绿色铜缓蚀剂的研究进展
Research Progress of Environment-friendly Inhibitors for Copper
摘 要
随着环保意识的加强, 传统缓蚀剂已经无法满足工业绿色化发展的需要。开发易生物降解、价格低廉、高效的绿色缓蚀剂是近年来铜缓蚀剂研究的热点。结合本课题组在聚天冬氨酸、聚环氧琥珀酸、植酸等方面的研究成果, 对国内外绿色铜缓蚀剂的研究现状进行了概括, 对铜缓蚀剂中存在的问题及未来发展的方向作了分析。
铜
进展
缓蚀
green inhibitor
copper
progress
corrosion inhibition
Abstract
As environmental awareness increases, the traditional corrosion inhibitors are unable to meet the needs of environmentally industrial development. The development of easy biodegradable, cheap and efficient green copper inhibitors becomes a hot issue recently. In this paper, the research progress of green copper inhibitors were summarized, the problems and development directions of copper corrosion inhibitors were analyzed briefly.
中图分类号 TG174.42
所属栏目 专论
基金项目 上海市教委科创重点项目(14ZZ152)
收稿日期 2014/1/24
修改稿日期
网络出版日期
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备注徐群杰(1969-),教授,博士,从事电厂化学,腐蚀电化学研究,13371896005.
引用该论文: LI Mei-ming,XU Qun-jie,HAN Jie,ZHANG Zhi-guo. Research Progress of Environment-friendly Inhibitors for Copper[J]. Corrosion & Protection, 2014, 35(12): 1243
被引情况:
【1】韩 杰,刘 伟,闵宇霖,徐群杰, "金属基合金表面超疏水膜的构筑及其耐蚀性的研究进展",腐蚀与防护 37, 988-993(2016)
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参考文献
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【29】张安定. 一种无毒性防锈剂的实验结果[J]. 腐蚀与防护, 2004,25(11): 497-499.
【30】徐群杰, 齐航, 周小晶, 等. 新型绿色缓蚀剂植酸的研究进展[J]. 腐蚀与防护, 2009,30(2): 75-78.
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【35】郑红艾, 张大全, 沈莉莉, 等. 盐酸介质中精氨酸与抗坏血酸复配对铜的缓蚀作用[J]. 腐蚀与防护, 2010,31(5): 342-346.
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【39】石文艳, 夏媛, 雷武, 等. 5种氨基酸对铁缓蚀剂机理的分子动力学模拟[J]. 中国腐蚀与防护学报, 2011,31(6): 478-484.
【40】赵文涛, 旷富贵, 姚禄安, 等. 表面增强拉曼散射在缓蚀剂作用机理研究中的应用[J]. 材料保护, 1993,26(12): 11-15.
【41】徐群杰, 周国定, 陆柱, 等. 苯并三氮唑及其衍生物在NaCl溶液中对铜缓蚀作用的表面增强拉曼光谱[J]. 应用化学, 2002,19(4): 390-394.
【42】袁亚仙, 姚建林, 顾仁敖, 等. 非水体系中苯并三氮唑在铜电极上吸附的电化学表面增强拉曼光谱研究[J]. 化学学报, 2006,64(4): 273-278.
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【44】YANG H F,YANG Y,YANG Y H,et al. Formation of inositol hexaphosphate monolayers at the copper surface from a Na-salt of phytic acid solution studied by in situ surface enhanced Raman scattering spectroscopy,Raman mapping and polarization measurement[J]. Analytica Chimica Acta,2005,548(1/2):159-165.
【45】徐群杰, 朱律均, 齐航, 等. Cu的腐蚀与缓蚀的光电化学研究[J]. 金属学报, 2008,44(11):1360-1365.
【46】徐群杰, 周国定, 陆柱, 等. 缓蚀剂对铜作用的激光扫描微区光电化学研究[J]. 化学学报, 2000,58(9): 1079-1084.
【47】朱律均, 徐群杰, 曹为民, 等. 聚天冬氨酸与钨酸钠复配对白铜B30的缓蚀作用[J]. 物理化学学报,2008,24(5):805-809.
【48】徐群杰, 单贞华, 朱律均, 等. 聚天冬氨酸与钨酸钠复配对黄铜缓蚀作用的光电化学研究[J]. 化学学报, 2009,67(7): 618-622.
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【2】张大全, 李瑾, 郑红艾. 盐酸介质中谷氨酸对铜的缓蚀作用[J]. 腐蚀与防护, 2010,31(1): 1-4.
