金属表面席夫碱缓蚀剂自组装膜的制备及性能研究现状
Research Status of Preparation and Properties of Self-assembled Monolayers of Schiff Base on Metal Surface
摘 要
席夫碱是由伯胺与活性羰基缩合而成的含有甲亚胺活性基团-RC=N-的一类有机化合物, 能在金属表面发生化学吸附反应而形成结构稳定、排列紧密有序的自组装膜(SAMs); SAMs是一种有缓蚀性能的单分子膜, 对基底金属有良好的防腐蚀作用。本文综述了近年来席夫碱类自组装膜的制备方法及自组装膜的表征技术, 进一步概述了分子模拟及拓扑结构在腐蚀防护研究中的应用现状, 展望了自组装膜的应用前景。
自组装膜
席夫碱
制备
缓蚀
量子化学
metal
self-assembled monolayer
schiff base
preparation
corrosion inhibition
quantum chemistry
Abstract
Shiff bases are a class of organic compounds containing azomethine active groups-RC=N-, synthesized by the condensation of primary amine and active carbonyl. Shiff bases could form self-assembled monolayers (SAMs) through chemical adsorption on metal surface, stable and compactly arranged. SAMs are corrosion inhibition molecular films and have good corrosion resistance for the metal substrate. The methods of preparation and characterization of self-assembled monolayers (SAMs) are reviewed, the application status of the molecular modeling and topological structure in the corrosion protection are outlined, and the prospect of self-assembled monolayers (SAMs)are outlooked.
中图分类号 TG174.42
所属栏目 综述
基金项目 广西高校优秀人才资助计划项目(No.RC2007021); 广西研究生教育创新计划项目(2009105960817M22); 广西研究生教育创新人才联合培养基地项目
收稿日期 2010/6/3
修改稿日期 2010/9/2
网络出版日期
作者单位点击查看
联系人作者刘峥(lisa4.6@163.com)
备注刘峥, 教授, 博士,
引用该论文: CHEN Shi-liang,LIU Zheng,ZHANG Xiao-ge. Research Status of Preparation and Properties of Self-assembled Monolayers of Schiff Base on Metal Surface[J]. Corrosion & Protection, 2011, 32(4): 326
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参考文献
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【2】廖强强, 岳忠文, 朱忠伟, 等. 吡咯烷二硫代氨基甲酸铵自组装膜对铜的缓蚀作用[J]. 物理化学学报, 2009, 25(8):1655-1661.
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【4】Kunitsugu Aramaki, Tadashi Shimura. An ultrathin polymer coating of carboxylate self-assembled monolayer adsorbed on passivated iron to prevent iron corrosion in 0.1 M Na2SO4[J]. Corrosion Science, 2010, 52(1):1-6.
【5】Desai S B, DesaiK R. Synthesis of some Schiff base thiozolidinones and azetidinones from 2, 6-di-aminobozol[l, 2d:-4, 5-d']bisthiazole and their antieancer activities[J]. Herercycle Commum, 2001, 7(1):83-90.
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【9】Yue H J, Zhang D, Shi Z, et al. Synthesis and characterization of two oxovanadium (IV)Schiff base complexes derived from amino acids and pyridoxal[J]. Solid State Sciences, 2006, 8(11):1368-1372.
【10】Yong L, Huanh J L, Lian B, et al. Synthesis of titanium(Ⅳ) complexes with Schiff bases ligand and theircatalyic activities for polymerization of ethylene and etyrene[J]. Chinese Journal of Chemistry, 2001, 19(4):429-432.
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【18】全贞兰, 陈慎豪, 华兰, 等. 希夫碱在铜表面上的自组装膜的STM和XPS研究[J]. 科学通报, 2001, 46(19):1618-1621.
【19】De Sheng Kong, Li J W. Self-assembled monolayer of a schiff base on Au(111) surface:an electrochemistry and electrochemical STM study[J]. Electrochim Acta, 2002, 48(4):303-309.
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【21】Nabel A Negm, Mohamed F Zaki. Corrosion inhibition efficiency of nonionic Schiff base amphiphiles of p-aminobenzoic acid for aluminum in 4N HCl[J]. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 322:97-102.
【22】Martinez S, Stagljar I. Correlation between the molecular structure and the corrosion inhibition efficiency of chestnut tannin in acidic solutions[J]. J Mol Struct.(Theochem.), 2003, 640:167-174.
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【24】曾文, 林志东. 香兰素Schiff碱及其异构体分子特性的预测研究[J]. 计算机与应用化学, 2008, 25(2):205-208.
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【26】王刚, 李爱秀, 朱华玲, 等. PMBP缩氨基酸酯类席夫碱的量子化学研究[J]. 武警医学院学报, 2009, 18(3):175-183.
【2】廖强强, 岳忠文, 朱忠伟, 等. 吡咯烷二硫代氨基甲酸铵自组装膜对铜的缓蚀作用[J]. 物理化学学报, 2009, 25(8):1655-1661.
