不锈钢点蚀行为及研究方法的进展
Progress in Research of Pitting Corrosion Behavior and Research Methods of Stainless Steels
摘 要
综述了不锈钢亚稳态点蚀的几种形核机理、生长和再钝化过程, 亚稳态点蚀向稳态点蚀转变的临界条件, 稳态点蚀在不同环境下的生长模式以及研究方法。亚稳态点蚀萌生的判据和再钝化的机理还有待进一步研究, 点蚀的机理、动力学及形貌学仍有较大发展空间, 需发展有效的研究方法来完善点蚀行为和规律。
点蚀
生长
研究方法
stainless steel
pitting corrosion
growth
research method
Abstract
The nucleation mechanism, growth, repassivation of metastable pits, the critical conditions of transforming metastable pits to stable pits, the growth of stable pits under different conditions and research methods are reviewed in this paper. The criterion of metastable pit nucleation and the mechanism of repassivation, as well as the mechanism, kinetics and geometry of pits corrosion remain to be studied further. Effective methods will be needed to improve the research of pitting behaviors and pit developing rules.
中图分类号 TG172
所属栏目 专论
基金项目 国家自然科学基金(51071083)
收稿日期 2013/5/14
修改稿日期
网络出版日期
作者单位点击查看
联系人作者杜楠(d_unan@sina.com)
备注杜楠(1956-),教授,硕士,从事材料的腐蚀与防护研究,
引用该论文: YE Chao,DU Nan,ZHAO Qing,TIAN Wen-ming. Progress in Research of Pitting Corrosion Behavior and Research Methods of Stainless Steels[J]. Corrosion & Protection, 2014, 35(3): 271
被引情况:
【1】朱方辉,罗泽松,李小峰,刘伟,杨斌, "高温高压条件下13Cr钢的乙酸腐蚀",腐蚀与防护 36, 735-737(2015)
【2】黄世新,杜楠,赵晴,艾莹珺,王力强,文庆杰, "Fe3+水解及其对304不锈钢点蚀行为的影响",腐蚀与防护 37, 453-457(2016)
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参考文献
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【14】ERNST P,NEWMAN R C. Pit growth studies in stainless steel foils:II. Effect of temperature,chloride concentrantion and sulphate addition[J]. Corrosion Science,2002,44:943-954.
【15】FRANKENTHAL R P,PICKERING H W. On the mechanism of localized corrosion of iron and stainless steel[J]. Electrochemical Science and Technology,1972,119(10):1304-1310.
【16】刘道新. 材料的腐蚀与防护[M]. 西安:西北工业大学出版社,2006:119-120.
【17】BRIGHAM R,TOZER E. Temperature as a pitting criterion[J]. Corrosion,1973,29(1):33-36.
【18】QVARFORT R. Critical pitting temperature measurements of stainless steels with an improved electrochemical method[J]. Corrosion Science,1989,29,987-993.
【19】ERNST P,NEWMAN R. Explanation of the effect of high chloride concentration on the critical pitting temperature of stainless steel[J]. Corrosion Science,2007,49:3705-3715.
【20】WU Q K,LE G P,JALLERAT N,et al. Fast method for determination of critical pitting temperature[J]. Corrosion Science,1988,28:423-424.
【21】KRAKOEWIAK S,DAROWICKI K,SLEPSKI P. Impedance of mestastable pitting corrosion[J]. Electroanalytical Chemistry,2005,575:33-38.
【22】JIA Z J,DU C W,LI C T,et al. Study on pitting process of 316L stainless steel by means of staircase potential electrochemical impedance spectroscopy[J]. International Journal of Minerals,Metallurgy and Materials,2011,18(1):48-52.
【23】张胜寒,檀玉,梁可心. 电化学阻抗谱法对304不锈钢孔蚀生长和再钝化阶段的原位研究[J]. 中国腐蚀与防护学报,2011,31(2):130-134.
【24】EBRAHIMI N,MOMENI M,MOAYED M H,et al. A comparative study of critical pitting temperature(CPT) of stainless steels by electrochemical impedance spectroscopy(EIS),potentiodynamic and potentiostatic techniques[J]. Corrosion Science,2012,59:96-102.
