电磁水处理的结垢和腐蚀控制研究进展
Research Progress on Scaling and Corrosion Control of Electromagnetic Water Treatment
摘 要
电磁水处理是一种绿色的水处理技术,可应用于工业冷却水系统,通过电磁场对水的物理化学性质进行改变来达到热交换表面的阻垢和对金属的缓蚀。综述了近年来国内外学者的相关研究动态,分析了电磁场对水溶液物理化学特性(如氢键、Zeta 电势、电导率、pH)的影响,探讨了电磁处理对水溶液中成垢物质的阻垢作用和阻垢机理,分析了电磁处理对水中金属耐蚀性能的影响及机制,并对电磁水处理的应用前景进行了展望。
阻垢作用
阻垢机理
腐蚀
electromagnetic water treatment
scale inhibition
scale inhibition mechanism
corrosion
Abstract
Electromagnetic water treatment is a green water treatment technique that can be applied to industrial cooling water systems to achieve scale inhibition on heat exchange surfaces and corrosion inhibition on metals by changing the physicochemical properties of water through electromagnetic fields. The relevant research developments in recent years were reviewed. The influence of electromagnetic fields on the physicochemical properties such as hydrogen bonds, Zeta potential, conductivity, and pH of water solutions was analyzed. The scale inhibition effect and scale inhibition mechanism of electromagnetic treatment on scale-forming substances in water solution were discussed. The effect and mechanism of electromagnetic treatment on corrosion resistance of metals in water were analyzed. The application prospect of electromagnetic water treatment was prospected.
中图分类号 TG174 DOI 10.11973/fsyfh-202310008
所属栏目 专论
基金项目 上海市自然科学基金(20ZR1421500);上海市科委项目(19DZ2271100)
收稿日期 2021/12/22
修改稿日期
网络出版日期
作者单位点击查看
引用该论文: LI Ji,GE Honghua,ZHANG Jialin,YU Huaqiang,LIU Jiaman. Research Progress on Scaling and Corrosion Control of Electromagnetic Water Treatment[J]. Corrosion & Protection, 2023, 44(10): 42
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参考文献
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【8】JUNG D H,YANG J H,JHON M S. The effect of an external electric field on the structure of liquid water using molecular dynamics simulations[J]. Chemical Physics, 1999,244(2):331-337.
【9】SEYFI A, AFZALZADEH R, HAJNOROUZI A. Increase in water evaporation rate with increase in static magnetic field perpendicular to water-air interface[J]. Chemical Engineering and Processing-Process Intensification, 2017,120(1):195-200.
【10】JHA P K, XANTHAKIS E, JURY V, et al. An overview on magnetic field and electric field interactions with ice crystallisation application in the case of frozen food[J]. Crystals, 2017, 7(10):56-62.
【11】MISRA A, PANDA A. Variation of H-2 bond length with magnetic field[J]. Journal of Molecular Spectroscopy, 2008, 252(1):98-100.
【12】MA Y,WANG Y X,CONG J Z,et al.Magnetic-field tuning of hydrogen bond order-disorder transition in metal-organic frameworks[J].Physical Review Letters,2019,122(25):255701.
【13】XU Y B,HOU M Y,RUAN J J,et al.Effect of magnetic field on surface properties of bacillus cereus CrA and its extracellular polymeric substances (EPS)[J].Journal of Adhesion Science and Technology,2014,28(21):2196-2208.
【14】SZCZES A, CHIBOWSKI E, HOLYSZ L, et al. Effects of static magnetic field on water at kinetic condition[J]. Chemical Engineering and Processing-Process Intensification, 2011, 50(1):124-127.
【15】CHEN S, WANG X Y, LI F, et al. Study of Raman spectroscopy on the structure of NH4Cl aqueous solution under strong magnetic field[J]. Spectroscopy and Spectral Analysis, 2021, 41(1):116-121.
