等通道转角挤压制备超细晶镁合金腐蚀行为研究进展
Progress in Research on Corrosion Behaviour of Ultra-fine Grained Mg Alloys Fabricated by ECAP
摘 要
镁合金较差的耐蚀性制约着其应用进程，等通道转角挤压(ECAP)可实现镁合金的组织超细化，有望在提高镁合金力学性能的同时改善其耐蚀性。综述了当前ECAP制备超细晶镁合金腐蚀行为的研究进展，通过对纯镁、Mg-Al合金、Mg-RE合金等典型镁材腐蚀行为与机理的分析，初步探索了借助ECAP同时实现镁合金强韧化和耐蚀化的可能途径。
超细晶
镁合金
耐蚀性
腐蚀与防护
equal-channel angular pressing(ECAP)
ultra-fine grained
magnesium alloy
corrosion resistance
corrosion and protection
Abstract
Magnesium alloys have relatively poor corrosion resistance, which is actually one of the main obstacles to their application in practical environments. Equal-channel angular pressing (ECAP) is one of the most effective techniques for fabricating ultrafine-grained (UFG) bulk magnesium alloys, which can significantly improve their corrosion resistance and superior mechanical properties. This paper reviews recent research progress on corrosion behaviour of UFG magnesium alloys fabricated by ECAP, and discusses the corrosion mechanism of typical magnesium alloys (pure Mg, Mg-Al, Mg-RE). Some possible methods to improve their strength and corrosion resistance are preliminary explored.
中图分类号 TG174
所属栏目 专论
基金项目 国家自然科学基金(51141002); 江苏省自然科学基金(BK2011249); 南通市应用研究计划(BK2012042)
收稿日期 2013/7/23
修改稿日期
网络出版日期
作者单位点击查看
联系人作者郭光辉(wa24de@163.com)
备注郭光辉(1988-),硕士研究生,从事高性能金属材料及其加工,
引用该论文: GUO Guang-hui,JIANG Jing-hua,MA Ai-bin,SONG Dan,HE Qing. Progress in Research on Corrosion Behaviour of Ultra-fine Grained Mg Alloys Fabricated by ECAP[J]. Corrosion & Protection, 2014, 35(5): 413
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参考文献
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【26】WU Y，BAKER I. An experimental study of equal channel angular extrusion[J]. Scripta Materialia,1997,37(4):437-442.
【27】ELIEZER D，UZAN P，AGHION E. Effect of second phases on the corrosion behavior of magnesium alloys[J]. Trans Tech Publ，2003(2):857-866.
【28】SONG D，MA A B，JIANG J H，et al. Corrosion behaviour of bulk ultra-fine grained AZ91D magnesium alloy fabricated by equal-channel angular pressing[J]. Corrosion Science,2011,53(1):362-373.
【29】CHEN B，LIN D L，JIN L，et al. Equal-channel angular pressing of magnesium alloy AZ91 and its effects on microstructure and mechanical properties[J]. Materials Science and Engineering:A,2008,483:113-116.
【30】GAN W M，ZHENG M Y，CHANG H，et al. Microstructure and tensile property of the ECAPed pure magnesium[J]. Journal of Alloys and Compounds,2009,470(1):256-262.
【31】SCHINO A D，KENNY J M. Effects of the grain size on the corrosion behavior of refined AISI 304 austenitic stainless steels[J]. Journal of Materials Science Letters,2002,21(20):1631-1634.
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【33】HIROYUKI Miyamoto，KOHEI Harada，TAKURO Mimaki，et al. Corrosion of ultra-fine grained copper fabricated by equal-channel angular pressing[J]. Corrosion Science,2008,50(5):1215-1220.
【34】CHUNG M K，CHOI Y S，KIM J G，et al. Effect of the number of ECAP pass time on the electrochemical properties of 1050 Al alloys[J]. Materials Science and Engineering:A,2004,366(2):282-291.
【35】HOOG C，BIRBILIS N，ESTRIN Y. Corrosion of Pure Mg as a Function of Grain Size and Processing Route[J]. Advanced Engineering Materials,2008,10(6):579-582.
【36】SONG D，MA A B，JIANG J H，et al. Corrosion behavior of equal-channel-angular-pressed pure magnesium in NaCl aqueous solution[J]. Corrosion Science,2010,52(2):481-490.
【37】宋丹,马爱斌,江静华,等. 等径角挤压制备的超细晶AZ91D镁合金块材的腐蚀行为[J]. 中国有色金属学报,2010,20(3):397-406.
