海泡石在环氧树脂复合涂层中的研究进展
Research Progress of Sepiolite in Epoxy Resin Composite Coating
摘 要
海泡石是一种无毒无害的天然黏土矿物,具有比表面积大、吸附性好和较强的耐酸碱腐蚀性能。介绍了海泡石的微观结构和化学组成,阐述了目前比较典型的几种海泡石改性环氧树脂复合涂层的制备方法和性能,并总结了复合涂层的防腐蚀机理,展望了海泡石在环氧复合涂层领域的发展。
环氧树脂
复合涂层
防腐蚀性能
sepiolite
epoxy resin
composite coating
anti-corrosion property
Abstract
Sepiolite is a non-toxic and harmless natural clay mineral with large specific surface area, good adsorption and strong acid and alkali corrosion resistance. The microstructure and chemical composition of sepiolite are introduced, the preparation methods and properties of several typical sepiolite modified epoxy resin composite coatings are described, the anti-corrosion mechanism of the composite coatings is summarized, and the development of sepiolite in the field of epoxy composite coatings is proposed.
中图分类号 TG174 DOI 10.11973/fsyfh-202309010
所属栏目 专论
基金项目 国家自然科学基金项目(51574045); 江苏省油气储运技术重点实验室开放课题(CDYQCY202101); 常州市科技计划项目(CE20160069); 常州市应用基础研究项目(CJ20200085)
收稿日期 2021/12/10
修改稿日期
网络出版日期
作者单位点击查看
联系人作者赵书华(zsh@cczu.edu.cn)
引用该论文: ZHAO Shuhua,LI Jiabo,DUAN Yunfei,REN Gui,RAO Yongchao,LU Xiaodie. Research Progress of Sepiolite in Epoxy Resin Composite Coating[J]. Corrosion & Protection, 2023, 44(9): 65
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【2】MO M T,ZHAO W J,CHEN Z F,et al. Excellent tribological and anti-corrosion performance of polyurethane composite coatings reinforced with functionalized graphene and graphene oxide nanosheets[J]. RSC Advances,2015,5(70):56486-56497.
【3】王立超. 埋地金属管道腐蚀防护研究[J]. 全面腐蚀控制,2021,35(5):98-100.
【4】赵书华,陈宏,王树立,等. 石墨烯对硅酸盐富锌防腐蚀涂层性能的影响[J]. 腐蚀与防护,2018,39(12):930-935,940.
【5】WANG F,LIANG J S,TANG Q G,et al. Preparation and far infrared emission properties of natural sepiolite nanofibers[J]. Journal of Nanoscience and Nanotechnology,2010,10(3):2017-2022.
【6】熊海龙. 改性海泡石——纳米钛/环氧树脂复合涂层材料的制备及防腐性能研究[D]. 湘潭:湘潭大学,2020.
【7】AFIFY A S,HASSAN M,PIUMETTI M,et al. Elaboration and characterization of modified sepiolites and their humidity sensing features for environmental monitoring[J]. Applied Clay Science,2015,115:165-173.
【8】SNCHEZ DEL RO M,MARTINETTO P,REYES-VALERIO C,et al. Synthesis and acid resistance of maya blue pigment[J]. Archaeometry,2006,48(1):115-130.
【9】MAISANABA S,PICHARDO S,PUERTO M,et al. Toxicological evaluation of clay minerals and derived nanocomposites:a review[J]. Environmental Research,2015,138:233-254.
【10】刘腾飞. 湖南浏阳永和海泡石矿床地质及开发利用现状[J]. 冶金地质动态,1995(5):9-11.
【11】周永兴. 从专利变化看国内海泡石应用趋势[J]. 中国非金属矿工业导刊,2020(6):1-5,53.
【12】李虹. 海泡石资源的开发及利用[J]. 国外建材科技,1996,17(2):3-8.
【13】邓庚凤,罗来涛,陈昭平,等. 海泡石的性能及其应用[J]. 江西科学,1999,17(1):59-66.
【14】王雪琴,李珍,杨友生. 海泡石的改性及应用研究现状[J]. 中国非金属矿工业导刊,2003(3):11-14.
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【20】XIONG H L,QI F G,ZHAO N E,et al. Effect of organically modified sepiolite as inorganic nanofiller on the anti-corrosion resistance of epoxy coating[J]. Materials Letters,2020,260:126941.
【21】YUAN S A,ZHAO X A,JIN Z Q,et al. Fabrication of an environment-friendly epoxy coating with flexible superhydrophobicity and anti-corrosion performance[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,633:127545.
【22】YEH J M,LIOU S J,LIN C Y,et al. Anticorrosively enhanced PMMA-clay nanocomposite materials with quaternary alkylphosphonium salt as an intercalating agent[J]. Chemistry of Materials,2002,14(1):154-161.
【23】HENRIQUES R R,SOARES B G. Sepiolite modified with phosphonium ionic liquids as anticorrosive pigment for epoxy coatings[J]. Applied Clay Science,2021,200:105890.
【24】KNOPP D,TANG D P,NIESSNER R. Review:Bioanalytical applications of biomolecule-functionalized nanometer-sized doped silica particles[J]. Analytica Chimica Acta,2009,647(1):14-30.
【25】YOON D,JANG J,CHEONG I. Synthesis of cationic polyacrylamide/silica nanocomposites from inverse emulsion polymerization and their flocculation property for papermaking[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2012,411:18-23.
【26】王盛鑫,梁红玉,张连红. 海泡石纤维/SiO2复合材料的制备、表征及性能[J]. 涂料工业,2016,46(10):6-10,16.
【27】李跃文,陈如意,胡远军,等. 聚丙烯/纳米钛合金复合材料力学性能的研究[J]. 塑料工业,2006,34(11):39-41.
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