CeO2添加量对激光熔覆TiB2-TiC/Ni复合涂层组织和性能的影响
Effect of CeO2 Addition Amount on Microstructure and Properties ofLaser Cladded TiB2-TiC/Ni Composite Coating
摘 要
利用激光熔覆技术在TC4钛合金表面制备了添加质量分数1.0%，1.5%，2.0% CeO2的TiB2-TiC/Ni复合涂层，研究了复合涂层的物相组成、显微组织和硬度，讨论了搭接率（30%，40%，50%）对最佳CeO2含量条件下复合涂层试样摩擦磨损性能的影响。结果表明：复合涂层均由TiB2、TiB、α-Ti、TiC、Ni3Ti、Cr23C6、Ti2Ni、Cr3C2、γ-Ni等相组成；添加质量分数1.5% CeO2复合涂层的组织最为均匀致密，细化效果明显；随着CeO2添加量的增加，复合涂层的硬度先增后降，添加质量分数1.5% CeO2复合涂层的硬度最高，约为1 015 HV。CeO2的最佳添加质量分数为1.5%，在此条件下随着搭接率的增加，试样的磨损质量损失先减小后增大，当搭接率为40%时，磨损质量损失最小，磨损机理为磨粒磨损。
激光熔覆
TiB2-TiC/Ni复合涂层
组织
硬度
摩擦磨损性能
CeO2
laser cladding
TiB2-TiC/Ni composite coating
microstructure
hardness
friction and wear property
Abstract
The TiB2-TiC/Ni composite coating added with 1wt%, 1.5wt% and 2wt% CeO2 was prepared on the surface of TC4 titanium alloy by laser cladding technique. The phase composition, microstructure, and hardness of the composite coating were studied, and the effect of lapping rate (30%, 40%, 50%) on the friction and wear properties of the composite coating sample under the optimal CeO2 content condition was discussed. The results show that the composite coating consisted of TiB2, TiB, α-Ti, TiC, Ni3Ti, Cr23C6, Ti2Ni, Cr3C2 and γ-Ni phases. The microstructure of the composite coating added with 1.5wt% CeO2 was the most uniform and dense, and the refinement effect was obvious. With the increase of CeO2 addition amount, the hardness of the composite coating increased first and then decreased. The hardness of the composite coating added with 1.5wt% CeO2 was the highest of about 1 015 HV. The optimal mass fraction of CeO2 was 1.5%; under this condition, the wear mass loss of the sample decreased first and then increased with the increase of lapping rate. When the lapping rate was 40%, the wear mass loss was the smallest, and the wear mechanism was abrasive wear.
中图分类号 TG174.4 DOI 10.11973/jxgccl202309014
所属栏目 专题报道（金属材料表面处理）
基金项目 国家自然科学基金资助项目（52161017，51865055）
收稿日期 2022/7/4
修改稿日期 2023/7/12
网络出版日期
作者单位点击查看
备注田鹿岩(1996-),男,河南周口人,硕士研究生
引用该论文: TIAN Luyan,LI Xinmei,LIU Weibin. Effect of CeO2 Addition Amount on Microstructure and Properties ofLaser Cladded TiB2-TiC/Ni Composite Coating[J]. Materials for mechancial engineering, 2023, 47(9): 82～86
田鹿岩,李新梅,刘伟斌. CeO2添加量对激光熔覆TiB2-TiC/Ni复合涂层组织和性能的影响[J]. 机械工程材料, 2023, 47(9): 82～86
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参考文献
【1】SONG W W, FENG C, ZHU L J, et al.Progress of laser cladding wear resistant coating on titanium alloy surface:A review[J].Materials Science Forum, 2021, 1035:521-527.
【2】张佳虹, 孙荣禄.钛合金表面激光熔覆的研究进展[J].材料导报, 2014, 28(11):89-93. ZHANG J H, SUN R L.Research progress of laser cladding on surface of titanium alloy[J].Materials Review, 2014, 28(11):89-93.
【3】许长庆, 宋长柏, 张宏波, 等.化学气相沉积技术对碳化硼硬质颗粒表面改性及在电沉积技术中的应用[J].河北工业大学学报, 2001, 30(3):82-85. XU C Q, SONG C B, ZHANG H B, et al.Improve the wetting character of boron carbon powders by chemical vapor deposition and electroplating routes[J].Journal of Hebei University of Technology, 2001, 30(3):82-85.
【4】张超, 邵黎军, 毛向阳.Ni-C离子注入316L不锈钢表面硬度与耐蚀性能的研究[J].现代交通与冶金材料, 2022, 2(2):76-83. ZHANG C, SHAO L J, MAO X Y.Study on surface hardness and corrosion resistance of Ni-C ion implanted 316L stainless steel[J].Modern Transportation and Metallurgical Materials, 2022, 2(2):76-83.