【25】BERTOCCI U ,HUET F. Noise analysis applied to electrochemical systems[J]. Corrosion,1995 ,51(2):131-144.
【26】GUSMANO G,MONTESPERELLI G,PACETTI S,et al. Electrochemical noise resistance as a tool for corrosion rate prediction[J]. Corrosion,1997,53(11):860-868.
【27】SALINAS B V,NEWMAN R. An alternative method to determine critical pitting temperature of stainless steels in ferric chloride solution[J]. Corrosion Science,1994,36:67-77.
【28】杜楠,黄乐,徐珊,等. 304不锈钢点蚀行为的电化学噪声研究[J]. 失效分析与预防,2009,4(2):71-77.
【29】WANG M F,LI X G,DU N,et al. Direct evidence of initial pitting corrosion[J]. Electrochemistry Communications,2008,10:1000-1004.
【30】徐珊,杜楠,赵晴,等. 激光电子散斑干涉技术监测奥氏体不锈钢在NaCl溶液中的早期点蚀敏感性[J]. 中国腐蚀与防护学报,2010,30(5):403-409.
【31】DAROWICKI K,MIRAKOWSKI A,KRAKOWIAK S. Investigation of pitting corrosion of stainless steel by means of acoustic emission and potentiodynamic methods[J]. Corrosion Science,2003,45:1747-1756.
【32】XU J,WU X Q,HAN E H. Acoustic emission during pitting corrosion of 304 stainless steel[J]. Corrosion Science,2011,53:1537-1546.
【33】JIRARUNGSATIAN C,PRATEEPASEN A. Pitting and uniform corrosion source recognition using acoustic emission parameters[J]. Corrosion Science,2010,52:187-197.
【34】GONZLEZ G Y,BURSTEIN G T,GONZLEZ S. Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential[J]. Electrochemistry Communications,2004,6:637-642.
【35】张明明,孟君,黄晓义,等. 利用SECM技术研究304不锈钢的点蚀行为[J]. 腐蚀与防护,2012,33(6):482-486.
【2】左禹,王海涛. 金属亚稳态孔蚀行为的电化学研究[J]. 腐蚀科学与防护技术,1999,11(1): 44-52.
【3】ZAMALETDINOV I I. Pitting on passive metals[J]. Protection of Metals,2007,43(5):470-475.
【4】MARCUS P,MAURICE V,STREHBLOW H H. Localized corrosion(pitting):A model of passivity breakdown including the role of the oxide layer nanostructure[J]. Corrosion Science,2008,50:2698-2704.
【5】SZKLARSKA-S Z. Mechanism of pit nucleation by electrical breakdown of the passive film[J]. Corrosion Science,2002,44:1143-1149.
【6】RYAN M P,WILLIAMS D E,CHATER R J,et al. Why stainless steel corrodes[J]. Nature,2002,415:770-774.
【7】BURSTEIN G T,LIU C,SOUTO R M,et al. Origin of pitting corrosion[J]. Corrosion Engineering,Science and Technology,2004,39(1):25-30.
【8】LI L,LI X G,DONG C F,et al. Cellular automaton model for simulation of metastable pitting[J]. Corrosion Engineering,Science and Technology,2011,46(4):340-345.
【9】FRANKEL G S,STOCKERT L,HUNKELER F,et al. Metastable pitting of stainless steel[J]. Corrosion,1987,43(7):429-436.
【10】DAROWICKI K,KRAKOWIAK S,LEPSKI P. Evalution of pitting corrosion by means of dynamic electrochemical impedance spectroscopy[J]. Electrochemical Acta,2004,49:2909-2918.
【11】SUN D M,JIANG Y M,LI J,et al. Pitting corrosion behavior of stainless in ultrasonic cell[J]. Electrochemical Acta,2009,54:1558-1563.
【12】王成原,王明娥,朱健,等. 304L不锈钢在溴离子作用下的点蚀行为[J]. 南京化工大学学报,1999,21(6): 26-30.
【13】孙道明,蒋益明,李劲,等. 不锈钢点蚀花边盖脱落与稳定生长[J]. 郑州大学学报,2009,30(1):70-74.
