喷丸处理对S31035奥氏体耐热钢抗高温水蒸气氧化行为的影响
Effect of Shot Peening on High Temperature Steam Oxidation Resistance of S31035 Austenitic Heat Resistant Steel
摘 要
对S31035钢进行喷丸处理,再在665 ℃下进行高温蒸汽氧化试验,研究了喷丸处理对该钢抗高温水蒸气氧化行为的影响。结果表明:未喷丸试样在氧化100 h后即出现明显的氧化物衍射峰,氧化3 000 h后形成双氧化物层,氧化膜厚度约为8.07 μm;喷丸试样在氧化1 000 h后才出现微弱的(Fe,Cr)2O3衍射峰,在氧化3 000 h后表面氧化膜仍然较薄,厚度仅为0.45 μm;在氧化过程中,喷丸试样的氧化速率常数比未喷丸试样低3个数量级,抗水蒸气氧化性能较好;喷丸处理细化了表层晶粒,为铬元素扩散提供了更多通道,使表面形成Cr2O3保护膜而提高了该钢的抗高温水蒸气氧化性能。
晶粒细化
S31035钢
水蒸气氧化
shot peening
grain refinement
S31035 steel
water vapor oxidation
Abstract
The S31035 steel was shot peened, and then the high temperature steam oxidation test was carried out at 665 ℃. The effect of shot peening on the high temperature steam oxidation behavior of the steel was studied. The results show that the unpeening sample had obvious oxide diffraction peaks after 100 h oxidation, and a double-layer of oxides was formed after 3 000 h oxidation. The oxide film thickness of the unpeening sample was about 8.07 μm. The weak (Fe,Cr)2O3 diffraction peak appeared in the shot peening sample after 1 000 h oxidation, and the surface oxide film was still thin after 3 000 h oxidation, with a thickness of only 0.45 μm. In oxidation, the oxidation rate constant of the shot peening sample was 3 orders of magnitude lower than that of the unpeening sample, and the steam oxidation resistance was better. The shot peening refined the surface grains, which provided more channels for chromium diffusion and led to formation of a Cr2O3 protective film on the surface, thereby improved the high temperature steam oxidation resistance of the steel.
中图分类号 TG174.4 DOI 10.11973/jxgccl202308011
所属栏目 材料性能及应用
基金项目 国家自然科学基金资助项目(51961028)
收稿日期 2022/6/13
修改稿日期 2023/7/31
网络出版日期
作者单位点击查看
联系人作者刘光明
备注李玉(1998-),女,江西南昌人,硕士研究生
引用该论文: LI Yu,HE Sifan,LIU Guangming,YANG Shou,LIU Zhihao,LI Futian. Effect of Shot Peening on High Temperature Steam Oxidation Resistance of S31035 Austenitic Heat Resistant Steel[J]. Materials for mechancial engineering, 2023, 47(8): 65～71
李玉,何思凡,刘光明,杨首恩,柳志浩,李富天. 喷丸处理对S31035奥氏体耐热钢抗高温水蒸气氧化行为的影响[J]. 机械工程材料, 2023, 47(8): 65～71
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参考文献
【1】周慧云,洪嘉,黄健航,等.超临界锅炉用材料的高温腐蚀研究进展[J].表面技术,2016,45(11):145-152. ZHOU H Y,HONG J,HUANG J H,et al.Research progress on the high temperature corrosion of supercritical boiler materials[J].Surface Technology,2016,45(11):145-152.
【2】李辛庚,齐慧滨,王学刚,等.火电厂锅炉再热器管高温腐蚀研究[J].材料保护,2003,36(6):9-11. LI X G,QI H B,WANG X G,et al.High temperature corrosion of TP304H boiler re-heater tubes[J].Materials Protection,2003,36(6):9-11.
【3】方旭东,李阳,夏焱,等.新型耐热合金TG700C热变形及动态再结晶行为[J].材料热处理学报,2016,37(9):92-99. FANG X D,LI Y,XIA Y,et al.Hot deformation and dynamic recrystallization behavior of new heat resistant alloy TG700C[J].Transactions of Materials and Heat Treatment,2016,37(9):92-99.
【4】Design guidelines for corrosion, erosion and steam oxidation of boiler tubes in pulverized coal-fired boilers:STP-PT-066-2014[S]. New York:ASME Standards Technology LLC,2014.
