超声辅助-表面活性剂增强乳化微萃取-气相色谱-质谱法测定薄荷芳香水中的挥发性成分
GC-MS Determination of Volatile Compounds in Aromatic Water from Mentha Haplocalyx Briq. with Ultrasound Assisted-Surfactant Enhanced Emulsification Microextraction
摘 要
提出了基于低密度溶剂超声辅助-表面活性剂增强乳化微萃取-气相色谱-质谱法测定薄荷芳香水中的挥发性成分。优化的试验条件如下:① 萃取剂为甲苯;② 1 mg·L-1吐温 80溶液的用量为30 μL;③ 超声时间为1 min。在气相色谱分离中用DB-5石英毛细管柱为固定相,在质谱分析中采用全扫描检测模式。方法用于薄荷样品的分析,薄荷芳香水中共鉴定出20种挥发性成分,薄荷挥发油中共鉴定出30种挥发性成分,其中所含的主要成分基本一致。
超声辅助
表面活性剂增强乳化微萃取
低密度溶剂
薄荷
GC-MS
Ultrasound assisted
Surfactant enhanced emulsification microextraction
Low density solvent
Mentha haplocalyx Briq.
Abstract
A method of GC-MS for the determination of volatile compounds in aromatic water from Mentha haplocalyx Briq. with low density solvent based ultrasound assisted-surfactant enhanced emulsification microextraction was proposed. The optimized conditions found were as follows: ① extractant: toluene; ② amount of 1 mg·L-1 Tween 80 solution: 30 μL; ③ ultrasound time: 1 min. The DB-5 quartz capillary column was used for GC separation and the full-scanning mode was adopted in MS determination. The proposed method was applied to the analysis of the Mentha haplocalyx Briq. samples. 20 compounds in aromatic water and 30 compounds in volatile oil from Mentha haplocalyx Briq. were identified. Most of the effective compounds existed in the aromatic water was the same as those in volatile oil.
中图分类号 O657.63
所属栏目 试验与研究
基金项目 浙江省本科院校中青年学科带头人学术攀登项目(pd2013016);国家人力资源与社会保障部留学人员科技活动择优资助(优秀类)项目(2011443);浙江省科技厅钱江人才计划资助项目(2010R10044)
收稿日期 2014/1/20
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联系人作者闻亚(lzg@zjut.edu.cn)
备注闻亚(1987-),女,浙江杭州人,硕士研究生,主要从事分析化学的研究工作。
引用该论文: WEN Ya,XU Xin-yi,NIE Jing,LI Zu-guang,WU Xian-wei,DENG Feng-tao. GC-MS Determination of Volatile Compounds in Aromatic Water from Mentha Haplocalyx Briq. with Ultrasound Assisted-Surfactant Enhanced Emulsification Microextraction[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2014, 50(9): 1065～1069
闻亚,徐心怡,聂晶,李祖光,吴先伟,邓丰涛. 超声辅助-表面活性剂增强乳化微萃取-气相色谱-质谱法测定薄荷芳香水中的挥发性成分[J]. 理化检验－化学分册, 2014, 50(9): 1065～1069
被引情况:
【1】郝玉红,吴建军, "气相色谱-质谱法测定硅凝胶中两种硅氧烷",理化检验－化学分册 51, 818-820(2015)
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参考文献
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【2】国家药典委员会.中华人民共和国药典(一部)［M］.北京:中国医药科技出版社, 2010:370-372．
【3】祝祎玮,怀悦,何翠翠.吴药薄荷挥发油成分的GC-MS分析与薄荷醇含量测定［J］.南京中医药大学学报, 2011,27(1):73-76．
【4】吴芳,乔蓉霞,王国海.2011年中国药学大会暨第十一届中国药师周论文集［C］.烟台:中国学术期刊电子杂志出版社, 2011:410-414．
【5】刘玉萍,苏旭.青藏高原野薄荷挥发油成分的气相色谱-质谱分析［J］.江苏农业科学, 2012,40(1):265-266．
【6】ORIO L, CRAVOTTO G, BINELLO A, et al. Hydrodistillation and in situ microwave-generated hydrodistillation of fresh and dried mint leaves: a comparison study［J］. Journal of Science Food Agriculture, 2012,92:3085-3090．
【7】TSAI M L, WU C T, LIN T F, et al. Chemical composition and biological properties of essential oils of two mint species［J］. Tropical Journal of Pharmaceutical Research, 2013,12(4):577-582．
【8】REZAEE M, ASSASI Y, HOSSEINI M R M, et al. Determination of organic compounds in water using dispersive liquid-liquid microextraction［J］. Journal of Chromatography A, 2006,1116:1-9．
