance, 2018, 27(3):948-960.
【5】季鑫, 宓一鸣, 周细应.TiN薄膜制备方法、性能及其应用的研究进展[J].热加工工艺, 2009, 38(4):81-84. JI X, MI Y M, ZHOU X Y.Research progress of preparation technology, properties and application development of TiN thin film[J].Hot Working Technology, 2009, 38(4):81-84.
【6】PATSALAS P, LOGOTHETIDIS S.In-situ monitoring of the electronic properties and growth evolution of TiN films[J].Surface and Coatings Technology, 2004, 180/181:421-424.
【7】KIM T S, PARK S S, LEE B T.Characterization of nano-structured TiN thin films prepared by R.F.magnetron sputtering[J].Materials Letters, 2005, 59(29/30):3929-3932.
【8】RUDOLPHI Å K, JACOBSON S.Gross plastic fretting mechanical deterioration of silver coated electrical contacts[J].Wear, 1996, 201(1/2):244-254.
【9】SENOUCI A, ZAIDI H, FRENE J, et al.Damage of surfaces in sliding electrical contact copper/steel[J].Applied Surface Science, 1999, 144/145:287-291.
【10】刘德宝, 崔春翔.TiN颗粒增强铜基复合材料的制备及性能研究[J].稀有金属, 2004, 28(5):856-861. LIU D B, CUI C X.Fabrication and properties of TiN particle-reinforced copper matrix composites[J].Chinese Journal of Rare Metals, 2004, 28(5):856-861.
【11】刘德宝, 崔春翔.氮化物陶瓷颗粒增强铜基复合材料的干摩擦磨损性能研究[J].摩擦学学报, 2006, 26(1):54-59. LIU D B, CUI C X.Study on dry friction and wear properties of copper-matrix composites reinforced with nitrides ceramics particles[J].Tribology, 2006, 26(1):54-59.
【12】YAN M M, WANG X Y, ZHANG S W, et al.Friction and wear properties of GLC and DLC coatings under ionic liquid lubrication[J].Tribology International, 2020, 143:106067.
【13】BATTEZ A H, GONZALEZ R, VIESCA J L, et al.Lubrication of PVD coatings with ethyl-dimethyl-2-methoxyethylammonium tris (pentafluoroethyl) trifluorophosphate[J].Tribology International, 2013, 58:71-78.
【14】BLANCO D, GONZALEZ R, HERNANDEZ B A, et al.Use of ethyl-dimethyl-2-methoxyethylammonium tris(pentafluoroethyl)trifluorophosphate as base oil additive in the lubrication of TiN PVD coating[J].Tribology International, 2011, 44(5):645-650.
【15】CAO Z F, XIA Y Q, LIU L H, et al.Study on the conductive and tribological properties of copper sliding electrical contacts lubricated by ionic liquids[J].Tribology International, 2019, 130:27-35.
【16】CHEN J H, XIA Y Q, HU Y C, et al.Tribological performance and conductive capacity of Ag coating under boundary lubrication[J].Tribology International, 2017, 110:161-172.
【17】葛翔宇, 夏延秋, 赵小培, 等.锂盐添加剂对润滑油摩擦学性能和导电性的影响[J].摩擦学学报, 2015, 35(3):254-258. GE X Y, XIA Y Q, ZHAO X P, et al.Tribological properties and electrical conductivity of lithium salts in lubricant oil[J].Tribology, 2015, 35(3):254-258.
【18】夏延秋, 韩钰, 冯欣, 等.离子液体润滑性及导电能力研究进展[J].摩擦学学报, 2016, 36(6):794-802. XIA Y Q, HAN Y, FENG X, et al.The research progress on lubrication and electrical conductivity of ionic liquids[J].Tribology, 2016, 36(6):794-802.
【19】伏彦龙.氮化钛薄膜/液体润滑剂复合体系真空摩擦学性能研究[D].兰州:兰州大学, 2015. FU Y L.Tribological behavior of TiN/liquid lubricant composite systems under vacuum conditions[D].Lanzhou:Lanzhou University, 2015.
【20】宋晨飞, 孙毓明, 张燕燕, 等.纯铜滚动载流摩擦副在不同载荷和电压作用下的失效研究[J].机械工程学报, 2019, 55(9):63-70. SONG C F, SUN Y M, ZHANG Y Y, et al.Failure of Cu rolling triboelectric pairs under various load and voltage[J].Journal of Mechanical Engineering, 2019, 55(9):63-70.
【21】黄伊辉, 李芬芳, 尤建伟, 等.离子液体用作润滑剂的研究进展[J].润滑油, 2010, 25(1):4-11. HUANG Y H, LI F F, YOU J W, et al.The research progress of ionic liquids used as lubricants[J].Lubricating Oil, 2010, 25(1):4-11.
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