【5】赵慧传,唐丽英,贾建民,等.喷丸处理对S30432锅炉管抗蒸汽氧化性能的影响[J].中国电力,2014,47(4):9-13. ZHAO H C,TANG L Y,JIA J M,et al.Influences of shot blasting on steam oxidation resistance of S30432 boiler tubes[J].Electric Power,2014,47(4):9-13.
【6】王智春,蔡文河,韩哲文,等.喷丸处理对S30432钢650℃蒸汽氧化行为的影响[J].表面技术,2018,47(2):42-47. WANG Z C,CAI W H,HAN Z W,et al.Effects of shot peening on oxidation behavior of S30432 steel in steam at 650℃[J].Surface Technology,2018,47(2):42-47.
【7】刘宇钢,刘银河,莫春鸿,等.630℃煤电锅炉用S31035管材的高温腐蚀性能[J].表面技术,2022,51(4):176-182. LIU Y G,LIU Y H,MO C H,et al.High temperature corrosion of S31035 for 630℃ coal-fired power plant boiler[J].Surface Technology,2022,51(4):176-182.
【8】ZHANG N Q,ZHU Z L,YUE G Q,et al.The oxidation behaviour of an austenitic steel in deaerated supercritical water at 600-700℃[J].Materials Characterization,2017,132:119-125.
【9】岳增武,李辛庚.喷丸处理提高奥氏体耐热钢抗氧化性能的研究及应用[J].材料热处理学报,2013,34(1):157-162. YUE Z W,LI X G.Research and application of shot peening on oxidation resistance of austenitic steels in steam[J].Transactions of Materials and Heat Treatment,2013,34(1):157-162.
【10】刘巍栋,蔡文河,赵勇,等.630~650℃超超临界参数锅炉受热面管备选材料建议[J].钢铁研究学报,2021,33(9):891-900. LIU W D,CAI W H,ZHAO Y,et al.Suggestion on alternative heated surface tube materials for 630-650℃ ultra-supercritical units[J].Journal of Iron and Steel Research,2021,33(9):891-900.
【11】王玲,向军淮,张洪华,等.3种不同Cr含量Co-20Re-Cr合金在1000和1100℃的高温氧化行为[J].中国腐蚀与防护学报,2019,39(1):83-88. WANG L,XIANG J H,ZHANG H H,et al.High temperature oxidation behavior of three Co-20Re-xCr alloys in 3.04×10-5 Pa oxygen at 1000 and 1100℃[J].Journal of Chinese Society for Corrosion and Protection,2019,39(1):83-88.
【12】BIRKS N,MEIER G H,PETTIT F S.金属高温氧化导论[M].北京:高等教育出版社,2010. BIRKS N,MEIER G H,PETTIT F S.Introduction to the high-temperature oxidation of metals[M].Beijing:Higher Education Press,2010.
【13】张骏,蔡文河,杜双明,等.喷丸奥氏体耐热钢抗蒸汽氧化性的研究与使用现状[J].表面技术,2020,49(9):133-140. ZHANG J,CAI W H,DU S M,et al.Research and application status of steam oxidation resistance of shot peening austenitic heat-resistant steel[J].Surface Technology,2020,49(9):133-140.
【14】PARK D J,KIM H G,PARK J Y,et al.A study of the oxidation of FeCrAl alloy in pressurized water and high-temperature steam environment[J].Corrosion Science,2015,94:459-465.
【15】王志民,刘光明,吴世强,等.热处理对S30432喷丸不锈钢抗高温水蒸汽氧化性能的影响[J].材料热处理学报,2019,40(2):124-132. WANG Z M,LIU G M,WU S Q,et al.Effect of heat treatment on high temperature steam oxidation resistance of shot blasted S30432 stainless steel[J].Transactions of Materials and Heat Treatment,2019,40(2):124-132.
【16】王锐坤,郑志军,高岩.表面喷丸工艺对Super304H奥氏体耐热钢组织与性能的影响[J].中南大学学报(自然科学版),2017,48(4):903-909. WANG R K,ZHENG Z J,GAO Y.Effect of surface shot peening on microstructure and properties of Super304H austenitic heat-resistant steels[J].Journal of Central South University (Science and Technology),2017,48(4):903-909.
