Sb-SnO2掺杂量对Al2O3-13% TiO2复合陶瓷涂层抗结垢性能的影响
Effect of Sb-SnO2 Doping Amount on Anti-scaling Performance ofAl2O3-13%TiO2 Composite Ceramic Coating
摘 要
以Al2O3-13% TiO2（AT13）和纳米掺锑SnO2（Sb-SnO2）粉体为原料，采用等离子喷涂工艺在4145H合金钢基体表面制备了掺杂不同质量分数（0~16%） Sb-SnO2的AT13复合陶瓷涂层，研究了复合陶瓷涂层的表面性能、微观形貌、显微硬度、结合强度以及在地层采出水中的抗结垢性能，并与电镀铬层和未处理4145H合金钢进行对比。结果表明：与电镀铬层和未处理4145H合金钢相比，复合陶瓷涂层的水接触角较大，表面能较低，随着Sb-SnO2掺杂量的增加，水接触角基本呈先增大后减小的趋势，表面能先减小后增大；复合陶瓷涂层具有大量的孔隙；随着Sb-SnO2掺杂量的增加，硬度整体呈降低趋势，但均高于4145H合金钢和电镀铬层，单位面积结垢质量先减小后增大；掺杂质量分数10% Sb-SnO2的复合陶瓷涂层具有最大的水接触角、最小的表面能、最小的单位面积结垢质量，平均结合强度为25.7 MPa。
Al2O3-13%TiO2复合陶瓷涂层
抗结垢性能
nano-Sb-SnO2
Al2O3-13%TiO2 composite ceramic coating
anti-scaling property
Abstract
With Al2O3-13%TiO2 (AT13) and nano antimony tin oxide (Sb-SnO2) powders as raw materials, AT13 composite ceramic coatings doped with different mass fractions (0-16%) of Sb-SnO2 were prepared on surface of 4145H alloy steel substrate by plasma spraying process, and the surface performance, micromorphology, microhardness, bond strength, and anti-scaling properties in formation produced water of the composite ceramic coatings were investigated and compared with those of the chromium-electrodeposited layer and untreated 4145H alloy steel. The results show that the water contact angle of composite ceramic coating was larger than those of chromium-electrodeposited layer and untreated 4145H alloy steel, and the surface energy was lower. With increasing Sb-SnO2 doping amount, the water contact angle basically increased first and then decreased, and the surface energy decreased first and then increased. The composite ceramic coating had a large number of pores. With increasing Sb-SnO2 doping amount, the hardness had an overall decreasing trend, but was higher than those of 4145H alloy steel and chromium-electrodeposited layer. With increasing Sb-SnO2 doping amount, and the fouling mass per unit area decreased first and then increased. The composite ceramic coating doped with 10wt%Sb-SnO2 had the largest water contact angle, the smallest surface energy, and the minimum fouling mass per unit area; the average bond strength was 25.7 MPa.
中图分类号 TG147 DOI 10.11973/jxgccl202309017
所属栏目 专题报道（金属材料表面处理）
基金项目
收稿日期 2022/5/10
修改稿日期 2023/7/5
网络出版日期
作者单位点击查看
备注左凯(1979-),男,河北保定人,高级工程师,博士
引用该论文: ZUO Kai,JU Shaodong,ZHANG Bin,HONG Xiumei. Effect of Sb-SnO2 Doping Amount on Anti-scaling Performance ofAl2O3-13%TiO2 Composite Ceramic Coating[J]. Materials for mechancial engineering, 2023, 47(9): 101～105
左凯,鞠少栋,张斌,洪秀玫. Sb-SnO2掺杂量对Al2O3-13% TiO2复合陶瓷涂层抗结垢性能的影响[J]. 机械工程材料, 2023, 47(9): 101～105
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参考文献
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