【14】ERNST P,NEWMAN R C. Pit growth studies in stainless steel foils:II. Effect of temperature,chloride concentrantion and sulphate addition[J]. Corrosion Science,2002,44:943-954.
【15】FRANKENTHAL R P,PICKERING H W. On the mechanism of localized corrosion of iron and stainless steel[J]. Electrochemical Science and Technology,1972,119(10):1304-1310.
【16】刘道新. 材料的腐蚀与防护[M]. 西安:西北工业大学出版社,2006:119-120.
【17】BRIGHAM R,TOZER E. Temperature as a pitting criterion[J]. Corrosion,1973,29(1):33-36.
【18】QVARFORT R. Critical pitting temperature measurements of stainless steels with an improved electrochemical method[J]. Corrosion Science,1989,29,987-993.
【19】ERNST P,NEWMAN R. Explanation of the effect of high chloride concentration on the critical pitting temperature of stainless steel[J]. Corrosion Science,2007,49:3705-3715.
【20】WU Q K,LE G P,JALLERAT N,et al. Fast method for determination of critical pitting temperature[J]. Corrosion Science,1988,28:423-424.
【21】KRAKOEWIAK S,DAROWICKI K,SLEPSKI P. Impedance of mestastable pitting corrosion[J]. Electroanalytical Chemistry,2005,575:33-38.
【22】JIA Z J,DU C W,LI C T,et al. Study on pitting process of 316L stainless steel by means of staircase potential electrochemical impedance spectroscopy[J]. International Journal of Minerals,Metallurgy and Materials,2011,18(1):48-52.
【23】张胜寒,檀玉,梁可心. 电化学阻抗谱法对304不锈钢孔蚀生长和再钝化阶段的原位研究[J]. 中国腐蚀与防护学报,2011,31(2):130-134.
【24】EBRAHIMI N,MOMENI M,MOAYED M H,et al. A comparative study of critical pitting temperature(CPT) of stainless steels by electrochemical impedance spectroscopy(EIS),potentiodynamic and potentiostatic techniques[J]. Corrosion Science,2012,59:96-102.
【25】BERTOCCI U ,HUET F. Noise analysis applied to electrochemical systems[J]. Corrosion,1995 ,51(2):131-144.
【26】GUSMANO G,MONTESPERELLI G,PACETTI S,et al. Electrochemical noise resistance as a tool for corrosion rate prediction[J]. Corrosion,1997,53(11):860-868.
【27】SALINAS B V,NEWMAN R. An alternative method to determine critical pitting temperature of stainless steels in ferric chloride solution[J]. Corrosion Science,1994,36:67-77.
【28】杜楠,黄乐,徐珊,等. 304不锈钢点蚀行为的电化学噪声研究[J]. 失效分析与预防,2009,4(2):71-77.
【29】WANG M F,LI X G,DU N,et al. Direct evidence of initial pitting corrosion[J]. Electrochemistry Communications,2008,10:1000-1004.
【30】徐珊,杜楠,赵晴,等. 激光电子散斑干涉技术监测奥氏体不锈钢在NaCl溶液中的早期点蚀敏感性[J]. 中国腐蚀与防护学报,2010,30(5):403-409.
【31】DAROWICKI K,MIRAKOWSKI A,KRAKOWIAK S. Investigation of pitting corrosion of stainless steel by means of acoustic emission and potentiodynamic methods[J]. Corrosion Science,2003,45:1747-1756.
【32】XU J,WU X Q,HAN E H. Acoustic emission during pitting corrosion of 304 stainless steel[J]. Corrosion Science,2011,53:1537-1546.
【33】JIRARUNGSATIAN C,PRATEEPASEN A. Pitting and uniform corrosion source recognition using acoustic emission parameters[J]. Corrosion Science,2010,52:187-197.
【34】GONZLEZ G Y,BURSTEIN G T,GONZLEZ S. Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential[J]. Electrochemistry Communications,2004,6:637-642.
【35】张明明,孟君,黄晓义,等. 利用SECM技术研究304不锈钢的点蚀行为[J]. 腐蚀与防护,2012,33(6):482-486.
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