超临界CO2条件下钢的腐蚀行为研究进展
Review on Corrosion Behaviors of Steels under Supercritical CO2 Condition
摘 要
低压CO2腐蚀规律已经被人们广泛认识, 而超临界CO2腐蚀方面的研究却非常有限。国内外的研究主要集中在钢在超临界CO2环境中的腐蚀速率、腐蚀产物膜的结构、形貌、组成及电化学行为等。然而, 现有的研究均未涉及到超临界CO2腐蚀机理问题。本文综述了目前国内外超临界CO2条件下钢的腐蚀行为的研究成果, 指出了现有研究中的不足, 并对超临界CO2腐蚀的研究前景进行了展望, 期望能对科研工作者全面了解超临界CO2腐蚀提供参考和借鉴, 并能够为油气工业中管道的选材提供理论指导。
不锈钢
超临界CO2
腐蚀
缓蚀剂
carbon steel
stainless steel
supercritical CO2
corrosion
inhibitor
Abstract
The CO2 corrosion under low partial pressure has been recognized widely, but the researches on supercritical carbon dioxide (SC CO2) corrosion were very limited. By far, investigations on steel corrosion under SC CO2 conditions were mainly about the corrosion rate, structure, morphology and composition of corrosion scales, and the electrochemical behaviors. However, present studies were not related to the corrosion mechanism in SC CO2. This paper reviews the research results on corrosion behaviors of steel under supercritical CO2 conditions, points out the shortcomings in the present investigations and finally looks forward to the research prospects on supercritical CO2 corrosion. It is expected that this paper can not only provide reference for the workers in the field of supercritical CO2 corrosion, but also be served as a theoretical guidance for materials selection in oil and gas industry.
中图分类号 TG172
所属栏目 专论
基金项目
收稿日期 2011/4/16
修改稿日期 2011/5/29
网络出版日期
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备注高克玮, 教授,
引用该论文: ZHANG Yu-cheng,QU Shao-peng,PANG Xiao-lu,GAO Ke-wei. Review on Corrosion Behaviors of Steels under Supercritical CO2 Condition[J]. Corrosion & Protection, 2011, 32(11): 854
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参考文献
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【2】Kermani M B, Morshed A. Carbon dioxide corrosion in oil and gas production[J]. Corrosion, 2003, 59(8):659-681.
【3】赵国仙, 严密林. 石油天然气工业中CO2腐蚀的研究进展[J]. 腐蚀与防护, 1998, 19(2):51-54.
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【5】陈立强, 陈长风, 刘瑞刚, 等. 凝析气田多相流环境下常用油套管钢的CO2腐蚀规律[J]. 腐蚀与防护, 2010, 31(12):929-932.
【6】Gulbrandsen E, Bilkova K. Solution chemistry effects on corrosion of carbon steels in presence of CO2 and acetic acid[C]. Corrosion/2006, Houston/TX:NACE International, 2006, Paper No.06364.
【7】周兰花, 董玉华, 陈长风, 等. 常用集输管线钢在CO2多相流中的腐蚀行为[J]. 腐蚀与防护, 2009, 30(8):538-541.
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【11】Palacios C A, Shadley J K. Characteristics of corrosion scales on steel in a corrosion saturated naice arine[J]. Corrosion, 1991, 47(2):122-127.
【12】李廷取, 吴化, 李雪松. 天然气输气管线钢的CO2 腐蚀行为[J]. 腐蚀与防护, 2008, 29(5):260-263.
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【15】Choi Y S, Nesic S. Corrosion behaviour of carbon steel in supercritical CO2-Water Environments[C]//Corrosion/2009, Houston/TX:NACE International, 2009, Paper No.09256.
【16】Zhang Y C, Gao K W, Schmitt G. Water effect on steel corrosion under supercritical CO2 conditions[C]//Corrosion/2011, Houston/TX:NACE International, 2011, Paper No.11378.
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【19】Schremp F W, Roberson G R. Effect of supercritical carbon dioxide (CO2) on construction materials [J]. Journal Society of Petroleum Engineers, 1975(15):227-233.
【20】Newton L E Jr. Sacroc CO2 project corrosion problems and solution[C]//Corrosion/84, Houston/TX:NACE International, 1984, Paper No.67.
【21】Choi Y S, Nesic S. Effect of impurities on the corrosion behaviour of carbon steel in supercritical CO2-water environments[C]//Corrosion/2010, Houston/TX:NACE International, 2010, Paper No.10196.
【22】Cui Z D, Wu S L, Zhu S L, et al. Study on corrosion properties of pipelines in simulated produced water saturated with supercritical CO2[J]. Applied Surface Science, 2006, 252:2368-2374.
【23】李春福, 王斌, 代加林, 等. P110 钢高温高压下CO2 腐蚀产物组织结构及电化学研究[J]. 材料热处理学报, 2006, 27(5):73-78.
【24】Craig B. Corrosion in oil/water systems[J]. Materials Performance, 1996, 8:61-62.
【25】Cui Z D, Wu S L, Li C F, et al. Corrosion behavior of oil tube steels under conditions of multiphase flow saturated with supercritical carbon dioxide[J]. Materials Letters, 2004, 58:1035-1040.
【26】Kongshaug K O, Seiersten M. Baseline experiments for the modelling of corrosion at high CO2 pressure[C]//Corrosion/2004, Houston/TX:NACE International, 2004, Paper No.04630.
【27】Thodla R, Ayello F, Sridhar N. Materials performance in supercritical CO2 environments[C]//Corrosion/2009, Houston/TX:NACE International, 2009, Paper No.09255.
