表面转化膜无铬化技术的研究动向
Development Status of Chromium-free Conversion Coating Technology
摘 要
环保的需要使得铬酸盐转化膜逐渐被各种无铬转化膜所替代.本文介绍了含氧酸盐、锆盐和钛盐、稀土、植酸、硅烷等无铬表面转化膜的形成机理及发展现状.随着科技的发展,无铬转化膜将引起人们越来越多的重视,并能应用于更多的领域中.
含氧酸盐
稀土
植酸
硅烷
conversion coating
oxyacid salt
rare earth
phytic acid
silane
Abstract
Chromate conversion coatings have been gradually replaced by chromium-free conversion coatings for the environmental demand.The formation mechanism and development of chromium-free conversion coatings,such as oxyacid salt,zirconium salt and titanium salt,phytic acid,rare earth,silane were introduced in this paper.With the development of technology,chromium-free conversion coatings would obtain more and more attention and be applied to more fields.
中图分类号 TG174 TG178
所属栏目 专论
基金项目 黑龙江省自然科学基金项目(E0325)
收稿日期 2008/10/6
修改稿日期 2008/10/21
网络出版日期
作者单位点击查看
引用该论文: HU Hui-li,CHEN Li-jiao. Development Status of Chromium-free Conversion Coating Technology[J]. Corrosion & Protection, 2009, 30(10): 727～731
被引情况:
【1】张圣麟,张小麟, "氧化钇掺杂对铝合金表面硅烷膜耐蚀性的影响",腐蚀与防护 32, 965-968(2011)
【2】堵艳艳,潘勇,周兆锋,李玮,惠建科, "电沉积镀镍层的无铬钝化工艺",腐蚀与防护 33, 60-63(2012)
【3】蒋晓军,陈昌国,刘渝萍,尹玲,张丁非, "稀土强化镁合金耐蚀性能的研究进展",腐蚀与防护 33, 46-50(2012)
【4】雷越,汤宏伟,张圣麟, "6061铝合金上硅烷膜的制备与性能",腐蚀与防护 35, 64-68(2014)
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】Magalhes A A O,Margarit I C P,Mattos O R.Molybdate conversion coatings on zinc surfaces[J].Journal of Electroanalytical Chemistry,2004,572(2):433-440.
【2】郑环宇,安茂忠,赖勤志.镀锌层无铬钝化工艺的研究[J].材料保护,2005,35(8):29-31.
【3】Silva O R,Correia A N,Lima-Neto P,et al.Study of conversion coatings obtained from tungstate-phosphoric acid solutions[J].Corrosion Science,2005,47(3):709-722.
【4】Veeraraghavan B,Slavkov D,Prabhu S,et al.Synthesis and characterization of a novel non-chrome electrolytic surface treatment process to protect zinc coatings[J].Surface and Coatings Technology,2003,167(1):41-51.
【5】刘文君,张英杰,章江洪,等.工艺因素对硅酸盐无铬钝化中耐蚀性的影响[J].表面技术,2007,36(1):60-61,96.
【6】Underhill P R,Goring G,DuQuesnay D L.The effect of humidity on the curing of 3-glycidoxypropyltrimethoxy silane (GPS)[J].International Journal of Adhesion Adhesive,2000,20(3):195-199.
【7】张微,何莉萍,唐绍裘,等.富锌环氧涂层的防腐蚀研究[J].涂料工业,2002(12):4-6.
【8】马蒂亚斯·科赫,科斯廷·莫茨凯特,卡斯滕·哈克巴斯,等.不含铬的防腐剂和防腐蚀方法[P].中国专利:00807712.6,2002-06-05.
【9】Montemor M F,Rosqvst A,Faerholm H.The early corrosion behaviour of hot dip galvanised steel pre-treated with Bis-1,2-(triethoxysilyl)eathane[J].Progress in Organic Coatings,2004,51(3):188-194.
【10】Montemor M F,Trabelsi W,Zheludevich M,et al.Modification of Bis-silane solutions with rare-earth cations for improved corrosion protection of galvanized steel substrates[J].Progress in Organic Coatings,2006,57(1):67-77.
【11】Trabelsi W,Triki E,Dhouibi L.The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanised steel substrates[J].Surface & Coating Technology,2006,200(14/15):4240-4250.
【12】Kunitsugu Aramaki.Self-healing protective films prepared on zinc electrodes by treatment in a cerium(III) nitrate solution and modification with sodium phosphate and calcium or magnesium nitrate[J].Corrosion Science,2003,45(10):2361-2376.
