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纯H2S环境中腐蚀产物离子选择性对P110S低合金钢腐蚀行为的影响
          
Effect of Ion Selectivity of Corrosion Products on Corrosion Behavior ofP110S Low Alloy Steel in Pure H2S Environment

摘    要
利用高温高压反应釜模拟纯H2S-Cl-腐蚀环境,对P110S低合金钢在不同温度下进行腐蚀试验。通过失重法,对P110S低合金钢的腐蚀速率进行了评价,并利用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、激光共聚焦显微镜和膜电位测试等方法,探究了温度对P110S低合金钢腐蚀行为的影响。结果表明:随着温度的升高,腐蚀速率变大;当温度低于120℃时,腐蚀速率上升幅度较小,而当温度高于120℃时腐蚀速率急剧上升;低温下试样腐蚀速率较小且为均匀腐蚀,腐蚀产物为马基诺矿,呈现阳离子选择性;而高温下试样腐蚀速率较大且存在点蚀,腐蚀产物为磁黄铁矿,呈现阴离子选择性。
标    签 H2S腐蚀   腐蚀产物   离子选择性   温度   点蚀   H2S corrosion   corrosion product   ion selectivity   temperature   pitting  
 
Abstract
A high temperature and high pressure autoclave was used to simulate pure H2S-Cl- corrosion environment, and the corrosion weight loss tests of P110S low alloy steel were carried out at different temperatures. The corrosion rate of the steel was evaluated by weight loss method, and the effects of temperature on the corrosion behavior of the steel were investigated by means of scanning electron microscopy (SEM), X-ray diffractometer (XRD), laser confocal microscope and membrane potential test. The results showed that the corrosion rate increased with the increase of temperature. When the temperature was lower than 120℃, the increase of corrosion rate was small, but when the temperature was higher than 120℃, the corrosion rate increased sharply. At low temperature, the corrosion rate of sample was low and uniform, and the corrosion product was mackinawite, showing cation selectivity. At high temperature, the corrosion rate of sample was higher and existed pitting. The corrosion product was pyrrhotite, which was anion selective.

中图分类号 TG174   DOI 10.11973/fsyfh-202312008

 
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收稿日期 2023/5/16

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引用该论文: LIU Jianing,CHEN Changfeng,JIA Xiaolan,TU Lanke. Effect of Ion Selectivity of Corrosion Products on Corrosion Behavior ofP110S Low Alloy Steel in Pure H2S Environment[J]. Corrosion & Protection, 2023, 44(12): 53


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