【16】TOLEDO E J, RAMALHO T C, MAGRIOTIS Z M. Influence of magnetic field on physical-chemical properties of the liquid water:insights from experimental and theoretical models[J]. Journal of Molecular Structure, 2008, 888(1-3):409-415.
【17】CHEN L, LI C J, REN Z M. Variation of surface tension of water in high magnetic field[C]//Advanced Materials Research. Trans Tech Publications Ltd.,[S.l.]:[s.n.], 2013, 2279-2282.
【18】强智明,马保吉,王瑞峰,等. 磁场对电化学反应中电解液微观扩散特性影响的分子动力学研究[J]. 分子科学学报, 2019,35(1):70-76.
【19】PARSONS S A,JUDD S J,STEPHENSON T,et al.Magnetically augmented water treatment[J].Process Safety and Environmental Protection,1997,75(2):98-104.
【20】UMEKI S,WATANABE T,SHIMABUKURO H,et al.Change in zeta potential by alternating electromagnetic treatment as scale prevention process[J].Transactions of the Materials Research Society of Japan,2007,32(3):611-614.
【21】葛红花,位承君,龚晓明,等.电磁处理对水溶液中碳酸钙微粒沉降及附着性能的影响[J].化学学报,2011,69(19):2313-2318.
【22】GE H H, WEI C J, GONG X M, et al. Effect of electromagnetic treatment on sedimentation and adhesion behavior of calcium carbonate particles formed in aqueous solution[J]. Acta Chimica Sinica, 2011, 69(19):2313-2318.
【23】RUAN X H,WANG Y,XUAN S H,et al.Magnetic field dependent electric conductivity of the magnetorheological fluids:the influence of oscillatory shear[J].Smart Materials and Structures,2017,26(3):035067.
【24】CHEN L,LI N,CHAI F,et al.Comparison on effect of alternating and stationary magnetic field on the conductivity of NaCl solutions[J].Advanced Materials Research,2011,391/392:1095-1099.
【25】陈小砖,赵佳,张蓓乐,等.扫频电磁场对换热面结垢过程的作用规律[J].热能动力工程,2020,35(2)155-160.
【26】LEE S H, CHO Y I. Velocity effect on electronic-antifouling technology to mitigate mineral fouling in enhanced-tube heat exchanger[J]. International Journal of Heat & Mass Transfer, 2002, 45(20):4163-4174.
【27】MIAO X F,XIONG L,CHEN J P,et al.Experimental study on calcium carbonate precipitation using electromagnetic field treatment[J].Water Science and Technology,2013,67(12):2784-2790.
【28】孙昊. 扫频电磁场阻垢机理及实验研究[D]. 山东:青岛科技大学,2019.
【29】GLINIAK M,DRÓŻDŻ T,NAWARA P,et al.The effect of static magnetic field on chemical properties of sewage sludge during biological treatment[C]//2018 Progress in Applied Electrical Engineering (PAEE).June 18-22,2018,Koscielisko,Poland.IEEE,2018:1-5.
【30】BUSCH K W,BUSCH M A, DARLING R,et al. Evaluation of the principles of magnetic water treatment[M]. American:American Petroleum Institute Publication, 1985.
【31】PANG X F,DENG B.Investigation of changes in properties of water under the action of a magnetic field[J].Science in China Series G:Physics,Mechanics and Astronomy,2008,51(11):1621-1632.
【32】朱元保,颜流水,曹祉祥,等.磁化水的物理化学性能[J].湖南大学学报,1999,26(1):21-25,32.
【33】YANG Z K, XIONG L, LUO Y, et al. Experiment research on the frequency effects of pulsed electromagnetic field on industrial circulating water[M]. Lancaster:Destech Publications, Inc, 2015:373-382.
【34】MENG X F, DU J G, LI, et al. Research on magnetization and scale inhibition technology of China oil field waste water[J]. Fresenius Environmental Bulletin, 2019, 28(6):4414-4422.
