Research on Pipeline Corrosion of Oilfield Water Injection System and Main Control Factors
摘 要
为了明确油田注水管路腐蚀结垢的原因,利用X射线衍射仪和原子吸收分光光度计等仪器对水质和垢样进行了分析,采用电化学测试技术测试了管路材料在不同温度、CO2含量、H2S含量和硫酸盐还原菌(SRB)细菌含量组合作用下的腐蚀速率,设计了正交试验研究多因素耦合作用下腐蚀损伤的主控因素。结果表明,垢样成分中腐蚀垢占主导,温度为腐蚀结垢的主控因素,CO2和H2S对腐蚀均有两面性作用。
Abstract
In order to clarify the cause of corrosion and scale formation in oilfield water injection pipeline, the water quality and scale samples were analyzed by X-ray diffractometer and atomic absorption spectrophotometer, and the corrosion rates under the combination of different temperatures, CO2 content, H2S content and SRB bacteria content were measured by electrochemical testing technology. Orthogonal experiments were designed to study the main controlling factors of corrosion damage under multi-factor coupling. The results showed that corrosion scale was dominant in the scale sample components. The temperature was the main control factor of corrosion scale formation, and both CO2 and H2S have dual effects on corrosion.
中图分类号 TG174 DOI 10.11973/fsyfh-202301011
所属栏目 应用技术
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收稿日期 2022/8/3
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引用该论文: CHEN Kun,LI Donghao,LIU Chunhui,HU Hongxiang,WANG Zhengbin,NIU Cong. Research on Pipeline Corrosion of Oilfield Water Injection System and Main Control Factors[J]. Corrosion & Protection, 2023, 44(1): 63
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参考文献
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【4】陈涛,陈亮,王英. 油田注水系统结垢及治理措施探讨[J]. 安全与环境工程,2010,17(4):118-122.
【5】王庆. 东辛油田注水系统腐蚀结垢机理研究[J]. 石油化工腐蚀与防护,2007,24(1):25-28.
【6】马青庄,温淑新,杨建平,等.前大油田腐蚀结垢的原因及对策[J]. 腐蚀科学与防护技术,2002,14(5):299-301.
【7】郭润生,孙红江,刘杰. 韩渠油田注水管线的结垢腐蚀与防治[J]. 海洋石油,2001,21(3):49-51.
【8】WEI L,PANG X L,GAO K W. Corrosion of low alloy steel and stainless steel in supercritical CO2/H2O/H2S systems[J]. Corrosion Science,2016,111:637-648.
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【10】NE I AC'G S. Key issues related to modelling of internal corrosion of oil and gas pipelines-A review[J]. Corrosion Science,2007,49(12):4308-4338.
【11】ZHANG Y L,DU M,ZHANG J,et al. Corrosion behavior of X65 carbon steel in simulated oilfield produced water[J]. Materials and Corrosion,2015,66(4):366-374.
【12】SUN W,NE I AC'G S. Kinetics of corrosion layer formation:part 1-iron carbonate layers in carbon dioxide corrosion[J]. CORROSION,2008,64(4):334-346.
【13】TANG J W,SHAO Y W,GUO J B,et al. The effect of H2S concentration on the corrosion behavior of carbon steel at 90℃[J]. Corrosion Science,2010,52(6):2050-2058.
【14】MA H Y,CHENG X L,LI G Q,et al. The influence of hydrogen sulfide on corrosion of iron under different conditions[J]. Corrosion Science,2000,42(10):1669-1683.
【15】REN C Q,LIU D X,BAI Z Q,et al. Corrosion behavior of oil tube steel in simulant solution with hydrogen sulfide and carbon dioxide[J]. Materials Chemistry and Physics,2005,93(2/3):305-309.
【16】SUN W,NE I AC'G S. A mechanistic model of uniform hydrogen sulfide/carbon dioxide corrosion of mild steel[J]. CORROSION,2009,65(5):291-307.
【17】艾俊哲,梅平,邱小庆,等. 油气水共存的非均相介质中N80钢二氧化碳/硫化氢腐蚀行为研究[J]. 石油天然气学报,2009,31(4):157-160,427.
【18】康阿利. 潍北油田注水井套管腐蚀机理及防腐措施技术研究[D]. 西安:西安石油大学,2011.
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【20】李昊宸,谢飞,齐季,等. 温度和硫酸盐还原菌(SRB)协同作用下X80钢的腐蚀行为[J]. 钢铁研究学报,2020,32(10):900-908.
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