Determination of Trimethylamine in Seawater by Gas Chromatography with Headspace
摘 要
测定海水中三甲胺含量的现有方法存在样品用量大、仪器昂贵或操作繁琐等问题,因此进行了题示研究。取10.00 mL海水样品置于20 mL顶空瓶中,加入2.5 g氯化钠、0.8 g硫酸钾和2.5 mL 7.5 mol·L-1氢氧化钠溶液,于85℃平衡40 min,所得气体进入气相色谱仪,在CP-Volamine石英毛细管色谱柱上用升温程序分离,用氮磷检测器测定三甲胺的含量,基质匹配法定量。结果显示,三甲胺的质量浓度在5.0~100.0 μg·L-1内和其对应的响应信号呈线性关系,检出限(3.143s)为0.4 μg·L-1。方法用于加标空白样品的分析,测定值的相对标准偏差(n=5)为2.1%,回收率为92.0%~118%。
Abstract
The existing methods for the determination of trimethylamine in seawater had problems such as large sample amount, expensive instrument, or cumbersome operations, so the research mentioned by the title was conducted. An aliquot (10.00 mL) of seawater sample was taken and placed into a 20 mL-headspace bottle, 2.5 g of sodium chloride, 0.8 g of potassium sulfate, and 2.5 mL of 7.5 mol·L-1 sodium hydroxide solution were added. The mixture was equilibrated at 85℃ for 40 min. The obtained gas was introduced into the gas chromatograph, and the separation was conducted by heating program on the CP-Volamine quartz capillary column, and trimethylamine was determined by the nitrogen phosphorus detector, with the matrix matching method for quantification. It was shown that linear relationship between values of the mass concentration of trimethylamine and the response signal was kept in the range of 5.0-100.0 μg·L-1, with detection limit (3.143s) of 0.4 μg·L-1.The proposed method was applied to the analysis of the spiked blank sample, RSDs (n=5) of the determined values was 2.1%, and recoveries ranged from 92.0% to 118%.
中图分类号 O657.7 DOI 10.11973/lhjy-hx202311014
所属栏目 工作简报
基金项目
收稿日期 2022/12/12
修改稿日期
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联系人作者许秀艳(xuxy@cnemc.cn)
备注曹方方,工程师,博士,主要从事环境监测相关工作
引用该论文: CAO Fangfang,SHI Jinghua,XIE Xin,XU Xiuyan,ZHANG Fengju,YOU Xihua. Determination of Trimethylamine in Seawater by Gas Chromatography with Headspace[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2023, 59(11): 1327~1331
曹方方,石敬华,解鑫,许秀艳,张凤菊,由希华. 顶空-气相色谱法测定海水中三甲胺的含量[J]. 理化检验-化学分册, 2023, 59(11): 1327~1331
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参考文献
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【14】邹阅超,李伟芳,刘绿叶.顶空-气相色谱-质谱法同时测定土壤中6种有机胺的含量[J].理化检验-化学分册, 2022,58(7):836-840.
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【16】宁皓月,卢莉璟,潘嘹,等.顶空进样-气相色谱/质谱联用法同时测定食品接触用润滑油中11种苯系物[J].分析试验室, 2021,40(5):513-517.
【2】WU C X, WEN Y X, HUA L, et al. Rapid and highly sensitive measurement of trimethylamine in seawater using dynamic purge-release and dopant-assisted atmospheric pressure photoionization mass spectrometry[J]. Analytica Chimica Acta, 2020,1137:56-63.
【3】ZHUANG G C, YANG G P, YU J, et al. Production of DMS and DMSP in different physiological stages and salinity conditions in two marine algae[J]. Chinese Journal of Oceanology and Limnology, 2011,29(2):369-377.
【4】J. BARLETTA A B, MEINARDI A S, et al. Molecular understanding of sulphuric acid-amine particle nucleation in the atmosphere[J]. Nature, 2013,502(7471):359-363.
【5】MURPHY S M, SOROOSHIAN A, KROLL J H, et al. Secondary aerosol formation from atmospheric reactions of aliphatic amines[J]. Atmospheric Chemistry and Physics, 2007,7(9):2313-2337.
【6】YANG X Y, CAO F, FAN M Y, et al. Seasonal variations of low molecular alkyl amines in PM2.5 in a North China Plain industrial city:Importance of secondary formation and combustion emissions[J]. Science of the Total Environment, 2023,857:159371.
【7】TONG D, CHEN J Y, QIN D D, et al. Mechanism of atmospheric organic amines reacted with ozone and implications for the formation of secondary organic aerosols[J]. Science of the Total Environment, 2020,737:139830.
【8】YUAN J J, DING W X, LIU D Y, et al. Shifts in methanogen community structure and function across a coastal marsh transect:Effects of exotic Spartina alterniflora invasion[J]. Scientific Reports, 2016,6:18777.
【9】OREMLAND R S, MARSH L M, POLCIN S. Methane production and simultaneous sulphate reduction in anoxic, salt marsh sediments[J]. Nature, 1982,296(5853):143-145.
【10】赵乐,韩丽君,刘兰红,等.河北省近岸海域氮磷变化及其影响因素分析[J].中国环境监测, 2021,37(1):87-94.
【11】徐永辉,黄文国,梁泰尔.万宁小海海水增养殖区海域水质状况分析与评价[J].广东化工, 2021,48(8):204-207.
【12】魏潇,李凡,马元庆,等.2014年山东近岸海域海水氮磷营养盐含量特征及富营养化评价[J].海洋湖沼通报, 2019(5):103-109.
【13】CREE C H L, AIRS R, ARCHER S D, et al. Measurement of methylamines in seawater using solid phase microextraction and gas chromatography[J]. Limnology and Oceanography:Methods, 2018,16(7):411-420.
【14】邹阅超,李伟芳,刘绿叶.顶空-气相色谱-质谱法同时测定土壤中6种有机胺的含量[J].理化检验-化学分册, 2022,58(7):836-840.
【15】张存良,李红莉,岳太星,等.顶空-气相色谱法测定固定污染源废气中三甲胺的含量[J].理化检验-化学分册, 2019,55(7):778-783.
【16】宁皓月,卢莉璟,潘嘹,等.顶空进样-气相色谱/质谱联用法同时测定食品接触用润滑油中11种苯系物[J].分析试验室, 2021,40(5):513-517.
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