【3】CUBILLOS M,SANCY M,PAVEZ J,et al. Influence of 8-aminoquinoline on the corrosion behaviour of copper in 0.1 MNaCl[J]. Electrochimica Acta,2010,55:2782-2792.
【4】ROXANA B,SIMONA V, LUIZA G,et al. Evaluation of some phenothiazine deri-vatives as corrosion inhibitors for bronze in weakly acidic solution[J]. Corrosion Science,2012,63:275-286.
【5】SATOVIC D,VALEKULY L,DESNICA V,et al. Corrosion evaluation and surface characterization of the corrosion product layer formed on Cu-6Sn bronze in aqueous Na2SO4 solution[J]. Corrosion Science,2009,51:1596-1603.
【6】张天胜, 张浩, 高红. 缓蚀剂[M]. 北京: 化工工业出版社, 2008.
【7】MATJZ F,ANTONIJA L,ANTON K,et al. A comparative electrochemical and quantum chemical calculation study of BTAH and BTAOH as copper corrosion inhibitors in near neutral chloride solution[J]. Electrochimica Acta,2008,53:8287-8297.
【8】MILAN M A,SNEANA M. Films formed on copper surface in chloride media in the presence of azoles[J]. Corrosion Science,2009,51:1228-1237.
【9】苏文娜, 靳晓霞, 腾厚开, 等. 环境友好型缓蚀剂的研究进展[J]. 工业水处理, 2009, 29(3): 16-20.
【10】江红, 王连军, 江莞, 等. 绿色化学概念在水处理剂材料中的应用及发展状况[J]. 无机材料学报, 2003,18(5):998-1003.
【11】QIAN B,WANG J,ZHENG M,et al. Synergistic effect of polyaspartic acid and iodide ion on corrosion inhibition of mild steel in H2SO4[J]. Corrosion Science,2013,75:184-192.
【12】周晓蔚, 赵鑫. 聚环氧琥珀酸对铜缓蚀性能的研究[J]. 腐蚀科学与防护技术, 2004,16(3):172-174.
【13】ZHANG W Y,GU H C,XI L J,et al. Preparation of phytic acid and its characteristics as copper inhibitor[J]. Energy Procedia,2012,17:1641-1647.
【14】MAHMOUD N. Chitosan as a green inhibitor for copper corrosion in acidic medium[J]. International Journal of Biological Macromolecules,2013,55:142-149.
【15】FERNANDO S D S,CRISTIANO G,REIANLDO S,et al. Adsorption behavior of caffeine as a green corrosion inhibitor for copper[J]. Materials Science and Engineering C,2012,32:2436-2444.
【16】何蕊, 杜盼盼, 李春梅, 等. 聚天冬氨酸与三聚氰胺复配对铜的协同缓蚀机理[J]. 腐蚀与防护, 2012,33(9): 761-765.
【17】徐群杰, 朱律均, 曹为民, 等. 绿色缓蚀剂聚天冬氨酸对铜的缓蚀性能与吸附行为[J]. 物理化学学报, 2008,24(9): 1724-1728.
【18】QU Q,LI L,BAI W,et al. Sodium tungstate as a corrosion inhibitor of cold rolled steel in peracetic acid solution[J]. Corrosion Science,2009,51:2423-2428.
【19】于静敏, 柳鑫华, 梁英华. 海水中碳钢钨系复合缓蚀剂的研究[J]. 材料保护, 2007,40(2): 17-22.
【20】徐群杰, 董孔祥, 周国定. 聚天冬氨酸和钨酸钠复配对模拟水中铜的缓蚀作用研究[J]. 腐蚀与防护, 2005, 26(10): 415-418.
【21】徐群杰, 周国定, 王会峰, 等. 聚天冬氨酸和钨酸钠复配对3% NaCl溶液中白铜B10的缓蚀作用[J]. 电化学,2006,12(1):65-68.
【22】熊蓉春, 周庆, 魏刚. 绿色阻垢剂聚环氧琥珀酸的缓蚀协同效应[J]. 化工学报, 2003,54(9): 1323-1325.
【23】王静, 高丽丽, 张正, 等. 模拟2倍浓缩海水中聚环氧琥珀酸和Na2MoO4对304不锈钢的缓蚀作用[J]. 材料保护, 2012, 245(1): 61-65.
【24】陈颖敏, 要亚坤, 史亚微, 等. 聚环氧琥珀酸及其复配物的缓蚀性能的研究[J]. 汽轮机技术, 2010,52(5): 395-398.
