熔融太阳盐中金属氧化物纳米颗粒对304不锈钢的防护效果
Protection Effects of Metal Oxide Nanoparticles in Molten Solar Salt on Corrosion of 304 Stainless Steel
摘 要
采用腐蚀增重法和表面分析技术研究了模拟熔融太阳盐中Al2O3,CuO,ZnO,TiO2,SnO2等五种纳米颗粒对太阳盐储罐材料304不锈钢腐蚀的影响。结果表明:304不锈钢浸渍在含与不含纳米颗粒的熔融太阳盐中均出现腐蚀增重现象。Al2O3,CuO,ZnO,TiO2,SnO2等五种纳米颗粒的加入会均对304不锈钢的腐蚀增重产生抑制作用,抑制效果由大到小依次为Al2O3>ZnO>CuO>TiO2>SnO2。在熔融太阳盐中,纳米金属氧化物颗粒可在不锈钢表面形成良好的保护膜,除了与纳米颗粒在不锈钢表面氧化层形成物理掺杂以外,发生化学掺杂是更重要的影响因素。
太阳盐
不锈钢
腐蚀
金属氧化物
纳米颗粒
photothermal power generation
solar salt
stainless steel
corrosion
metal oxide
nano particl
Abstract
The effect of five kinds of nano particles Al2O3, CuO, ZnO, TiO2 and SnO2 in simulated molten solar salt on corrosion of 304 stainless steel used as solar salt storage tank material was studied by corrosion weight gain method and surface analysis technology. The results showed that all the 304 stainless steel samples immersed in molten solar salt with or without nano particles had corrosion and weight gain. The addition of Al2O3, CuO, ZnO, TiO2 and SnO2 nano particles could inhibit the corrosion of 304 stainless steel, and the inhibition effect rank was Al2O3, ZnO, CuO, TiO2 and SnO2 in turn. In molten solar salt, the nano metal oxide particles could form a good protective film on the stainless steel surface. In addition to forming physical doping with nano particles on the stainless steel surface oxide layer, chemical doping was a more important factor.
中图分类号 TG174 DOI 10.11973/fsyfh-202304007
所属栏目 试验研究
基金项目
收稿日期 2021/4/20
修改稿日期
网络出版日期
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引用该论文: MA Linrui,LI Weiju,TANG Fei,LIAO Qiangqiang. Protection Effects of Metal Oxide Nanoparticles in Molten Solar Salt on Corrosion of 304 Stainless Steel[J]. Corrosion & Protection, 2023, 44(4): 38
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参考文献
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【2】DUDDA B,SHIN D. Effect of nanoparticle dispersion on specific heat capacity of a binary nitrate salt eutectic for concentrated solar power applications[J]. International Journal of Thermal Sciences,2013,69:37-42.
【3】DING W J,GOMEZ-VIDAL J,BONK A,et al. Molten chloride salts for next generation CSP plants:Electrolytical salt purification for reducing corrosive impurity level[J]. Solar Energy Materials and Solar Cells,2019,199:8-15.
【4】XU X,WANG X,LI P,et al. Experimental test of properties of KCl-MgCl2 eutectic molten salt for heat transfer and thermal storage fluid in concentrated solar power systems[J]. Journal of Solar Energy Engineering, 2018, 140(5): 051011.
【5】KXEARNEY,LI D,HERRMANN U,NAVA P,et al. Assessment of a molten salt heat transfer fluid in a parabolic trough solar field[J]. Journal of Solar Energy Engineering,2003,125(2):170-176.
【6】周才正,洛桑,孙延虎,等. 304不锈钢在不同温度硝酸熔盐中的腐蚀行为[J]. 机械工程材料,2019,43(5):68-70,78.
【7】宋明. 多元氯化物熔盐体系的构建及性能研究[D]. 广州:华南理工大学,2015.
【8】马宏芳,朱明,赵云苗,等. 两种合金在氯化物熔盐中腐蚀行为研究[J]. 材料导报,2014,28(14):109-113.
【9】彭浩. 氟熔盐体系腐蚀杂质及氧化物溶解行为的研究[D]. 上海:中国科学院研究生院(上海应用物理研究所),2017.
【10】OLSON L C,AMBROSEK J W,SRIDHARAN K,et al. Materials corrosion in molten LiF-NaF-KF salt[J]. Journal of Fluorine Chemistry,2009,130(1):67-73.
【11】KUMAR V,ARORA N. High temperature corrosion behaviour of 20MnMoNi55 and AISI 304 bare steel in 75% Na2SO4 +25% K2SO4 molten salt environment at 900℃[J]. Procedia Materials Science,2014,5:76-85.
【12】YAN Y F,XU X Q,ZHOU D Q,et al. Hot corrosion behaviour and its mechanism of a new alumina-forming austenitic stainless steel in molten sodium sulphate[J]. Corrosion Science,2013,77:202-209.
【13】孙华,张鹏,王建强. 传热储热用熔融硝酸盐及其腐蚀问题[J]. 腐蚀科学与防护技术,2017,29(5):567-574.
【14】KEARNEY D,HERRMANN U,NAVA P,et al. Assessment of a molten salt heat transfer fluid in a parabolic trough solar field[J]. Journal of Solar Energy Engineering,2003,125(2):170-176.
