馆藏脆弱铁质文物展柜相对湿度被动控制的定量研究
Quantitative Study on Passive Control of Relative Humidity in the Showcase Microenvironment of Fragile Iron Cultural Relics in Museum Collections
摘 要
在三种具有代表性的展柜空气交换率状态下,定量研究了硅胶的使用方式及长期控制效果,并放置预腐蚀铁片样品对控制效果进行验证。结果表明:当展柜空气交换率不高于0.42 d-1时,采用硅胶材料能够至少在3个月内为铁质文物创造相对湿度低于20%的展柜微环境;在控制相对湿度的展柜内,含有四方纤铁矿(β-FeOOH)的铁片样品未发生明显变化,而放置在展柜外的对照组铁片样品表面锈层增厚,并出现肉眼可见的新生壳状产物、裂缝和层状剥离,进一步证明了该被动控制方法的有效性。
展柜微环境
被动控制方法
预防性保护
iron cultural relic
showcase microenvironment
passive control method
preventive conservation
Abstract
Quantitative research was conducted on the use of silica gel and its long-term control effect under three representative air exchange rates (AER) of showcases, and pre-corroded iron sheet samples were placed to verify the control effect. The results showed that when the AER was not higher than 0.42 d-1, the passive control method could create a showcase microenvironment with relative humidity lower than 20% for iron cultural relics in a period of at least three months. The iron sheets with akaganeite (β-FeOOH) in the showcase did not change significantly, but the rust layer on the samples placed outside of the showcase had thickened, and there were visible shell products, cracks and spalling, which further proved the effectiveness of the passive control method.
中图分类号 G264 DOI 10.11973/fsyfh-202307004
所属栏目 试验研究
基金项目 国家重点研发计划(2020YFC1522105);国家文物局重点科研基地自筹经费科研项目(2020ZCK111)
收稿日期 2023/3/12
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: LIU Min,ZHANG Ran,WANG Jianping. Quantitative Study on Passive Control of Relative Humidity in the Showcase Microenvironment of Fragile Iron Cultural Relics in Museum Collections[J]. Corrosion & Protection, 2023, 44(7): 20
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】马清林,张治国. 博物馆铁质文物保护技术手册[M]. 北京:文物出版社,2011.
【2】许淳淳,潘路. 金属文物保护——全程技术方案[M]. 北京:化学工业出版社,2012.
【3】王蕙贞. 文物保护学[M]. 北京:文物出版社,2009.
【4】张然,柳敏. 铁质文物预防性保护研究进展之一:含氯化物的铁质文物保存环境研究[J]. 上海视觉,2022(1):19-25.
【5】YU D,KLEIN S A,REINDL D T. An evaluation of silica gel for humidity control in display cases[J]. WAAC Newsletter, 2001,23(1):14-19.
【6】RIMMER M,THICKETT D,WATKINSON D,et al. Guidelines for the storage and display of archaeological metalwork[M]. Swindon:English Heritage,2013.
【7】WATTS S,CROMBIE D S,JONES S,et al. Museum showcases:specification and reality,costs and benefits[C]//"Museum Microclimates" Copenhagen Conference,[S.l.]:[s.n.],2007:253-260.
【8】段兵兵. 基于扩散吸收式制冷的文物展柜恒湿环境控制研究[D]. 杭州:浙江大学,2017.
【9】PERINO M. Air tightness and RH control in museum showcases:Concepts and testing procedures[J]. Journal of Cultural Heritage,2018,34:277-290.
【10】THICKETT D,ODLYHA M. Assessment of dry storage microenvironments for archaeological iron[C]//Williams E,Peachey C. The Conservation of Archaeological Materials:Current Trends and Future Directions. Oxford,England:Archaeopress,2010:187-199.
【11】徐方圆,解玉林,吴来明. 文物保存微环境用调湿材料调湿性能研究[J]. 文物保护与考古科学,2009,21(S1):18-23.
【12】国家质量监督检验检疫总局,中国国家标准化管理委员会. 文物展柜密封性能及检测:GB/T 36110-2018[S]. 北京:中国标准出版社,2018.
【13】WEINTRAUB S. Demystifying silica gel[J]. Objects Specialty Group Postprints,2002,9.
【14】TURGOOSE S. The nature of surviving iron objects[C]//Clarke R W,Blackshaw S M. Conservation of Iron. Greenwich,London:Trustees of the National Maritime Museum,1982:1-7.