【28】Zhang Y C, Gao K W, Schmitt G. Inhibition of steel corrosion under aqueous supercritical CO2 conditions[C]//Corrosion/2011, Houston/TX:NACE International, 2011, Paper No.11379.
【29】Choi Y S, Nesic S, Young D. Effect of impurities on the corrosion behavior of CO2 transmission pipeline steel in supercritical CO2-water environments[J]. Environmental Science & Technology, 2010, 44(23):9233-9238.
【2】Kermani M B, Morshed A. Carbon dioxide corrosion in oil and gas production[J]. Corrosion, 2003, 59(8):659-681.
【3】赵国仙, 严密林. 石油天然气工业中CO2腐蚀的研究进展[J]. 腐蚀与防护, 1998, 19(2):51-54.
【4】Dugstadt A. Fundamental aspects of CO2 metal loss corrosion-part I:Mechanism[C]//Corrosion/2006, Houston/TX:NACE International, 2006, Paper No.06111.
【5】陈立强, 陈长风, 刘瑞刚, 等. 凝析气田多相流环境下常用油套管钢的CO2腐蚀规律[J]. 腐蚀与防护, 2010, 31(12):929-932.
【6】Gulbrandsen E, Bilkova K. Solution chemistry effects on corrosion of carbon steels in presence of CO2 and acetic acid[C]. Corrosion/2006, Houston/TX:NACE International, 2006, Paper No.06364.
【7】周兰花, 董玉华, 陈长风, 等. 常用集输管线钢在CO2多相流中的腐蚀行为[J]. 腐蚀与防护, 2009, 30(8):538-541.
【8】Gao M, Pang X, Gao K. The growth mechanism of CO2 corrosion product films[J]. Corrosion Science, 2011, 53:557-568.
【9】柴成文, 张国安, 路民旭. X65 钢在CO2 饱和油田水中的电化学行为和腐蚀机理[J]. 腐蚀与防护, 2008, 29(2):55-58.
【10】Nesic S, Lee K L J. A mechanistic model for carbon dioxide corrosion of mild steel in the presence of protective iron carbonate films[J]. Corrosion Science, 2003, 6:616-628.
【11】Palacios C A, Shadley J K. Characteristics of corrosion scales on steel in a corrosion saturated naice arine[J]. Corrosion, 1991, 47(2):122-127.
【12】李廷取, 吴化, 李雪松. 天然气输气管线钢的CO2 腐蚀行为[J]. 腐蚀与防护, 2008, 29(5):260-263.
【13】中国腐蚀与防护学会. 腐蚀科学与防腐蚀工程技术新进展[M]. 北京:化工出版社, 1999:274.
【14】King M B, Mubarak A, Kim J D, et al. The mutual solubilities of water with supercritical and liquid carbon dioxide[J]. The Journal of Supercritical Fluids, 1992, 5:296-302.
【15】Choi Y S, Nesic S. Corrosion behaviour of carbon steel in supercritical CO2-Water Environments[C]//Corrosion/2009, Houston/TX:NACE International, 2009, Paper No.09256.
【16】Zhang Y C, Gao K W, Schmitt G. Water effect on steel corrosion under supercritical CO2 conditions[C]//Corrosion/2011, Houston/TX:NACE International, 2011, Paper No.11378.
【17】韩布兴著. 超临界流体科学与技术[M]. 北京:中国石化出版社, 2005:1-2.
【18】Russick E M, Poulter G A, Adkins C L J, et al. Corrosive effects of supercritical carbon dioxide and cosolvents on metals[J]. The Journal of Supercritical Fluids, 1996, 9:43-50.
【19】Schremp F W, Roberson G R. Effect of supercritical carbon dioxide (CO2) on construction materials [J]. Journal Society of Petroleum Engineers, 1975(15):227-233.
【20】Newton L E Jr. Sacroc CO2 project corrosion problems and solution[C]//Corrosion/84, Houston/TX:NACE International, 1984, Paper No.67.
【21】Choi Y S, Nesic S. Effect of impurities on the corrosion behaviour of carbon steel in supercritical CO2-water environments[C]//Corrosion/2010, Houston/TX:NACE International, 2010, Paper No.10196.
【22】Cui Z D, Wu S L, Zhu S L, et al. Study on corrosion properties of pipelines in simulated produced water saturated with supercritical CO2[J]. Applied Surface Science, 2006, 252:2368-2374.
【23】李春福, 王斌, 代加林, 等. P110 钢高温高压下CO2 腐蚀产物组织结构及电化学研究[J]. 材料热处理学报, 2006, 27(5):73-78.
【24】Craig B. Corrosion in oil/water systems[J]. Materials Performance, 1996, 8:61-62.
【25】Cui Z D, Wu S L, Li C F, et al. Corrosion behavior of oil tube steels under conditions of multiphase flow saturated with supercritical carbon dioxide[J]. Materials Letters, 2004, 58:1035-1040.
【26】Kongshaug K O, Seiersten M. Baseline experiments for the modelling of corrosion at high CO2 pressure[C]//Corrosion/2004, Houston/TX:NACE International, 2004, Paper No.04630.
【27】Thodla R, Ayello F, Sridhar N. Materials performance in supercritical CO2 environments[C]//Corrosion/2009, Houston/TX:NACE International, 2009, Paper No.09255.
【28】Zhang Y C, Gao K W, Schmitt G. Inhibition of steel corrosion under aqueous supercritical CO2 conditions[C]//Corrosion/2011, Houston/TX:NACE International, 2011, Paper No.11379.
【29】Choi Y S, Nesic S, Young D. Effect of impurities on the corrosion behavior of CO2 transmission pipeline steel in supercritical CO2-water environments[J]. Environmental Science & Technology, 2010, 44(23):9233-9238.
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