Soil Corrosion of Grounding Grid Materials Studied by Same Material Three-electrodes
摘 要
采用电化学阻抗谱(EIS),以同材料三电极为测试体系研究了Q235钢、紫铜和热镀锌钢在土壤中的腐蚀行为,采用金相显微镜观察了腐蚀产物形貌,并比较了紫铜和热镀锌钢的耐蚀性。结果表明,Q235钢发生了较严重的腐蚀,腐蚀产物层疏松,腐蚀介质在产物层中浓缩,造成了Q235钢的点蚀; 紫铜表面生成了致密的灰褐色钝化膜,膜层电阻随时间上升,在第9天时最高,之后维持稳定; 热镀锌钢表面生成了淡黄色的疏松覆盖层,镀层电阻随时间先升后降,在第5天时最大,镀层具有一定的自修复功能。紫铜耐蚀强于热镀锌钢。
Abstract
Corrosion behavior of Q235 steel, red copper and hot dip galvanized (HDG) steel in soil was studied by EIS, using a new kind of same material three-electrode. Morphology of corrosion product was observed by metallographic microscope, and corrosion resistance of red copper and HDG steel was compared. The results showed that Q235 steel was corroded heavily with loose corrosion product layer formed, the steel suffered pitting at later stage due to the concentration of corrosive ions in the product layer. Dust-color compact passive film was formed on the red copper surface, film resistance increased with corrosion time and was stable after a max value at the 9th day. Yellow loose covering layer formed on the urface of red copper. Coating resistance of HDG ateel increased first and decreased later with a max value at the 5th day, self-repairing function was found in the coating. Corrosion resistance of red copper is stranger than that of HDG steel.
中图分类号 TG174.3
所属栏目 试验研究
基金项目 国家电网公司总部科技项目(KG12K16004);湖南省电力公司科技项目(5116AA110005)
收稿日期 2013/10/13
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备注查方林(1988-),助理工程师,硕士,从事金属材料腐蚀与防护,
引用该论文: ZHA Fang-lin,FENG Bing,XU Song. Soil Corrosion of Grounding Grid Materials Studied by Same Material Three-electrodes[J]. Corrosion & Protection, 2014, 35(9): 907
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【3】朱一帆,孙慧珍,万小山,等. 土壤腐蚀测试的一种新型电极[J]. 南京化工大学学报,1995,17: 161-164.
【4】CACHET C,GANNE F,JOIRET S,et al. EIS investigation of Zinc dissolution in aerated sulphate medium.Part II: zinc coatings[J]. Electrochimica Acta,2002,47(21): 3409-3422.
【5】刘焱,伍远辉,罗宿星. SO42-对Q235钢在土壤中腐蚀行为影响的电化学研究[J]. 西南大学学报:自然科学版,2008,30(7): 74-77.
【6】聂向辉,杜翠薇,李晓刚. 温度对Q235钢在大港模拟溶液中腐蚀行为的影响[J]. 腐蚀与防护,2008,29(4): 171-174.
【7】DDFLOFIAN F,ROSSIA S,FEDRIZZI L,et al. EIS study of organic coating on zinc surface pretreated with environmentally friendly products[J]. Prog Org Coat,2005,52(4): 271-279.
【8】徐克,肖书彬,刘艳辉,等. 铝合金微弧氧化膜在高温盐水中的耐蚀性能研究[J]. 中国腐蚀与防护学报,2013,33(1): 17-22.
【9】STEPHEN R Y.Galvanized Steel Reinforcement in Concreter[M]. Oxford: Elsevier,2004:113-118.
【10】孔纲,陈九龙,卢锦堂. 饱和Ca(OH)2溶液pH值对热镀锌钢表面锌酸钙覆盖层的影响[J]. 材料工程,2010,9: 74-79.
【11】林碧兰,卢锦堂,孔纲. 磷化/钼酸盐后处理的热镀锌钢板的电化学行为[J]. 华南理工大学学报:自然科学版,2007,35(8): 93-97.
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