Corrosion Mechanism of Elemental Sulfur and Its Source in a Light Hydrocarbon Station in Tahe
摘 要
采用扫描电子显微镜(SEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)等方法检测分析了塔河油田轻烃站部分设备内表面的腐蚀产物,并且通过现场取样试验对单质硫的来源进行了分析。结果表明:该轻烃站内设备及管线的腐蚀产物中含有大量单质硫,单质硫腐蚀是该轻烃站腐蚀的重要原因之一;该轻烃站内的单质硫主要来源于原料气;该轻烃站单质硫腐蚀的主要机理为水解机理即单质硫水解生成硫酸、硫化氢等腐蚀性物质。
Abstract
The corrosion products on the inner surface of some equipment of a light hydrocarbon station in Tahe oilfield were analyzed by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). In addition, the source of elemental sulfur was also clarified by on-site sampling experiments. The results showed that the corrosion products of the equipment and pipeline in the hydrocarbon station contained a large amount of elemental sulfur. Elemental sulfur corrosion was one of the important reasons for the corrosion of this light hydrocarbon station. And the elemental sulfur in the light hydrocarbon station mainly come from feed gas. The main mechanism of elemental sulfur corrosion of the light hydrocarbon station was hydrolysis mechanism that is, sulfur hydrolzed to produce corrosive substances such as sulfuric acid and hydrogen sulfide.
中图分类号 TG172 DOI 10.11973/fsyfh-202305018
所属栏目 失效分析
基金项目 国家重大专项(2016ZX05053);中石化重点项目(319016-5)
收稿日期 2021/6/29
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引用该论文: ZHANG Zhihong,GAO Qiuying,YANG Zuguo,ZHONG Xiankang,LIU Qiang,SUN Haijiao. Corrosion Mechanism of Elemental Sulfur and Its Source in a Light Hydrocarbon Station in Tahe[J]. Corrosion & Protection, 2023, 44(5): 100
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【10】KENNELLEY K J, SMITH S N, RAMANARAYANAN T A. Effect of elemental sulfur on the performance of nitrogen-based oilfield corrosion inhibitors[J]. Materials Performance, 1990, 29(2).
【11】ZHANG L, WEN Z B, LI X Y, et al. Effects of depositing characteristic and temperature on elemental sulfur corrosion[C]//Corrosion 2011. Houston, TX:NACE International, 2011.
【12】赵震, 黄雪峰, 刘强. 塔河油田地面集输处理系统腐蚀穿孔原因[J]. 腐蚀与防护, 2013, 34(5):442-445.
【13】张志宏, 许艳艳, 葛鹏莉, 等. 塔河油田集输管线20#钢在CO2/H2S环境中的腐蚀行为[J]. 工业安全与环保, 2020, 46(1):32-36.
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