【15】TAVAKOLI M,GHOLAMI-KERMANSHAHI M,NEUBERT V W M. Effects of molten-salt LiNO3 on high-temperature corrosion behaviour of absorption tubes of a concentrating solar power system[J]. Corrosion Engineering,Science and Technology,2020,55(1):18-26.
【16】GROSU Y,BONDARCHUK O,FAIK A. The effect of humidity,impurities and initial state on the corrosion of carbon and stainless steels in molten HitecXL salt for CSP application[J]. Solar Energy Materials and Solar Cells,2018,174:34-41.
【17】FEDERSEL K,WORTMANN J,LADENBERGER M. High-temperature and corrosion behavior of nitrate nitrite molten salt mixtures regarding their application in concentrating solar power plants[J]. Energy Procedia,2015,69:618-625.
【18】MUÑOZ-SÁNCHEZ B,NIETO-MAESTRE J,IPARRAGUIRRE-TORRES I,et al. Molten salt-based nanofluids as efficient heat transfer and storage materials at high temperatures.An overview of the literature[J]. Renewable and Sustainable Energy Reviews,2018,82:3924-3945.
【19】熊亚选,王振宇,徐鹏,等. 添加纳米SiO2对单组分及二元硝酸盐热物性的影响[J]. 化工学报,2018,69(10):4418-4426.
【20】李昭,李宝让,崔柳,等. 高温熔盐基纳米流体热物性的稳定性研究[J]. 储能科学与技术,2020,9(6):1775-1783.
【21】HO M X,PAN C. Optimal concentration of alumina nanoparticles in molten Hitec salt to maximize its specific heat capacity[J]. International Journal of Heat and Mass Transfer,2014,70:174-184.
【22】FERNÁNDEZ A G,MUÑOZ-SÁNCHEZ B,NIETO-MAESTRE J,et al. High temperature corrosion behavior on molten nitrate salt-based nanofluids for CSP plants[J]. Renewable Energy,2019,130:902-909.
【23】GROSU Y,UDAYASHANKAR N,BONDARCHUK O,et al. Unexpected effect of nanoparticles doping on the corrosivity of molten nitrate salt for thermal energy storage[J]. Solar Energy Materials and Solar Cells,2018,178:91-97.
【24】MUÑOZ-SÁNCHEZ B,NIETO-MAESTRE J,IMBULUZQUETA G,et al. A precise method to measure the specific heat of solar salt-based nanofluids[J]. Journal of Thermal Analysis and Calorimetry,2017,129(2):905-914.
【25】李昭,文卜,陈豪志,等. 高温熔融盐基纳米流体的研究现状及进展[J]. 中国电机工程学报,2021,41(6):2168-2187.
【26】BURSTEIN G T,PISTORIUS P C,MATTIN S P. The nucleation and growth of corrosion pits on stainless steel[J]. Corrosion Science,1993,35(1/2/3/4):57-62.
【27】MCCONOHY G,KRUIZENGA A. Molten nitrate salts at 600 and 680℃:Thermophysical property changes and corrosion of high-temperature nickel alloys[J]. Solar Energy,2014,103:242-252.
【28】GOMES A,NAVAS M,URANGA N,et al. High-temperature corrosion performance of austenitic stainless steels type AISI 316L and AISI 321H,in molten Solar Salt[J]. Solar Energy,2019,177:408-419.
【29】KHORSAND S,SHEIKHI A,RAEISSI K,et al. Hot corrosion behavior of inconel 625 superalloy in eutectic molten nitrate salts[J]. Oxidation of Metals,2018,90(1):169-186.
【30】GOODS S H,BRADSHAW R W. Corrosion of stainless steels and carbon steel by molten mixtures of commercial nitrate salts[J]. Journal of Materials Engineering and Performance,2004,13(1):78-87.
【31】张学文,李洪川,李生云,等. 304、316不锈钢和Inconel 617镍基合金在硝酸熔盐中的腐蚀行为[J]. 机械工程材料,2019,43(5):24-29.
【32】NAGARATHNAM K,KOMVOPOULOS K. Microstructural analysis and oxidation behavior of laser-processed Fe-Cr-AI-Y alloy coatings[J]. Metallurgical and Materials Transactions A,1996,27(2):381-390.
【33】BIEDENKOPF P,SPIEGEL M,GRABKE H J. The corrosion behavior of Fe-Cr alloys containing Co,Mn,and/or Ni and of a Co-base alloy in the presence of molten (Li,K)-carbonate[J]. Werkstoffe Und Korrosion,1997,48(11):731-743.
【34】ATTIA A A,SALIH S A,BARAKA A M. Corrosion and passivation behaviors of some stainless steel alloys in molten alkali carbonates[J]. Electrochimica Acta,2002,48(2):113-118.
【35】FERNÁNDEZ A G,GALLEGUILLOS H,PÉREZ F J. Thermal influence in corrosion properties of Chilean solar nitrates[J]. Solar Energy,2014,109:125-134.
【36】VILLADA C,BONK A,BAUER T,et al. High-temperature stability of nitrate/nitrite molten salt mixtures under different atmospheres[J]. Applied Energy,2018,226:107-115.
【37】刘薇,陈建立. 古代青铜器表面高锡锈层研究综述[J]. 中国国家博物馆馆刊,2019(5):146-160.
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