无间隙原子钢在退火过程中的再结晶行为及其对耐腐蚀性能的影响
Recrystallization Behavior During Annealing and Its Effect onCorrosion Resistance of Interstitial Free Steel
摘 要
对一种无间隙原子（IF）钢进行了不同温度（630~780℃）和时间（0~140 min）的退火处理，对退火后该钢的显微组织进行观察，研究了其再结晶行为并建立再结晶动力学模型，获得了不同退火温度下的再结晶激活能，研究了再结晶程度对耐腐蚀性能的影响。结果表明：退火温度越高，再结晶过程所需时间越短，再结晶动力学参数n值越大，630~670℃退火时的再结晶激活能为221.7 kJ·mol-1，而750~780℃退火时的再结晶激活能为109.2 kJ·mol-1；当再结晶体积分数由18%增加至82%时，试验钢在质量分数3.5% NaCl溶液中的自腐蚀电位负移，自腐蚀电流密度增大，而当再结晶体积分数增大至97%时，自腐蚀电位正移，自腐蚀电流密度减小，随着再结晶程度的提高，试验钢的耐腐蚀性能先减弱后增强。
再结晶动力学
再结晶行为
耐腐蚀性能
interstitial free steel
recrystallization kinetics
recrystallization behavior
corrosion resistance
Abstract
A interstitial free (IF) steel was annealed at different temperatures (630-780℃) for different time intervals (0-140 min). The microstructure of the annealed steel was observed. The recrystallization behavior was studied, and the recrystallization dynamic model was established. The recrystallization activation energy at different annealing temperatures was obtained. The influence of recrystallization degree on the corrosion resistance was studied. The results show that the higher the annealing temperature, the shorter the time required for the recrystallization, and the larger the recrystallization kinetics parameter n value. The recrystallization activation energy was 221.7 kJ·mol-1 when annealing at 630-670℃, and was 109.2 kJ·mol-1 when annealing at 750-780℃. When the volume fraction of recrystallization increased from 18% to 82%, the free-corrosion potential of the test steel in 3.5wt% NaCl solution shifted negatively and the free-corrosion current density increased. When the volume fraction of recrystallization increased to 97%, the free-corrosion potential shifted positively and the free-corrosion current density decreased. With increasing degree of recrystallization, the corrosion resistance of the test steel was first weakened and then strengthened.
中图分类号 TG156.21 DOI 10.11973/jxgccl202309001
所属栏目 试验研究
基金项目 陕西省2023年自然科学基础研究计划项目（2023-JC-QN-0462）
收稿日期 2022/7/16
修改稿日期 2023/7/26
网络出版日期
作者单位点击查看
备注孟祥兆(1999-),男,河北沧州人,硕士研究生
引用该论文: MENG Xiangzhao,YUAN Xiaoyun,YANG Pengkai. Recrystallization Behavior During Annealing and Its Effect onCorrosion Resistance of Interstitial Free Steel[J]. Materials for mechancial engineering, 2023, 47(9): 1～5
孟祥兆,袁晓云,杨鹏凯. 无间隙原子钢在退火过程中的再结晶行为及其对耐腐蚀性能的影响[J]. 机械工程材料, 2023, 47(9): 1～5
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【2】SINGH A K.Effect of rolling temperature on the microstructure and mechanical properties of interstitial free steel[J].International Journal of Microstructure and Materials Properties, 2016, 11(6):453.
【3】ZHANG P, GUO Y H, WANG Z D, et al.Texture evolution in ferritic rolled Ti-IF steel during cold rolling[J].Journal of Iron and Steel Research, International, 2010, 17(1):44-58.
【4】HE Q Y, JIANG X J, CAI P Z, et al.Effect of annealing on microstructure and corrosion behavior of interstitial free steel[J].Materials, 2021, 15(1):24.
【5】GALINDO-NAVA E I, RIVERA-DÍAZ-DEL-CASTILLO P E J.Grain size evolution during discontinuous dynamic recrystallization[J].Scripta Materialia, 2014, 72/73:1-4.
【6】YANG X Y, JI Z S, MIURA H, et al.Dynamic recrystallization and texture development during hot deformation of magnesium alloy AZ31[J].Transactions of Nonferrous Metals Society of China, 2009, 19(1):55-60.
【7】HASHIMOTO N, YOSHINAGA N, SENUMA T.Recrystallization and related phenomena.texture evolution of IF steel due to recrystallization[J].ISIJ International, 1998, 38(6):617-624.
【8】ELGOYHEN C, DE PAEPE A, LAQUERBE L, et al.Development of dual phase and multiphase high strength steels by using a new cooling technology:The Howaq-twice process[J].Steel Research International, 2005, 76(7):532-538.
【9】RAJI N A, OLUWOLE O O.Recrystallization kinetics and microstructure evolution of annealed cold-drawn low-carbon steel[J].Journal of Crystallization Process and Technology, 2013, 3(4):163-169.
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【14】HE T, BAI Y, LIU X T, et al.Effect of Sn micro-alloying on recrystallization nucleation and growth processes of ferritic stainless steels[J].Metals and Materials International, 2018, 24(4):789-801.
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【18】赵立华, 张艳姝, 吴桂芳.GH4169高温合金的静态再结晶动力学[J].材料热处理学报, 2015, 36(5):217-222. ZHAO L H, ZHANG Y S, WU G F.Static recrystallization dynamic behavior of GH4169 superalloy[J].Transactions of Materials and Heat Treatment, 2015, 36(5):217-222.
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【22】CHAO H Y, SUN H F, CHEN W Z, et al.Static recrystallization kinetics of a heavily cold drawn AZ31 magnesium alloy under annealing treatment[J].Materials Characterization, 2011, 62(3):312-320.
【23】李玉倩, 毛卫民, 杨平.微合金元素对冷轧取向电工钢再结晶行为的影响[J].材料热处理学报, 2011, 32(12):55-60. LI Y Q, MAO W M, YANG P.Influences of micro-alloying element on recrystallization behavior of cold-rolled grain oriented electrical steels[J].Transactions of Materials and Heat Treatment, 2011, 32(12):55-60.
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【26】莫建新, 潘清林, 李建湘, 等.一种新型Al-Mn-Mg合金管材退火工艺的研究[J].材料工程, 2011, 39(7):26-30. MO J X, PAN Q L, LI J X, et al.Research on annealing institution of the new Al-Mn-Mg alloy pipe[J].Journal of Materials Engineering, 2011, 39(7):26-30.
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