【17】杨首恩,杨华春,刘盛波.喷丸处理对18-8型奥氏体耐热钢抗蒸汽氧化性能的影响[J].发电设备,2019,33(3):189-192. YANG S E,YANG H C,LIU S B.Influence of shot peening on steam oxidation resistance of 18-8 type austenitic heat-resistant steels[J].Power Equipment,2019,33(3):189-192.
【18】崔忠圻,覃耀春.金属学与热处理[M].2版.北京:机械工业出版社,2011. CUI Z Q,QIN Y C.Metallurgy and heat treatment[M].2nd ed.Beijing:China Machine Press,2011.
【19】尹泽华,周永莉,鲁金涛,等.700℃下Nb对HR3C奥氏体耐热钢蒸汽氧化行为的影响[J].表面技术,2020,49(12):267-273. YIN Z H,ZHOU Y L,LU J T,et al.Effect on steam oxidation behavior of HR3C austenitic steels at 700℃[J].Surface Technology,2020,49(12):267-273.
【20】胡赓祥,蔡珣,戎咏华.材料科学基础[M].3版.上海:上海交通大学出版社,2011. HU G X,CAI X,RONG Y H.Fundamentals of materials science[M].3rd ed.Shanghai:Shanghai Jiao Tong University Press,2011.
【21】张新宇,王磊,王尧,等.静电场处理对GH4169合金中Fe、Cr元素扩散行为的影响[J].钢铁研究学报,2011,23(增刊2):146-149. ZHANG X Y,WANG L,WANG Y,et al.Effect of electrostatic-field treatment on the diffusion behaveors of Fe and Cr in GH4169 superalloy[J].Journal of Iron and Steel Research,2011,23(S2):146-149.
【2】李辛庚,齐慧滨,王学刚,等.火电厂锅炉再热器管高温腐蚀研究[J].材料保护,2003,36(6):9-11. LI X G,QI H B,WANG X G,et al.High temperature corrosion of TP304H boiler re-heater tubes[J].Materials Protection,2003,36(6):9-11.
【3】方旭东,李阳,夏焱,等.新型耐热合金TG700C热变形及动态再结晶行为[J].材料热处理学报,2016,37(9):92-99. FANG X D,LI Y,XIA Y,et al.Hot deformation and dynamic recrystallization behavior of new heat resistant alloy TG700C[J].Transactions of Materials and Heat Treatment,2016,37(9):92-99.
【4】Design guidelines for corrosion, erosion and steam oxidation of boiler tubes in pulverized coal-fired boilers:STP-PT-066-2014[S]. New York:ASME Standards Technology LLC,2014.
【5】赵慧传,唐丽英,贾建民,等.喷丸处理对S30432锅炉管抗蒸汽氧化性能的影响[J].中国电力,2014,47(4):9-13. ZHAO H C,TANG L Y,JIA J M,et al.Influences of shot blasting on steam oxidation resistance of S30432 boiler tubes[J].Electric Power,2014,47(4):9-13.
【6】王智春,蔡文河,韩哲文,等.喷丸处理对S30432钢650℃蒸汽氧化行为的影响[J].表面技术,2018,47(2):42-47. WANG Z C,CAI W H,HAN Z W,et al.Effects of shot peening on oxidation behavior of S30432 steel in steam at 650℃[J].Surface Technology,2018,47(2):42-47.
【7】刘宇钢,刘银河,莫春鸿,等.630℃煤电锅炉用S31035管材的高温腐蚀性能[J].表面技术,2022,51(4):176-182. LIU Y G,LIU Y H,MO C H,et al.High temperature corrosion of S31035 for 630℃ coal-fired power plant boiler[J].Surface Technology,2022,51(4):176-182.
【8】ZHANG N Q,ZHU Z L,YUE G Q,et al.The oxidation behaviour of an austenitic steel in deaerated supercritical water at 600-700℃[J].Materials Characterization,2017,132:119-125.
【9】岳增武,李辛庚.喷丸处理提高奥氏体耐热钢抗氧化性能的研究及应用[J].材料热处理学报,2013,34(1):157-162. YUE Z W,LI X G.Research and application of shot peening on oxidation resistance of austenitic steels in steam[J].Transactions of Materials and Heat Treatment,2013,34(1):157-162.