【38】AUST K T，ERB U，PALUMBO G. Interface control for resistance to intergranular cracking[J]. Materials Science and Engineering:A,1994,176(1):329-334.
【39】HERMAN A J，GEORGE B A，PIERRE V R. Anodic oxidation of aluminum,chromium,hafnium,niobium,tantalum,titanium,vanadium,and zirconium at very low current densities[J]. Journal of The Electrochemical Society,1957,104(6):339-346.
【40】MARTIN J，PERSSON D，CHRISTOFER L. Atmospheric corrosion of field-exposed magnesium alloy AZ91D[J]. Corrosion Science,2008,50(5):1406-1413.
【41】HAMU G B，ELIEZER A，GUTMAN E M. RETRACTED:Electrochemical behavior of magnesium alloys strained in buffer solutions[J]. Electrochimica Acta,2006,52(1):304-313.
【42】ALVAREZ-Lopez M，MARIA Dolores Pereda，JA Del Valle，et al. Corrosion behaviour of AZ31 magnesium alloy with different grain sizes in simulated biological fluids[J]. Acta Biomaterialia,2010,6(5):1763-1771.
【43】NAING N A，ZHOU W. Effect of grain size and twins on corrosion behaviour of AZ31B magnesium alloy[J]. Corrosion Science,2010,52(2):589-594.
【44】GENEVIEVE Baril，CHRISTINE B，NADINE P. AC impedance spectroscopy in characterizing time-dependent corrosion of AZ91 and AM50 magnesium alloys characterization with respect to their microstructures[J]. Journal of the Electrochemical Society,2001,148(12):B489-B496.
【45】JAN H N，SACHIKO O，NOBURO M，et al. Morphology and structure of oxide films formed on magnesium by exposure to air and water[J]. Journal of the Electrochemical Society,1995,142(10):3320-3322.
【46】PARDO A，MERINO M C，COY A E，et al. Corrosion behaviour of magnesium/aluminium alloys in 3.5% NaCl[J]. Corrosion Science,2008,50(3):823-834.
【47】SONG G L，ANDREJ A. Understanding magnesium corrosion——a framework for improved alloy performance[J]. Advanced Engineering Materials,2003,5(12):837-858.
【48】AMBAT R J，NAING N A，ZHOU W. Studies on the influence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy[J]. Journal of Applied Electrochemistry,2000,30(7):865-874.
【49】ZENG R C，ZHANG J，HUANG W J，et al. Review of studies on corrosion of magnesium alloys[J]. Transactions of Nonferrous Metals Society of China,2006,16:763-771.
【50】MINRIK P，KRL R，JANECEK M. Effect of ECAP processing on corrosion resistance of AE21 and AE42 magnesium alloys[J]. Applied Surface Science,2013,281(0):44-48.
【51】张勇，许越，周德瑞. 稀土铈对AZ91镁合金表面腐蚀性能的影响[J]. 哈尔滨工业大学学报,2002,34(3):376-378.
【52】ZUCCHI F，GRASSI V，FRIGNANI A，et al. Electrochemical behaviour of a magnesium alloy containing rare earth elements[J]. Journal of Applied Electrochemistry,2006,36(2):195-204.
【2】SONG G L. Control of biodegradation of biocompatable magnesium alloys[J]. Corrosion Science,2007,49(4):1696-1701.
【3】PENG Q M，HUANG Y D，ZHOU L，et al. Preparation and properties of high purity Mg-Y biomaterials[J]. Biomaterials,2010,31(3):398-403.
【4】郑玉峰，顾雪楠，李楠，等. 生物可降解镁合金的发展现状与展望[J]. 中国材料进展,2011,30(4):30-43.
【5】CHEN F，ZHOU H，YAO B，et al. Corrosion resistance property of the ceramic coating obtained through microarc oxidation on the AZ31 magnesium alloy surfaces[J]. Surface and Coatings Technology,2007,201(9):4905-4908.
【6】GRAY J E，LUAN B. Protective coatings on magnesium and its alloys-a critical review[J]. Journal of Alloys and Compounds,2002,336(1):88-113.
【7】WANG L Y，HUANG G S，FAN Y G，et al. Grain refinement of wrought AZ31 magnesium alloy[J]. Chinese Journal of Nonferrous Metals,2003,13(3):598-604.
【8】LEE Y C，DAHLE A K，JOHN D H S. The role of solute in grain refinement of magnesium[J]. Metallurgical and Materials Transactions A,2000,31(11):2895-2906.