【35】DOOSTI M R, KARGAR R, SAYADI M H. Water treatment using ultrasonic assistance:a review[J]. Proceedings of the international academy of ecology and environmental sciences, 2012, 2(2):96-110.
【36】蒋文斌. 基于变化电磁场的电磁除垢系统[D]. 浙江:中国计量学院, 2012.
【37】LIPUS L C,ACKO B,HAMLER A.Electromagnets for high-flow water processing[J]. Chemical Engineering and Processing:Process Intensification, 2011, 50(9):952-958.
【38】GILAN F,DEAS D,FERRER D,et al.High flow capacity devices for anti-scale magnetic treatment of water[J].Chemical Engineering and Processing:Process Intensification,2013,70:211-216.
【39】蒋文斌,陈华德,李青,等.用于除垢的新型电磁场发生装置设计[J].中国计量学院学报,2011,22(3):263-267.
【40】MAHMOUD B, YOSRA M, NADIA A. Effects of magnetic treatment on scaling power of hard waters[J]. Separation and Purification Technology, 2016, 171:88-92.
【41】WANG J G, LUO Z H, LIANG Y D, et al. Effect of electromagnetic fields on calcium carbonate solution crystallization and magnetic memory effect[J]. Crystal Research and Technology, 2018, 53(6):7-15.
【42】DENG B, PANG X F. Variations of optic properties of water under action of static magnetic field[J]. Chinese Science Bulletin, 2007, 52(23):3179-3182.
【43】HAN Y, WANG X, WANG S T. Research on the influence of alternating electromagnetic field on conductivity of hard water[J]. International Journal of Electrochemical Science, 2016, 11(4):3123-3136.
【44】CALABRÒ E,MAGAZÙ S.Response of hydrogen bonding to low-intensity 50 Hz electromagnetic field in typical proteins in bi-distilled water solution[J].Spectroscopy Letters,2017,50(6):330-335.
【45】WANG Y F, ZHANG B, GONG Z B, et al. The effect of a static magnetic field on the hydrogen bonding in water using frictional experiments[J]. Journal of Molecular Structure, 2013, 1052(1):102-104.
【46】SIMONIC M, URBANCL D. Alternating magnetic field influence on scaling in pump diffusers[J]. Journal of Cleaner Production, 2017, 156(1):445-450.
【47】卓民权,赵历,李艳琳,等. 球霰石碳酸钙宏量制备的研究进展[J].化工技术与开发, 2020, 49(4):25-28.
【48】SRONSRI C, U-YEN K, SITTIPOL W. Quantitative analysis of calcium carbonate formation in magnetized water[J]. Materials Chemistry and Physics, 2020, 245(6):122735.
【49】HAN Y, ZHANG C X, ZHU L, et al. Effect of alternating electromagnetic field and ultrasonic on CaCO3 scale inhibitive performance of EDTMPS[J]. Journal of the Taiwan Institute of Chemical Engineers, 2019, 99(1):104-112.
【50】宋飞, 葛红花, 邓宇强, 等. 磁处理对水溶液及CaCO3颗粒物理化学性质的影响[J]. 水处理技术, 2012, 38(3):23-26.
【51】XU Z M,CHANG H L,WANG B B,et al.Characteristics of calcium carbonate fouling on heat transfer surfaces under the action of electric fields[J].Journal of Mechanical Science and Technology,2018,32(7):3445-3451.
【52】MYSLIWIEC D, SZCZES A, CHIBOWSKI S. Influence of static magnetic field on the kinetics of calcium carbonate formation[J]. Journal of Industrial and Engineering Chemistry, 2016, 35(1):400-407.
【53】LIU B C,LIU N,WANG S Y,et al.Effect of output parameters of electromagnetic anti-fouling technology[J].International Journal of Applied Electromagnetics and Mechanics,2020,62(3):433-445.
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