【5】林基辉, 温亚辉, 范文博, 等.钛合金表面激光改性技术研究进展[J].金属热处理, 2022, 47(3):215-221. LIN J H, WEN Y H, FAN W B, et al.Research progress of laser modification technology for titanium alloy surface[J].Heat Treatment of Metals, 2022, 47(3):215-221.
【6】金玉花, 邢逸初, 周子正, 等.喷丸改性对7050铝合金FSW接头性能的影响[J].材料导报, 2023, 37(10):169-173. JIN Y H, XING Y C, ZHOU Z Z, et al.Effect of shot peening on properties of 7050 aluminum alloy FSW joint[J].Materials Reports, 2023, 37(10):169-173.
【7】何利舰, 张小农.钛及钛合金的表面处理技术新进展[J].上海金属, 2005, 27(3):39-45. HE L J, ZHANG X N.Recent progress on surface treatment technologies of titanium and titanium alloys[J].Shanghai Metals, 2005, 27(3):39-45.
【8】冯淑容, 张述泉, 王华明.钛合金激光熔覆硬质颗粒增强金属间化合物复合涂层耐磨性[J].中国激光, 2012, 39(2):0203002. FENG S R, ZHANG S Q, WANG H M.Wear resistance of laser clad hard particles reinforced intermetallic composite coating on TA15 alloy[J].Chinese Journal of Lasers, 2012, 39(2):0203002.
【9】徐欢欢, 林晨, 刘佳, 等.CeO2加入含量对激光熔覆WC增强镍基合金涂层组织与性能的影响[J].机械工程材料, 2021, 45(7):27-34. XU H H, LIN C, LIU J, et al.Effect of CeO2 adding content on microstructure and properties of laser cladding WC reinforced nickel-based alloy coating[J].Materials for Mechanical Engineering, 2021, 45(7):27-34.
【10】侯晓云, 庄怀风, 柏明磊, 等.CeO2对Ti811表面钛基激光熔覆层微观组织及性能的影响[J].热加工工艺, 2019, 48(14):84-87. HOU X Y, ZHUANG H F, BAI M L, et al.Effect of CeO2 on microstructure and properties of Ti-based laser cladding layer on Ti811 surface[J].Hot Working Technology, 2019, 48(14):84-87.
【11】马永, 朱红梅, 孙楚光, 等.TC4钛合金表面激光熔覆掺Y2O3复合涂层的显微组织和性能[J].表面技术, 2017, 46(6):238-243. MA Y, ZHU H M, SUN C G, et al.Microstructure and properties of Y2O3-doped laser cladded composite coating on TC4 titanium alloy[J].Surface Technology, 2017, 46(6):238-243.
【12】张天刚, 张倩, 庄怀风, 等.TiC-TiB2复合相钛基稀土激光熔覆层组织与性能[J].航空学报, 2021, 42(7):424139. ZHANG T G, ZHANG Q, ZHUANG H F, et al.Microstructure and properties of TiC-TiB2 composite phase Ti-based rare earth laser cladding layers[J].Acta Aeronautica et Astronautica Sinica, 2021, 42(7):424139.
【13】王成磊, 高原, 张光耀.6061铝合金表面激光熔覆稀土CeO2+Ni60组织及摩擦磨损性能[J].焊接学报, 2015, 36(7):13-16. WANG C L, GAO Y, ZHANG G Y.Microstructure and wear resistanced of deposited rare earth CeO2+Ni60 alloys coatings on 6061 Al alloys by laser cladding[J].Transactions of the China Welding Institution, 2015, 36(7):13-16.
【14】侯南, 王佳峰, 张新杰.扫描速度对激光熔覆TiB2-TiC/Ni复合涂层组织与性能的影响[J].世界有色金属, 2016(13):69-70. HOU N, WANG J F, ZHANG X J.Effects of scanning speed on microstructures and properties of laser cladding TiB2-TiC-reinforced nickel matrix composite coatings[J].World Nonferrous Metals, 2016(13):69-70.
【15】孙荣禄, 杨贤金.激光熔覆原位合成TiC-TiB2/Ni基金属陶瓷涂层的组织和摩擦磨损性能[J].硅酸盐学报, 2003, 31(12):1221-1224. SUN R L, YANG X J.Microstructure, friction and wear properties of in situ synthesized TiC-TiB2/Ni-based metallic ceramic coating by laser cladding[J].Journal of the Chinese Ceramic Society, 2003, 31(12):1221-1224.
