Fluorescence Analysis for Corrosion of AA6061 Aluminum Alloy in Chloride Solutions
摘 要
采用荧光分析法和失重法研究了AA6061铝合金在不同Cl-浓度溶液中的腐蚀行为。结果表明, 荧光分析法能够很好地监测铝合金的腐蚀过程, 与失重法所得结果的趋势具有一致性。在含有不同Cl-浓度的溶液中, AA6061铝合金在浸泡初期, 腐蚀反应速率较快; 随着浸泡时间的延长, 腐蚀反应速率逐渐降低。
Abstract
The corrosion of AA6061 aluminum alloy in chloride solutions was investigated by fluorescence analysis and weight loss method. The results showed that the corrosion process of AA6061 alloy can be detected by fluorescence analysis effectively. The variation tendency of the corrosion rate derived from fluorescence analysis agreed well with that obtained by the weight loss method. AA6061 alloy had a higher corrosion rate at the initial immersion stages. The corrosion rate slowed down gradually in chloride solutions with prolonging the immersion time. The relationship between fluorescence analysis and weight loss method was disscused.
中图分类号 TG174
所属栏目 试验研究
基金项目 上海市基础研究重点项目(09JC1406800; 11JC1404400)
收稿日期 2013/8/5
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备注张大全(1968-), 教授, 博士, 从事电厂化学和金属腐蚀与防护研究,
引用该论文: XIA Tie-feng,LI Guang-yong,LI Kang,GAO Li-xin,ZHANG Da-quan. Fluorescence Analysis for Corrosion of AA6061 Aluminum Alloy in Chloride Solutions[J]. Corrosion & Protection, 2014, 35(7): 671
被引情况:
【1】张光耀,王成磊,高原,韦文竹,陆小会,张焱,吴炜钦, "铝合金表面2%CeO2/Ni60A激光熔覆层的组织及耐腐蚀性能",机械工程材料 39, 69-72(2015)
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【5】SZUNERITS S, DAVID R W. Aluminum surface corrosion and the mechanism of inhibitors using pH and metal ion selective imaging fiber bundles[J]. Anal Chem, 2002, 74: 886-894.
【6】JOHNSON R E,AGARWALA V S. Using fluorescent compounds as early warning detectors for corrosion[J]. Materials Performance,1994,33(4):25-29.
【7】张兵, 仵博万, 张克钧,等. 2,3,4-三羟基苯乙酮缩-2-羧基苯胺与铝的荧光反应及其应用[J]. 理化检验-化学分册,2006,42(4):304-306.
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