【3】Zhou J J, Chen S H, Zhang L, et al. Studies of protection of self-assembled films by 2-mercapto-5-methyl-1, 3, 4-thiadiazole on iron surface in 0.1 M H2SO4 solutions[J]. Journal of Electroanalytical Chemistry, 2008, 612(2/15):257-268.
【4】Kunitsugu Aramaki, Tadashi Shimura. An ultrathin polymer coating of carboxylate self-assembled monolayer adsorbed on passivated iron to prevent iron corrosion in 0.1 M Na2SO4[J]. Corrosion Science, 2010, 52(1):1-6.
【5】Desai S B, DesaiK R. Synthesis of some Schiff base thiozolidinones and azetidinones from 2, 6-di-aminobozol[l, 2d:-4, 5-d']bisthiazole and their antieancer activities[J]. Herercycle Commum, 2001, 7(1):83-90.
【6】Ehteshamzade M, Shahrabia T G, Hosse M. Inhibition of copper corosion by seif-assmebled films of new Schiff bases and their modification with alkanethiols in aqueous medium[J]. Applied Surface Science, 2006, 252:2949-2959.
【7】Quan Z L, Chen S L, Li S L. Protection of copper corrosion by modification of self-assembled films of Schiff bases with alkanethiol[J]. Corrosion Science, 2001, 43:1071-1080.
【8】Zhang D, Zang Z P, Zhou X Y, et al. A selective fluorescence probe for yttrium(III) based on acylhydrazone Schiff base[J]. Inorganic Chemistry Communications, 2009, 12:1154-1156.
【9】Yue H J, Zhang D, Shi Z, et al. Synthesis and characterization of two oxovanadium (IV)Schiff base complexes derived from amino acids and pyridoxal[J]. Solid State Sciences, 2006, 8(11):1368-1372.
【10】Yong L, Huanh J L, Lian B, et al. Synthesis of titanium(Ⅳ) complexes with Schiff bases ligand and theircatalyic activities for polymerization of ethylene and etyrene[J]. Chinese Journal of Chemistry, 2001, 19(4):429-432.
【11】袁泽利, 玉孪, 吴庆, 等. 含邻氨基苯甲酸新型三核席夫碱化合物的合成与表征[J]. 化学世界, 2009(6):324-327.
【12】洪涌, 肖静怡, 陈世平, 等. 取代芳香醛缩芳香胺双席夫碱的合成及谱学性质[J]. 有机化学, 2008, 28(8):1404-2409.
【13】李建平, 吉彦, 刘锐杰, 等. 微波无溶剂法合成香草醛氨基酸席夫碱[J]. 化学研究与应用, 2008, 20(1):87-89.
【14】郭文娟. 铜、铁表面组装磷酸酯类缓蚀功能分子膜实验技术的研究[D]. 济南:山东大学博士学位论文, 2007.
【15】马洪芳. 钢、铁表面缓蚀功能膜的研究[D]. 济南:山东大学博士学位论文, 2006.
【16】丁克强, 贾振斌, 王庆飞, 等. 带有巯基的席夫碱在金电极表面的自组装成膜[J]. 四川大学学报(自然科学版), 2001, 38(4):545-548.
【17】Lis L Chen, Lei S H. Investiqation on some Schiff base, as HCl corrosion inhibitors for copper[J]. Corrosion Science, 1999, 41(3):1273-1287.
【18】全贞兰, 陈慎豪, 华兰, 等. 希夫碱在铜表面上的自组装膜的STM和XPS研究[J]. 科学通报, 2001, 46(19):1618-1621.
【19】De Sheng Kong, Li J W. Self-assembled monolayer of a schiff base on Au(111) surface:an electrochemistry and electrochemical STM study[J]. Electrochim Acta, 2002, 48(4):303-309.
【20】Quan Z L, Chen S H, Li Y, et al. Adsorption behaviour of Schiff base and corrosion protection of resulting films to copper substrate[J]. Corrosion Science, 2002, 44(4):703-715.
【21】Nabel A Negm, Mohamed F Zaki. Corrosion inhibition efficiency of nonionic Schiff base amphiphiles of p-aminobenzoic acid for aluminum in 4N HCl[J]. Colloids and Surfaces A: Physicochem. Eng. Aspects, 2008, 322:97-102.
【22】Martinez S, Stagljar I. Correlation between the molecular structure and the corrosion inhibition efficiency of chestnut tannin in acidic solutions[J]. J Mol Struct.(Theochem.), 2003, 640:167-174.
【23】Lashgari M, Arshadi M R, Parsafar Gh A. A simple and fast method for comparison of corrosion inhibition powers between pairs of pyridine derivative molecules[J]. Corrosion, 2005, 61(8):778-783.
【24】曾文, 林志东. 香兰素Schiff碱及其异构体分子特性的预测研究[J]. 计算机与应用化学, 2008, 25(2):205-208.
【25】王国瑞. 取代吡啶甲酰腙席夫碱的合成、表征及其缓蚀行为研究[D]. 桂林理工大学, 2010.
【26】王刚, 李爱秀, 朱华玲, 等. PMBP缩氨基酸酯类席夫碱的量子化学研究[J]. 武警医学院学报, 2009, 18(3):175-183.
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