电子能量的基本原理及其在材料研究中的应用
Basic Principle and Applications of EELS in Study of Material Science
摘 要
电子能量损失谱(EELS)是一种集材料元素分析和元素成像为一体的现代分析技术, 由于其分析精度高、对碳、氮、氧、硼等轻元素敏感, 因此被越来越多地应用于材料研究领域, 并且由于EELS能反映原子外层的电子状态, 还可被用于原子价态变化分析。介绍了EELS的基本原理、基本组成、基本功能以及在材料研究中的应用。结合与其他分析技术之间的比较, 对EELS技术在材料研究中的作用进行了评价。
基本原理
应用
材料元素分析
厚度测量
electron energy lose spectroscopy
basic principle
applications
material elements analysis
thickness measurement
Abstract
Electron energy lose spectroscopy (EELS) is a kind of modern analysis technology integrated material elements analysis with elemental imaging. Due to high accuracy and high sensitivity to C, N, O, B and other light elements, EELS is widely used in the material research. Besides, due to the characteristics of being able to reflect the outer electron atom state of elements, EELS can also be used for the atomic valence analysis. The basic principle, component, function and application of EELS in the material research have been introduced. Furthermore, the advantages of EELS technology in the study of materials science have been evaluated compared with other analysis technique.
中图分类号 TH838+.6
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收稿日期 2013/2/27
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备注杨云(1988-), 女, 博士研究生。
引用该论文: YANG Yun,SONG Xi-ping. Basic Principle and Applications of EELS in Study of Material Science[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2014, 50(1): 19～24
杨云,宋西平. 电子能量的基本原理及其在材料研究中的应用[J]. 理化检验－物理分册, 2014, 50(1): 19～24
被引情况:
【1】李霞章,DENG Fei,NI Chao-ying,陈志刚, "原位透射电子显微术研究进展",理化检验－物理分册 51, 225-228(2015)
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参考文献
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【4】进藤大辅,及川哲夫合.材料评价的分析电子显微方法[M].刘安生,译.北京: 冶金工业出版社,2001.
【5】朱静,叶恒强,王仁卉.高空间分辨分析电子显微学[M].北京:科学出版社,1987.
【6】王永瑞,邹骥,卢党吾.电子能量损失谱学及其在材料科学中的应用[J].物理,1994,23(6):350-356.
【7】PORCU M, PETFORD-LONG A K, SYKES J M. TEM studies of Nb2O5 catalyst in ball-milled MgH2 for hydrogen storage[J].Alloys and Compounds,2008,453(1):341-346.
【8】王永瑞,邹骇,卢党吾,等.电子能量损失谱低能谱区的分析和应用[J].电子显微学报,1993,3:262-266.
【9】张丽娜,马钺,章晓中.CSP工艺生产的新一代普通碳素钢中纳米析出相的透射电镜研究[C]//2003中国钢铁年会论文集.北京: 中国金属学会,2003:595-598.
【10】SUN BAO-Yun, SATO Yuta, SUENAGA Kazutomo. Entrapping of exohedral metallofullerenes in carbon nanotubes:(CsC60)n@SWNT nano-peapods[J].Journal of America Chemistry Society,2005,127:17972-17973.
【11】秦艳,张晓娜,郑坤.非晶SiO2纳米线的合成及其显微结构和光学性质的研究[J].电子显微学报,2008,4:102-106.
【12】NI Na, LOZANO-PEREZ Sergio, SYKES John, et al. Quantitative EELS analysis of zirconium alloy metal/oxide interfaces[J].Ultramicroscopy,2011,112(2):123-130.
【13】鲁占灵,张兵临,姚宁.非晶碳膜中sp2和sp3相的检测方法[J].材料导报,2006,20(6):98-101.
【14】WANG Feng, GRAETZ Jason, MORENO M S, et al. Chemical distribution and bonding of lithium in intercalated graphite: identification with optimized electron energy loss spectroscopy[J].Acsnano,2011,5(2):1190-1197.
【15】AGUIRRE M H, SHKABKO Andrey, WEIDENKAFF Anke. Microwave plasma nitridation of SrTiO3: a quantitative EELS, TEM and STEM-HAADF analysis of the SrTiO3-xNy growth and the structural evolution[J].Crystal Growth & Design,2010,10(8):3562-3567.
【16】NAGUIB Nevin, YE Haihui, GOGOTSI Yury. Observation of water confined in nanometer channels of closed carbon nanotubes[J].Nano Lett,2004,4(11):2237-2243.
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