【16】马运哲, 董世运, 徐滨士, 等.CeO2对激光熔覆Ni基合金涂层组织与性能的影响[J].中国表面工程, 2006, 19(1):7-11. MA Y Z, DONG S Y, XU B S, et al.Effect of CeO2 on microstructure and performance of laser cladding Ni-based alloy coatings[J].China Surface Engineering, 2006, 19(1):7-11.
【17】张天刚, 庄怀风, 肖海强, 等.稀土对Ti基激光熔覆层组织与摩擦磨损性能的影响[J].中国激光, 2019, 46(9):0903001. ZHANG T G, ZHUANG H F, XIAO H Q, et al.Effect of rare earth on microstructure and friction and wear properties of Ti-based laser cladding layer[J].Chinese Journal of Lasers, 2019, 46(9):0903001.
【18】刘頔, 李敏, 黄坚, 等.CeO2含量对激光熔覆TiB/TiN涂层显微组织和性能的影响[J].中国激光, 2017, 44(12):123-129. LIU D, LI M, HUANG J, et al.Effect of CeO2 content on microstructures and properties of TiB/TiN coating by laser cladding[J].Chinese Journal of Lasers, 2017, 44(12):123-129.
【19】蔡春波.激光熔覆再制造涂层残余应力研究[D].东营:中国石油大学(华东), 2017. CAI C B.Study on residual stress of laser cladding remanufactured coating[D].Dongying:China University of Petroleum (Huadong), 2017.
【20】韩立影, 张雪, 王亚男, 等.激光功率对Ni基WC熔覆层组织的影响[J].金属热处理, 2014, 39(9):63-66. HAN L Y, ZHANG X, WANG Y N, et al.Influence of laser power on microstructure of Ni-based WC clad layer[J].Heat Treatment of Metals, 2014, 39(9):63-66.
【2】张佳虹, 孙荣禄.钛合金表面激光熔覆的研究进展[J].材料导报, 2014, 28(11):89-93. ZHANG J H, SUN R L.Research progress of laser cladding on surface of titanium alloy[J].Materials Review, 2014, 28(11):89-93.
【3】许长庆, 宋长柏, 张宏波, 等.化学气相沉积技术对碳化硼硬质颗粒表面改性及在电沉积技术中的应用[J].河北工业大学学报, 2001, 30(3):82-85. XU C Q, SONG C B, ZHANG H B, et al.Improve the wetting character of boron carbon powders by chemical vapor deposition and electroplating routes[J].Journal of Hebei University of Technology, 2001, 30(3):82-85.
【4】张超, 邵黎军, 毛向阳.Ni-C离子注入316L不锈钢表面硬度与耐蚀性能的研究[J].现代交通与冶金材料, 2022, 2(2):76-83. ZHANG C, SHAO L J, MAO X Y.Study on surface hardness and corrosion resistance of Ni-C ion implanted 316L stainless steel[J].Modern Transportation and Metallurgical Materials, 2022, 2(2):76-83.
【5】林基辉, 温亚辉, 范文博, 等.钛合金表面激光改性技术研究进展[J].金属热处理, 2022, 47(3):215-221. LIN J H, WEN Y H, FAN W B, et al.Research progress of laser modification technology for titanium alloy surface[J].Heat Treatment of Metals, 2022, 47(3):215-221.
【6】金玉花, 邢逸初, 周子正, 等.喷丸改性对7050铝合金FSW接头性能的影响[J].材料导报, 2023, 37(10):169-173. JIN Y H, XING Y C, ZHOU Z Z, et al.Effect of shot peening on properties of 7050 aluminum alloy FSW joint[J].Materials Reports, 2023, 37(10):169-173.
【7】何利舰, 张小农.钛及钛合金的表面处理技术新进展[J].上海金属, 2005, 27(3):39-45. HE L J, ZHANG X N.Recent progress on surface treatment technologies of titanium and titanium alloys[J].Shanghai Metals, 2005, 27(3):39-45.
【8】冯淑容, 张述泉, 王华明.钛合金激光熔覆硬质颗粒增强金属间化合物复合涂层耐磨性[J].中国激光, 2012, 39(2):0203002. FENG S R, ZHANG S Q, WANG H M.Wear resistance of laser clad hard particles reinforced intermetallic composite coating on TA15 alloy[J].Chinese Journal of Lasers, 2012, 39(2):0203002.
【9】徐欢欢, 林晨, 刘佳, 等.CeO2加入含量对激光熔覆WC增强镍基合金涂层组织与性能的影响[J].机械工程材料, 2021, 45(7):27-34. XU H H, LIN C, LIU J, et al.Effect of CeO2 adding content on microstructure and properties of laser cladding WC reinforced nickel-based alloy coating[J].Materials for Mechanical Engineering, 2021, 45(7):27-34.