【9】焦琳娟.超声提取-动态液相微萃取-气相色谱法测定土豆中有机磷农药［J］.理化检验-化学分册, 2012,48(11):1289-1291．
【10】李刚,张占恩.中空纤维膜液相微萃取-气相色谱-质谱法测定水样中拟除虫菊酯类农药［J］.理化检验-化学分册, 2010,46(3):227-231．
【11】叶朝霞,李莉,胡文凌,等.分散液相微萃取-高效液相色谱法测定水和土壤中多环芳烃［J］.理化检验-化学分册, 2012,48(4):467-470．
【12】刘芃岩,王有旺,李睿.分散液液微萃取-气相色谱法测定塑料浸泡液中17种邻苯二甲酸酯［J］.理化检验-化学分册, 2011,47(12):1380-1383．
【13】SHU Ming-wei, LEONG M I, FUH M R, et al. Determination of endocrine-disrupting phenols in water samples by a new manual shaking-enhanced, ultrasound-assisted emulsification microextraction method［J］. Analyst, 2012,137:2143-2150．
【14】RAMKUMAR A, PONNUSAMY V K, JEN J F. Rapid analysis of chlorinated anilines in environmental water samples using ultrasound assisted emulsification microextraction with solidification of floating organic droplet followed by HPLC-UV detection［J］. Talanta, 2012,97:279-284．
【15】SERESHTI H, ROHANIFAR A, BAKHTIARI S, et al. Bifunctional ultrasound assisted extraction and determination of Elettaria cardamomum Maton essential oil［J］. Journal of Chromatography A, 2012,1238:46-53．
【16】林海禄,彭雪娇,闫红.离子液体液相微萃取-气相色谱法测定水果中3种有机磷农药残留［J］.理化检验-化学分册, 2011,47(12):1440-1442．
【17】YIANTZI E, PSILLAKIS E, TYROVILA K, et al. Vortex-assisted liquid -liquid microextraction of octylphenol, nonylphenol and bisphenol-A［J］. Talanta, 2010,80:2057-2062．
【18】CHEN Hao, CHEN Rui-wen, LI Sheng-qing. Low-density extraction solvent-based solvent terminated dispersive liquid-liquid microextraction combined with gas chromatography-tandem mass spectrometry for the determination of carbamate pesticides in water samples［J］. Journal of Chromatography A, 2010,1217:1244-1248．
【19】WU Qiu-hua, CHANG Qing-yun, WU Chun-xia, et al. Ultrasound-assisted surfactant-enhanced emulsification microextraction for the determination of carbamate pesticides in water samples by high performance liquid chromatography［J］. Journal of Chromatography A, 2010,1217:1773-1778．
【20】LI Yee, CHEN Pai-shan, HUANG Shang-da. Water with low concentration of surfactant in dispersed solvent-assisted emulsion dispersive liquid-liquid microextraction for the determination of organochlorine pesticides in aqueous samples［J］. Journal of Chromatography A, 2013,1300:51-57．
【21】YANG Zhong-hua, LU Yue-le, LIU Yu, et al. Vortex-assisted surfactant-enhanced-emulsification liquid-liquid microextraction［J］. Journal of Chromatography A, 2011,1218:7071-7077．
【22】ZHANG Yu-feng, LEE H K. Low-density solvent-based vortex-assisted surfactant-enhanced-emulsification liquid-liquid microextraction combined with gas chromategramphy-mass spectrometry for the fast determination of phthalate esters in bottled water［J］. Journal of Chromatography A, 2013,1274:28-35．
【23】CIRIN D M, POSA M M, KRSTONOSIC V S, et al. Conductometric study of sodium dodecyl sulfate-nonionic surfactant (Triton X-100, Tween 20, Tween 60, Tween 80 or Tween 85) mixed micelles in aqueous solution［J］. Hemijskaindustrija, 2012,66(1):21-28．
【24】苏越,王呈仲,郭寅龙.基于准确质量测定和保留指数的GC-MS分析薄荷挥发性成分［J］.化学学报, 2009,67(6):546-554．
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