Research and Application of a Corrosion Inhibitor for CO2/Foam Flooding in Honghe Oilfield
摘 要
采用室内旋转挂片法测定了自制的一种咪唑啉类两性缓蚀剂HGC2-2在模拟CO2/泡沫驱系统中的缓蚀性能。结果表明,在最优浓度500 mg/L下,缓蚀剂HGC2-2对N80和J55挂片的缓蚀率达到90%以上,同时与现场所用的起泡剂具有良好的配伍性能,对温度和CO2分压具有良好的适应能力。现场应用结果表明,HGC2-2缓蚀剂能将注入流程金属的腐蚀速率降低至0.076 mm/a以下,同时也能大幅度减缓采出流程的腐蚀,两口见气油井产出水中铁离子含量分别降低78%和85%,有效缓解了红河油田CO2/泡沫驱的腐蚀,可满足红河油田CO2/泡沫驱的缓蚀要求。
Abstract
To alleviate the corrosion of CO2/foam flooding in Honghe oilfield, the corrosion inhibition performance of a synthesized amphoteric imidazoline corrosion inhibitor HGC2-2 was evaluated by rotary coupon test. The results showed that, under the condition of optimum concentration 500 mg/L, the corrosion inhibiting effect of HGC2-2 could reach 90% for N80 and J55 steels. The corrosion inhibitor HGC2-2 had an excellent compatibility with the foaming agent. The corrosion inhibitor HGC2-2 also had a good adaptability to temperature and CO2 partial pressure. The field test results showed that the corrosion inhibitor HGC2-2 could decrease the corrosion rate of injection process to below 0.076 mm/a, and decrease the corrosion of the production process greatly. The content of iron ions in the production water from two gas channeling wells got a reduction of 78% and 85% respectively. The corrosion inhibitor HGC2-2 could alleviate the corrosion of CO2/foam flooding in Honghe oilfield effectively and meet the corrosion inhibiting requirement of CO2/foam flooding in Honghe oilfield.
中图分类号 TG174.42
所属栏目 试验研究
基金项目 中国石化科技部项目(P13090)
收稿日期 2013/11/1
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备注张永刚(1986-),助理工程师,硕士,从事提高采收率工作,
引用该论文: ZHANG Yong-gang,LUO Yi,LIU Xue-quan,XIONG Pei,WEI Kai-peng,SI Rong. Research and Application of a Corrosion Inhibitor for CO2/Foam Flooding in Honghe Oilfield[J]. Corrosion & Protection, 2014, 35(9): 899
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参考文献
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【2】CROLET J L,BNOIS M R. How to pressurize autoclaves for corrosion testing under carbon dioxide and hydrogen sulfide pressure[J]. Corrosion,2000,56(2):167-182.
【3】杜海燕,韩阗俐,路民旭,等. 抗CO2腐蚀油气井缓蚀剂的研究与应用[J]. 表面技术,2006,35(1): 77-79.
【4】KERMANI M B,MORSHED A. Carbon dioxide corrosion in oil and gas production-A compendium[J]. Corrosion,2003,59(8):659.
【5】王彬,张静,杜敏. 咪唑啉类缓蚀剂对含饱和CO2的模拟油田采出液中Q235-A钢的缓蚀作用[J]. 中国腐蚀与防护学报,2012,30(1): 16-20.
【6】尹志福,李辉,刘立,等. 模拟CO2驱环境中咪唑啉类缓蚀剂对J55钢腐蚀性能的影响[J]. 腐蚀与防护,2013,34(6): 489-492.
【7】于会华,张静,杜敏. 含咪唑啉磷酸酯的复配缓蚀剂对Q235钢的缓蚀行为研究[J]. 表面技术,2010,39(3): 48-51.
【8】李倩,吕振波,赵杉林. 缓蚀剂咪唑啉季铵盐与烷基磷酸酯在饱和CO2模拟盐水体系中的协同效应[J]. 腐蚀科学与防护技术,2009,21(6): 571-573.
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