Corrosion of Pipeline Steel in Dry and Wet Alternative Environment
摘 要
在模拟土壤的NS4溶液中, 采用腐蚀失重、极化曲线和产物形貌观察等方法研究了X80钢在干湿交替环境下的腐蚀行为。结果表明, 腐蚀速率随干/湿交替时间比降低先增加后减小, 当干/湿交替时间比为9 h/15 h时, 腐蚀速率最高, 为全浸腐蚀速率的1.8倍; 在此条件下, 腐蚀速率随pH值增大而降低; 随着Cl-浓度增大, 腐蚀速率先降低后增加; 采用灰关联度法分析影响间浸腐蚀的因素排序为干/湿交替时间>pH值>Cl-浓度。
Abstract
Corrosion behaviors of X80 steel in alternating wet and dry environment were studied by the means of weight loss, electrochemical polarization curves and morphology observation in the NS4 solution. The results showed that the corrosion rate first increased and then decreased with decreasing the time ratio of dry to wet. When the time ratio of dry to wet was 9 h/15 h, the corrosion rate reached 0.56 mm/a which was 1.8 times of the corrosion rate under the condition of full immersion. Under the condition of interval immersion, the corrosion rate decreased with pH value increase. As the concentration of Cl- increased, the corrosion rate first decreased and then increased. The influence sequence on the interval immersion corrosion was time of wet-dry alternating, pH and Cl- concentration on the basis of analysis using gray relational theory.
中图分类号 TG172.4
所属栏目 试验研究
基金项目 西南石油大学中青年学术骨干教师计划与校级自然科技基金(2007XJZ036)
收稿日期 2010/6/9
修改稿日期 2010/7/2
网络出版日期
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备注任呈强, 副教授,
引用该论文: REN Cheng-qiang,LI Li,WANG Xu,LIU Li,LIU Tao. Corrosion of Pipeline Steel in Dry and Wet Alternative Environment[J]. Corrosion & Protection, 2011, 32(4): 272
被引情况:
【1】徐士祺, "温度对油田注水管道内电化学腐蚀的影响",腐蚀与防护 36, 226-229(2015)
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【3】Carlos Alberto M Ferreira, Jose A C Ponciano, Delmo Santiago Vaitsman, et al. Evaluation of the corrosivity of the soil through its chemical composition[J]. The Science of the Total Environment, 2007, 388(1):250-255.
【4】Benmoussa A, Hadjel M, Traisnel M. Corrosion behavior of API 5L X60 pipeline steel exposed to near neutral pH soil simulating solution[J]. Materials and Corrosion, 2006, 57(10):771-777.
【5】Capelle J, Gilgert J, Dmytrakh I, et al. Sensitivity of pipelines with steel API X52 to hydrogen embrittlement[J]. International Journal of Hydrogen Energy, 2008, 33(24):7630-7641.
【6】Fang B Y, Han E N, Wang J Q, et al. Stress corrosion cracking of X-70 pipeline steel in near neutral pH solution subjected to constant load and cyclic load testing[J]. Corrosion Engineering, Science and Technology, 2006, 42(2):123-129.
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【8】梁平, 李晓刚, 杜翠薇, 等. 影响埋地X70管线钢腐蚀性的土壤因素评价[J]. 腐蚀与防护, 2009, 30(8): 526-530.
【9】Hong K, Hooton R D. Effects of cyclic chloride exposure on penetration of concrete cover[J]. Cement and Concrete Research, 1999, 29(9):1379-1386.
【10】胥聪敏. X80管线钢在模拟盐碱土壤介质中的电化学腐蚀行为研究[J]. 材料工程, 2009(9): 66-70.
【11】胥聪敏, 霍春勇, 熊庆人, 等. X80管线钢在酸性土壤模拟溶液中的腐蚀行为研究[J]. 机械工程材料, 2009, 33(5): 29-32.
【12】顾家琳, 闫睿, 久本淳, 等. 碳钢在青岛不同暴露方式下的大气腐蚀[J]. 材料工程, 2009(12): 37-41.
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【15】梁平, 杜翠薇, 李晓刚, 等. X70管线钢在鹰潭土壤模拟溶液中腐蚀因素灰关联分析[J]. 腐蚀与防护, 2009, 30(4):231-233.
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