【15】张然. 铁质文物腐蚀产物β-FeOOH的产生及危害[J]. 腐蚀与防护,2021,42(11):1-11,48.
【16】THICKETT D. Post excavation changes and preventive conservation of archaeological iron[D]. London:University of London,2012:291-294.
【17】THICKETT D,ODLHA M. The formation and transformation of akageneite[C]//Hyslop E,Gonzalez V,Troalen L,et al. Metal 2013:Interim Meeting of the ICOM-CC Metal Working Group,Conference Proceedings. Edinburgh,Scotland:Historic Scotland, International Council of Museums,2013:107-113.
【18】LAIR V,ANTONY H,LEGRAND L,et al. Electrochemical reduction of ferric corrosion products and evaluation of galvanic coupling with iron[J]. Corrosion Science,2006,48(8):2050-2063.
【19】WANG Q. Effects of relative humidity on the corrosion of iron:an experimental view[J]. The British Museum Technical Research Bulletin,2007,1:65-73.
【20】WATKINSON D,LEWIS M. Desiccated storage of chloride-contaminated archaeological iron objects[J]. Studies in Conservation,2005,50(4):241-252.
【2】许淳淳,潘路. 金属文物保护——全程技术方案[M]. 北京:化学工业出版社,2012.
【3】王蕙贞. 文物保护学[M]. 北京:文物出版社,2009.
【4】张然,柳敏. 铁质文物预防性保护研究进展之一:含氯化物的铁质文物保存环境研究[J]. 上海视觉,2022(1):19-25.
【5】YU D,KLEIN S A,REINDL D T. An evaluation of silica gel for humidity control in display cases[J]. WAAC Newsletter, 2001,23(1):14-19.
【6】RIMMER M,THICKETT D,WATKINSON D,et al. Guidelines for the storage and display of archaeological metalwork[M]. Swindon:English Heritage,2013.
【7】WATTS S,CROMBIE D S,JONES S,et al. Museum showcases:specification and reality,costs and benefits[C]//"Museum Microclimates" Copenhagen Conference,[S.l.]:[s.n.],2007:253-260.
【8】段兵兵. 基于扩散吸收式制冷的文物展柜恒湿环境控制研究[D]. 杭州:浙江大学,2017.
【9】PERINO M. Air tightness and RH control in museum showcases:Concepts and testing procedures[J]. Journal of Cultural Heritage,2018,34:277-290.
【10】THICKETT D,ODLYHA M. Assessment of dry storage microenvironments for archaeological iron[C]//Williams E,Peachey C. The Conservation of Archaeological Materials:Current Trends and Future Directions. Oxford,England:Archaeopress,2010:187-199.
【11】徐方圆,解玉林,吴来明. 文物保存微环境用调湿材料调湿性能研究[J]. 文物保护与考古科学,2009,21(S1):18-23.
【12】国家质量监督检验检疫总局,中国国家标准化管理委员会. 文物展柜密封性能及检测:GB/T 36110-2018[S]. 北京:中国标准出版社,2018.
【13】WEINTRAUB S. Demystifying silica gel[J]. Objects Specialty Group Postprints,2002,9.
【14】TURGOOSE S. The nature of surviving iron objects[C]//Clarke R W,Blackshaw S M. Conservation of Iron. Greenwich,London:Trustees of the National Maritime Museum,1982:1-7.
【15】张然. 铁质文物腐蚀产物β-FeOOH的产生及危害[J]. 腐蚀与防护,2021,42(11):1-11,48.
【16】THICKETT D. Post excavation changes and preventive conservation of archaeological iron[D]. London:University of London,2012:291-294.
【17】THICKETT D,ODLHA M. The formation and transformation of akageneite[C]//Hyslop E,Gonzalez V,Troalen L,et al. Metal 2013:Interim Meeting of the ICOM-CC Metal Working Group,Conference Proceedings. Edinburgh,Scotland:Historic Scotland, International Council of Museums,2013:107-113.
【18】LAIR V,ANTONY H,LEGRAND L,et al. Electrochemical reduction of ferric corrosion products and evaluation of galvanic coupling with iron[J]. Corrosion Science,2006,48(8):2050-2063.
【19】WANG Q. Effects of relative humidity on the corrosion of iron:an experimental view[J]. The British Museum Technical Research Bulletin,2007,1:65-73.
【20】WATKINSON D,LEWIS M. Desiccated storage of chloride-contaminated archaeological iron objects[J]. Studies in Conservation,2005,50(4):241-252.
相关信息