【13】Kunitsugu Aramaki.Protection of zinc from corrosion by coverage with a hydrated cerium(III) oxide layer and ultrathin polymer films of a carboxylate self-assembled monolayer modified with alkyltriethoxysilanes[J].Corrosion Science,2007,49(4):1963-1980.
【14】Montemor M F,Simes A M,Ferreira M G S.Composition and corrosion behaviour of galvanised steel treated with rare-earth salts: the effect of the cation[J].Progress in Organic Coatings,2002,44(2):111-120.
【15】Arenas M A,Damborenea J J de.Surface characterisation of cerium layers on galvanised steel[J].Surface & Coatings Technology,2004,187(2/3):320-325.
【16】Sánchez M,Alonso M C,Cecílio P,et al.Electrochemical and analytical assessment of galvanized steel reinforcement pre-treated with Ce and La salts under alkaline media[J].Cement & Concrete Composites,2006,28(3):256-266.
【17】LU Jin-tang,WU Hai-jiang,KONG Gang,et al.Growth and corrosion behavior of rare earth film on hot-dip galvanized stee[J].Trans.Nonferrous Met.Soc.China,2006,16(6):1397-1401.
【18】Zheludkevich M L,Serra R,Montemor M F,et al.Nanostructured sol-gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 Corrosion protection performance[J].Electrochimica Acta,2005,51(2):208-217.
【19】Cabral A M,Trabelsi W,Serra R,et al.The corrosion resistance of hot dip galvanized steel and AA2024-T3 pre-treated with bis-［triethoxysilylpropyl］ tetrasulfide solutions doped with Ce(NO3)3[J].Corrosion Science,2006,48(11):3740-3758.
【20】Romero Pareja R,López Ibáez R,Martín F,et al.Corrosion behaviour of zirconia barrier coatings on galvanized steel[J].Surface & Coatings Technology,2006,200(22/23):6606-6610.
【21】Andreatta F,Aldighieri P,Paussa L,et al.Electrochemical behaviour of ZrO2 sol-gel pre-treatments on AA6060 aluminium alloy[J].Electrochimica Acta,2007,52(27):7545-7555.
【22】Gusmano G,Montesperelli G,Rapone M,et al.Zirconia primers for corrosion resistant coatings[J].Surface & Coatings Technology,2007,201(12):5822-5828.
【23】Zhu Liqun,Yang Fei,Ding Nan.Corrosion resistance of the electro-galvanized steel treated in a titanium conversion solution[J].Surface & Coatings Technology,2007,201(18):7829-7834.
【24】Lamaka S V,Zheludkevich M L,Yasakau K A,et al.Nanoporous titania interlayer as reservoir of corrosion inhibitors for coatings with self-healing ability[J].Progress in Organic Coatings,2007,58(2/3):127-135.
【25】Yashiro Kuniji,Yoshio Moriya.Metal surface coating agent[P].USP:4341558,1982-07-27.
【26】周和平.植酸在金属表面处理中的应用[J].电镀与环保,2003,23(2):23-25.
【27】张洪生,杨晓蕾,陈熹.植酸在金属防腐中应用的新进展[J].四川化工与腐蚀控制,2001,4(5):7-9.
【28】胡会利,李宁,程瑾宁.镀锌植酸钝化膜耐蚀性的研究[J].电镀与环保,2005,25(6):21-25.
【2】郑环宇,安茂忠,赖勤志.镀锌层无铬钝化工艺的研究[J].材料保护,2005,35(8):29-31.
【3】Silva O R,Correia A N,Lima-Neto P,et al.Study of conversion coatings obtained from tungstate-phosphoric acid solutions[J].Corrosion Science,2005,47(3):709-722.
【4】Veeraraghavan B,Slavkov D,Prabhu S,et al.Synthesis and characterization of a novel non-chrome electrolytic surface treatment process to protect zinc coatings[J].Surface and Coatings Technology,2003,167(1):41-51.
【5】刘文君,张英杰,章江洪,等.工艺因素对硅酸盐无铬钝化中耐蚀性的影响[J].表面技术,2007,36(1):60-61,96.
【6】Underhill P R,Goring G,DuQuesnay D L.The effect of humidity on the curing of 3-glycidoxypropyltrimethoxy silane (GPS)[J].International Journal of Adhesion Adhesive,2000,20(3):195-199.
【7】张微,何莉萍,唐绍裘,等.富锌环氧涂层的防腐蚀研究[J].涂料工业,2002(12):4-6.