【10】侯晓云, 庄怀风, 柏明磊, 等.CeO2对Ti811表面钛基激光熔覆层微观组织及性能的影响[J].热加工工艺, 2019, 48(14):84-87. HOU X Y, ZHUANG H F, BAI M L, et al.Effect of CeO2 on microstructure and properties of Ti-based laser cladding layer on Ti811 surface[J].Hot Working Technology, 2019, 48(14):84-87.
【11】马永, 朱红梅, 孙楚光, 等.TC4钛合金表面激光熔覆掺Y2O3复合涂层的显微组织和性能[J].表面技术, 2017, 46(6):238-243. MA Y, ZHU H M, SUN C G, et al.Microstructure and properties of Y2O3-doped laser cladded composite coating on TC4 titanium alloy[J].Surface Technology, 2017, 46(6):238-243.
【12】张天刚, 张倩, 庄怀风, 等.TiC-TiB2复合相钛基稀土激光熔覆层组织与性能[J].航空学报, 2021, 42(7):424139. ZHANG T G, ZHANG Q, ZHUANG H F, et al.Microstructure and properties of TiC-TiB2 composite phase Ti-based rare earth laser cladding layers[J].Acta Aeronautica et Astronautica Sinica, 2021, 42(7):424139.
【13】王成磊, 高原, 张光耀.6061铝合金表面激光熔覆稀土CeO2+Ni60组织及摩擦磨损性能[J].焊接学报, 2015, 36(7):13-16. WANG C L, GAO Y, ZHANG G Y.Microstructure and wear resistanced of deposited rare earth CeO2+Ni60 alloys coatings on 6061 Al alloys by laser cladding[J].Transactions of the China Welding Institution, 2015, 36(7):13-16.
【14】侯南, 王佳峰, 张新杰.扫描速度对激光熔覆TiB2-TiC/Ni复合涂层组织与性能的影响[J].世界有色金属, 2016(13):69-70. HOU N, WANG J F, ZHANG X J.Effects of scanning speed on microstructures and properties of laser cladding TiB2-TiC-reinforced nickel matrix composite coatings[J].World Nonferrous Metals, 2016(13):69-70.
【15】孙荣禄, 杨贤金.激光熔覆原位合成TiC-TiB2/Ni基金属陶瓷涂层的组织和摩擦磨损性能[J].硅酸盐学报, 2003, 31(12):1221-1224. SUN R L, YANG X J.Microstructure, friction and wear properties of in situ synthesized TiC-TiB2/Ni-based metallic ceramic coating by laser cladding[J].Journal of the Chinese Ceramic Society, 2003, 31(12):1221-1224.
【16】马运哲, 董世运, 徐滨士, 等.CeO2对激光熔覆Ni基合金涂层组织与性能的影响[J].中国表面工程, 2006, 19(1):7-11. MA Y Z, DONG S Y, XU B S, et al.Effect of CeO2 on microstructure and performance of laser cladding Ni-based alloy coatings[J].China Surface Engineering, 2006, 19(1):7-11.
【17】张天刚, 庄怀风, 肖海强, 等.稀土对Ti基激光熔覆层组织与摩擦磨损性能的影响[J].中国激光, 2019, 46(9):0903001. ZHANG T G, ZHUANG H F, XIAO H Q, et al.Effect of rare earth on microstructure and friction and wear properties of Ti-based laser cladding layer[J].Chinese Journal of Lasers, 2019, 46(9):0903001.
【18】刘頔, 李敏, 黄坚, 等.CeO2含量对激光熔覆TiB/TiN涂层显微组织和性能的影响[J].中国激光, 2017, 44(12):123-129. LIU D, LI M, HUANG J, et al.Effect of CeO2 content on microstructures and properties of TiB/TiN coating by laser cladding[J].Chinese Journal of Lasers, 2017, 44(12):123-129.
【19】蔡春波.激光熔覆再制造涂层残余应力研究[D].东营:中国石油大学(华东), 2017. CAI C B.Study on residual stress of laser cladding remanufactured coating[D].Dongying:China University of Petroleum (Huadong), 2017.
【20】韩立影, 张雪, 王亚男, 等.激光功率对Ni基WC熔覆层组织的影响[J].金属热处理, 2014, 39(9):63-66. HAN L Y, ZHANG X, WANG Y N, et al.Influence of laser power on microstructure of Ni-based WC clad layer[J].Heat Treatment of Metals, 2014, 39(9):63-66.
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