【10】刘巍栋,蔡文河,赵勇,等.630~650℃超超临界参数锅炉受热面管备选材料建议[J].钢铁研究学报,2021,33(9):891-900. LIU W D,CAI W H,ZHAO Y,et al.Suggestion on alternative heated surface tube materials for 630-650℃ ultra-supercritical units[J].Journal of Iron and Steel Research,2021,33(9):891-900.
【11】王玲,向军淮,张洪华,等.3种不同Cr含量Co-20Re-Cr合金在1000和1100℃的高温氧化行为[J].中国腐蚀与防护学报,2019,39(1):83-88. WANG L,XIANG J H,ZHANG H H,et al.High temperature oxidation behavior of three Co-20Re-xCr alloys in 3.04×10-5 Pa oxygen at 1000 and 1100℃[J].Journal of Chinese Society for Corrosion and Protection,2019,39(1):83-88.
【12】BIRKS N,MEIER G H,PETTIT F S.金属高温氧化导论[M].北京:高等教育出版社,2010. BIRKS N,MEIER G H,PETTIT F S.Introduction to the high-temperature oxidation of metals[M].Beijing:Higher Education Press,2010.
【13】张骏,蔡文河,杜双明,等.喷丸奥氏体耐热钢抗蒸汽氧化性的研究与使用现状[J].表面技术,2020,49(9):133-140. ZHANG J,CAI W H,DU S M,et al.Research and application status of steam oxidation resistance of shot peening austenitic heat-resistant steel[J].Surface Technology,2020,49(9):133-140.
【14】PARK D J,KIM H G,PARK J Y,et al.A study of the oxidation of FeCrAl alloy in pressurized water and high-temperature steam environment[J].Corrosion Science,2015,94:459-465.
【15】王志民,刘光明,吴世强,等.热处理对S30432喷丸不锈钢抗高温水蒸汽氧化性能的影响[J].材料热处理学报,2019,40(2):124-132. WANG Z M,LIU G M,WU S Q,et al.Effect of heat treatment on high temperature steam oxidation resistance of shot blasted S30432 stainless steel[J].Transactions of Materials and Heat Treatment,2019,40(2):124-132.
【16】王锐坤,郑志军,高岩.表面喷丸工艺对Super304H奥氏体耐热钢组织与性能的影响[J].中南大学学报(自然科学版),2017,48(4):903-909. WANG R K,ZHENG Z J,GAO Y.Effect of surface shot peening on microstructure and properties of Super304H austenitic heat-resistant steels[J].Journal of Central South University (Science and Technology),2017,48(4):903-909.
【17】杨首恩,杨华春,刘盛波.喷丸处理对18-8型奥氏体耐热钢抗蒸汽氧化性能的影响[J].发电设备,2019,33(3):189-192. YANG S E,YANG H C,LIU S B.Influence of shot peening on steam oxidation resistance of 18-8 type austenitic heat-resistant steels[J].Power Equipment,2019,33(3):189-192.
【18】崔忠圻,覃耀春.金属学与热处理[M].2版.北京:机械工业出版社,2011. CUI Z Q,QIN Y C.Metallurgy and heat treatment[M].2nd ed.Beijing:China Machine Press,2011.
【19】尹泽华,周永莉,鲁金涛,等.700℃下Nb对HR3C奥氏体耐热钢蒸汽氧化行为的影响[J].表面技术,2020,49(12):267-273. YIN Z H,ZHOU Y L,LU J T,et al.Effect on steam oxidation behavior of HR3C austenitic steels at 700℃[J].Surface Technology,2020,49(12):267-273.
【20】胡赓祥,蔡珣,戎咏华.材料科学基础[M].3版.上海:上海交通大学出版社,2011. HU G X,CAI X,RONG Y H.Fundamentals of materials science[M].3rd ed.Shanghai:Shanghai Jiao Tong University Press,2011.
【21】张新宇,王磊,王尧,等.静电场处理对GH4169合金中Fe、Cr元素扩散行为的影响[J].钢铁研究学报,2011,23(增刊2):146-149. ZHANG X Y,WANG L,WANG Y,et al.Effect of electrostatic-field treatment on the diffusion behaveors of Fe and Cr in GH4169 superalloy[J].Journal of Iron and Steel Research,2011,23(S2):146-149.
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