【9】RAJAN A，AUNG N N，ZHOU W. Evaluation of microstructural effects on corrosion behaviour of AZ91D magnesium alloy[J]. Corrosion Science,2000,42(8):1433-1455.
【10】MA A B，JIANG J H，SAITO N B，et al. Improving both strength and ductility of a Mg alloy through a large number of ECAP passes[J]. Materials Science and Engineering:A,2009,513:122-127.
【11】PRADOS E，SORDI V，FERRANTE M. Tensile behaviour of an Al-4% Cu alloy deformed by equal-channel angular pressing[J]. Materials Science and Engineering: A,2009,503(1):68-70.
【12】SEGAL V M. Materials processing by simple shear[J]. Materials Science and Engineering:A,1995,197(2):157-164.
【13】LAWRENCE C，YU Y，SHIGEHARU K，et al. Microstructures and tensile properties of ECAE-processed and forged AZ31 magnesium alloy[J]. Materials Transactions,2003,44(4):476-483.
【14】AKIHIRO Y，ZENJI H，TERENCE G L. Improving the mechanical properties of magnesium and a magnesium alloy through severe plastic deformation[J]. Materials Science and Engineering:A,2001,300(1):142-147.
【15】KIM W J，HONG S I，KIM Y S，et al. Texture development and its effect on mechanical properties of an AZ61 Mg alloy fabricated by equal channel angular pressing[J]. Acta Materialia,2003,51(11):3293-3307.
【16】JIANG J H，MA A B，SAITO N B，et al. Improving corrosion resistance of RE-containing magnesium alloy ZE41A through ECAP[J]. Journal of Rareearths,2009,27(5):848-852.
【17】陈振华. 变形镁合金[M]. 北京: 化学工业出版社,2005.
【18】WOO J K，HA G J. Mechanical properties and texture evolution in ECAP processed AZ61 Mg alloys[J]. Trans Tech Publ，2003(1):201-206.
【19】MINORU F K，HORITA Z J，TERENCE G L. Processing by equal-channel angular pressing:Applications to grain boundary engineering[J]. Journal of Materials Science,2005,40(4):909-917.
【20】DONG N L. An upper-bound solution of channel angular deformation[J]. Scripta Materialia,2000,43(2):115-118.
【21】汪建敏，许晓静，石凤健，等. 等径角挤压获得超细晶铜的研究[J]. 热加工工艺,2004(7):6-7.
【22】PATRICK B B，MINORU F K，HORITA Z J，et al. Influence of pressing speed on microstructural development in equal-channel angular pressing[J]. Metallurgical and Materials Transactions A,1999,30(8):1989-1997.
【23】何运斌，潘清林，刘晓艳，等. 镁合金等通道转角挤压过程中的晶粒细化机制[J]. 中国有色金属学报,2011,21(8):1785-1793.
【24】LEVENTE B，ROBERTO B F，TAMS U，et al. The contributions of grain size,dislocation density and twinning to the strength of a magnesium alloy processed by ECAP[J]. Materials Science and Engineering:A,2010,528(1):533-538.
【25】严凯，孙扬善，白晶，等. ECAP 对粗晶AZ31镁合金的晶粒细化机制的影响[J]. 热加工工艺,2011,40(10):70-73.
【26】WU Y，BAKER I. An experimental study of equal channel angular extrusion[J]. Scripta Materialia,1997,37(4):437-442.
【27】ELIEZER D，UZAN P，AGHION E. Effect of second phases on the corrosion behavior of magnesium alloys[J]. Trans Tech Publ，2003(2):857-866.
【28】SONG D，MA A B，JIANG J H，et al. Corrosion behaviour of bulk ultra-fine grained AZ91D magnesium alloy fabricated by equal-channel angular pressing[J]. Corrosion Science,2011,53(1):362-373.
【29】CHEN B，LIN D L，JIN L，et al. Equal-channel angular pressing of magnesium alloy AZ91 and its effects on microstructure and mechanical properties[J]. Materials Science and Engineering:A,2008,483:113-116.
【30】GAN W M，ZHENG M Y，CHANG H，et al. Microstructure and tensile property of the ECAPed pure magnesium[J]. Journal of Alloys and Compounds,2009,470(1):256-262.
【31】SCHINO A D，KENNY J M. Effects of the grain size on the corrosion behavior of refined AISI 304 austenitic stainless steels[J]. Journal of Materials Science Letters,2002,21(20):1631-1634.