【25】张建, 李国威, 朱彦荣, 等. 聚环氧琥珀酸及其复配物的缓蚀性能研究[J]. 腐蚀科学与防护技术, 2010,22(3): 128-131.
【26】XU Q J,DING S J,YUN H,et al. Inhibition action and adsorption behavior of PESA on copper[J]. Advanced Materials Research,2011(148/149):1351-1354.
【27】徐群杰, 池国镇, 时士峰, 等. 聚环氧琥珀酸对白铜在3% NaCl溶液中的缓蚀作用[J]. 材料保护, 2011,44(7): 71-75.
【28】TANG F,WANG X Y,XU X J,et al. Phytic acid doped nanoparticles for green anticorrosion coatings[J]. Colloids and Surfaces A:Physicochemical and engineering aspects,2010,369:101-105.
【29】张安定. 一种无毒性防锈剂的实验结果[J]. 腐蚀与防护, 2004,25(11): 497-499.
【30】徐群杰, 齐航, 周小晶, 等. 新型绿色缓蚀剂植酸的研究进展[J]. 腐蚀与防护, 2009,30(2): 75-78.
【31】XU Q J,WAN Z Y,ZHOU G D,et al. Electrochemical and photoelectrochemical study of self-assembled monolayer of phytic acid on brass[J]. Chinese Journal of Chemistry,2008,26(9):1579-1584.
【32】印仁和, 万宗跃, 徐群杰, 等. 植酸自组装单分子膜对白铜B30缓蚀作用的研究[J]. 功能材料, 2007, 38(4): 562-566.
【33】WAHED A B,KHALED M L,AHLAM M F. Corrosion control of Cu-Ni alloys in neutral chloride solutions by amino acids[J]. Electrochimica Acta,2006,51(20):4182-4189.
【34】田会娟, 柳鑫华, 苪玉兰. 氨基酸类绿色酸洗缓蚀剂的研究进展[J]. 腐蚀与防护, 2009,30(3): 186-190.
【35】郑红艾, 张大全, 沈莉莉, 等. 盐酸介质中精氨酸与抗坏血酸复配对铜的缓蚀作用[J]. 腐蚀与防护, 2010,31(5): 342-346.
【36】SAIFI H,BERNARD M C,JOIRET S,et al. Corrosion inhibitive action of cysteine on Cu-30Ni alloy in aerated 0.5 M H2SO4[J]. Materials Chemistry and Physics,2010,120:661-669.
【37】ZHANG D Q,CAI Q R,HE X M,et al. Inhibition effect of some amino acids on copper corrosion in HCl solution[J]. Materials Chemistry and Physics,2008,112:353-358.
【38】BAROUNI K,BAZZI L,SALGHI R,et al. Some amino acids as corrosion inhibitors for copper in nitric acid solution[J]. Materials Letters,2008,62:3325-3327.
【39】石文艳, 夏媛, 雷武, 等. 5种氨基酸对铁缓蚀剂机理的分子动力学模拟[J]. 中国腐蚀与防护学报, 2011,31(6): 478-484.
【40】赵文涛, 旷富贵, 姚禄安, 等. 表面增强拉曼散射在缓蚀剂作用机理研究中的应用[J]. 材料保护, 1993,26(12): 11-15.
【41】徐群杰, 周国定, 陆柱, 等. 苯并三氮唑及其衍生物在NaCl溶液中对铜缓蚀作用的表面增强拉曼光谱[J]. 应用化学, 2002,19(4): 390-394.
【42】袁亚仙, 姚建林, 顾仁敖, 等. 非水体系中苯并三氮唑在铜电极上吸附的电化学表面增强拉曼光谱研究[J]. 化学学报, 2006,64(4): 273-278.
【43】SHEN S,GUO X Y,SONG P,et al. Phytic acid adsorption on the copper surface:Obser-vation of electrochemistry and Raman spectroscopy[J]. Applied Surface Science,2013,276:167-173.
【44】YANG H F,YANG Y,YANG Y H,et al. Formation of inositol hexaphosphate monolayers at the copper surface from a Na-salt of phytic acid solution studied by in situ surface enhanced Raman scattering spectroscopy,Raman mapping and polarization measurement[J]. Analytica Chimica Acta,2005,548(1/2):159-165.
【45】徐群杰, 朱律均, 齐航, 等. Cu的腐蚀与缓蚀的光电化学研究[J]. 金属学报, 2008,44(11):1360-1365.
【46】徐群杰, 周国定, 陆柱, 等. 缓蚀剂对铜作用的激光扫描微区光电化学研究[J]. 化学学报, 2000,58(9): 1079-1084.
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