【8】马蒂亚斯·科赫,科斯廷·莫茨凯特,卡斯滕·哈克巴斯,等.不含铬的防腐剂和防腐蚀方法[P].中国专利:00807712.6,2002-06-05.
【9】Montemor M F,Rosqvst A,Faerholm H.The early corrosion behaviour of hot dip galvanised steel pre-treated with Bis-1,2-(triethoxysilyl)eathane[J].Progress in Organic Coatings,2004,51(3):188-194.
【10】Montemor M F,Trabelsi W,Zheludevich M,et al.Modification of Bis-silane solutions with rare-earth cations for improved corrosion protection of galvanized steel substrates[J].Progress in Organic Coatings,2006,57(1):67-77.
【11】Trabelsi W,Triki E,Dhouibi L.The use of pre-treatments based on doped silane solutions for improved corrosion resistance of galvanised steel substrates[J].Surface & Coating Technology,2006,200(14/15):4240-4250.
【12】Kunitsugu Aramaki.Self-healing protective films prepared on zinc electrodes by treatment in a cerium(III) nitrate solution and modification with sodium phosphate and calcium or magnesium nitrate[J].Corrosion Science,2003,45(10):2361-2376.
【13】Kunitsugu Aramaki.Protection of zinc from corrosion by coverage with a hydrated cerium(III) oxide layer and ultrathin polymer films of a carboxylate self-assembled monolayer modified with alkyltriethoxysilanes[J].Corrosion Science,2007,49(4):1963-1980.
【14】Montemor M F,Simes A M,Ferreira M G S.Composition and corrosion behaviour of galvanised steel treated with rare-earth salts: the effect of the cation[J].Progress in Organic Coatings,2002,44(2):111-120.
【15】Arenas M A,Damborenea J J de.Surface characterisation of cerium layers on galvanised steel[J].Surface & Coatings Technology,2004,187(2/3):320-325.
【16】Sánchez M,Alonso M C,Cecílio P,et al.Electrochemical and analytical assessment of galvanized steel reinforcement pre-treated with Ce and La salts under alkaline media[J].Cement & Concrete Composites,2006,28(3):256-266.
【17】LU Jin-tang,WU Hai-jiang,KONG Gang,et al.Growth and corrosion behavior of rare earth film on hot-dip galvanized stee[J].Trans.Nonferrous Met.Soc.China,2006,16(6):1397-1401.
【18】Zheludkevich M L,Serra R,Montemor M F,et al.Nanostructured sol-gel coatings doped with cerium nitrate as pre-treatments for AA2024-T3 Corrosion protection performance[J].Electrochimica Acta,2005,51(2):208-217.
【19】Cabral A M,Trabelsi W,Serra R,et al.The corrosion resistance of hot dip galvanized steel and AA2024-T3 pre-treated with bis-［triethoxysilylpropyl］ tetrasulfide solutions doped with Ce(NO3)3[J].Corrosion Science,2006,48(11):3740-3758.
【20】Romero Pareja R,López Ibáez R,Martín F,et al.Corrosion behaviour of zirconia barrier coatings on galvanized steel[J].Surface & Coatings Technology,2006,200(22/23):6606-6610.
【21】Andreatta F,Aldighieri P,Paussa L,et al.Electrochemical behaviour of ZrO2 sol-gel pre-treatments on AA6060 aluminium alloy[J].Electrochimica Acta,2007,52(27):7545-7555.
【22】Gusmano G,Montesperelli G,Rapone M,et al.Zirconia primers for corrosion resistant coatings[J].Surface & Coatings Technology,2007,201(12):5822-5828.
【23】Zhu Liqun,Yang Fei,Ding Nan.Corrosion resistance of the electro-galvanized steel treated in a titanium conversion solution[J].Surface & Coatings Technology,2007,201(18):7829-7834.
【24】Lamaka S V,Zheludkevich M L,Yasakau K A,et al.Nanoporous titania interlayer as reservoir of corrosion inhibitors for coatings with self-healing ability[J].Progress in Organic Coatings,2007,58(2/3):127-135.
【25】Yashiro Kuniji,Yoshio Moriya.Metal surface coating agent[P].USP:4341558,1982-07-27.
【26】周和平.植酸在金属表面处理中的应用[J].电镀与环保,2003,23(2):23-25.
【27】张洪生,杨晓蕾,陈熹.植酸在金属防腐中应用的新进展[J].四川化工与腐蚀控制,2001,4(5):7-9.
【28】胡会利,李宁,程瑾宁.镀锌植酸钝化膜耐蚀性的研究[J].电镀与环保,2005,25(6):21-25.
相关信息