【32】ZHANG X Y，SHI M H，LI C，et al. The influence of grain size on the corrosion resistance of nanocrystalline zirconium metal[J]. Materials Science and Engineering:A,2007,448(1):259-263.
【33】HIROYUKI Miyamoto，KOHEI Harada，TAKURO Mimaki，et al. Corrosion of ultra-fine grained copper fabricated by equal-channel angular pressing[J]. Corrosion Science,2008,50(5):1215-1220.
【34】CHUNG M K，CHOI Y S，KIM J G，et al. Effect of the number of ECAP pass time on the electrochemical properties of 1050 Al alloys[J]. Materials Science and Engineering:A,2004,366(2):282-291.
【35】HOOG C，BIRBILIS N，ESTRIN Y. Corrosion of Pure Mg as a Function of Grain Size and Processing Route[J]. Advanced Engineering Materials,2008,10(6):579-582.
【36】SONG D，MA A B，JIANG J H，et al. Corrosion behavior of equal-channel-angular-pressed pure magnesium in NaCl aqueous solution[J]. Corrosion Science,2010,52(2):481-490.
【37】宋丹,马爱斌,江静华,等. 等径角挤压制备的超细晶AZ91D镁合金块材的腐蚀行为[J]. 中国有色金属学报,2010,20(3):397-406.
【38】AUST K T，ERB U，PALUMBO G. Interface control for resistance to intergranular cracking[J]. Materials Science and Engineering:A,1994,176(1):329-334.
【39】HERMAN A J，GEORGE B A，PIERRE V R. Anodic oxidation of aluminum,chromium,hafnium,niobium,tantalum,titanium,vanadium,and zirconium at very low current densities[J]. Journal of The Electrochemical Society,1957,104(6):339-346.
【40】MARTIN J，PERSSON D，CHRISTOFER L. Atmospheric corrosion of field-exposed magnesium alloy AZ91D[J]. Corrosion Science,2008,50(5):1406-1413.
【41】HAMU G B，ELIEZER A，GUTMAN E M. RETRACTED:Electrochemical behavior of magnesium alloys strained in buffer solutions[J]. Electrochimica Acta,2006,52(1):304-313.
【42】ALVAREZ-Lopez M，MARIA Dolores Pereda，JA Del Valle，et al. Corrosion behaviour of AZ31 magnesium alloy with different grain sizes in simulated biological fluids[J]. Acta Biomaterialia,2010,6(5):1763-1771.
【43】NAING N A，ZHOU W. Effect of grain size and twins on corrosion behaviour of AZ31B magnesium alloy[J]. Corrosion Science,2010,52(2):589-594.
【44】GENEVIEVE Baril，CHRISTINE B，NADINE P. AC impedance spectroscopy in characterizing time-dependent corrosion of AZ91 and AM50 magnesium alloys characterization with respect to their microstructures[J]. Journal of the Electrochemical Society,2001,148(12):B489-B496.
【45】JAN H N，SACHIKO O，NOBURO M，et al. Morphology and structure of oxide films formed on magnesium by exposure to air and water[J]. Journal of the Electrochemical Society,1995,142(10):3320-3322.
【46】PARDO A，MERINO M C，COY A E，et al. Corrosion behaviour of magnesium/aluminium alloys in 3.5% NaCl[J]. Corrosion Science,2008,50(3):823-834.
【47】SONG G L，ANDREJ A. Understanding magnesium corrosion——a framework for improved alloy performance[J]. Advanced Engineering Materials,2003,5(12):837-858.
【48】AMBAT R J，NAING N A，ZHOU W. Studies on the influence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy[J]. Journal of Applied Electrochemistry,2000,30(7):865-874.
【49】ZENG R C，ZHANG J，HUANG W J，et al. Review of studies on corrosion of magnesium alloys[J]. Transactions of Nonferrous Metals Society of China,2006,16:763-771.
【50】MINRIK P，KRL R，JANECEK M. Effect of ECAP processing on corrosion resistance of AE21 and AE42 magnesium alloys[J]. Applied Surface Science,2013,281(0):44-48.
【51】张勇，许越，周德瑞. 稀土铈对AZ91镁合金表面腐蚀性能的影响[J]. 哈尔滨工业大学学报,2002,34(3):376-378.
【52】ZUCCHI F，GRASSI V，FRIGNANI A，et al. Electrochemical behaviour of a magnesium alloy containing rare earth elements[J]. Journal of Applied Electrochemistry,2006,36(2):195-204.
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