三价铬黑色钝化工艺的研究进展
Research Advances of Trivalent Chromium Black Passivation Process
摘 要
根据对近几年国内外最新专利文献资料的总结归纳, 先介绍了镀锌层三价铬黑色钝化液的主要组分、膜层的耐蚀机理及其性能特点, 再系统地综述了一些已公开的三价铬黑色钝化液配方。将三价铬黑色钝化工艺与无铬钝化工艺的优势结合起来研究必将是完全替代铬酸盐黑色钝化的重要趋势。
三价铬
六价铬
无铬钝化
黑色钝化
耐蚀性
galvanization
Cr(Ⅲ)
Cr(Ⅵ)
non-chromate passivation
black passivation
corrosion resistance
Abstract
Based on references from abroad and home, the main composition and mechanism of trivalent chromium solution, as well as film properties and characteristics are reported firstly. Some typical trivalent chromium black passivation technologies are introduced systemically. As hexavalent chromium is a high toxicity material, the trivalent chromium black passivation with non-chromate passivation should be widely investigated together in order to replace hexavalent black passivation.
中图分类号 TG174.44
所属栏目 专论
基金项目
收稿日期 2011/1/22
修改稿日期 2011/2/16
网络出版日期
作者单位点击查看
引用该论文: KE Chang-mei,ZHOU Li-qin,HU Yong,WANG Quan-quan,ZHANG Jin-long,WANG Zhen-zhong. Research Advances of Trivalent Chromium Black Passivation Process[J]. Corrosion & Protection, 2011, 32(11): 859
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参考文献
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【9】Tang, Bhatia, Parkos, et al. Stability additive for trivalent chrome conversion coating bath solution[P]. US Pat:6648986, 2003-11-18.
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【23】Tomitaka Yamamoto, Michimasa Yoshida, Satoshi Shimamune. Agent for reducing conversion film overall friction coefficient for trivalent chromate treating solution, trivalent chromate treating solution and method for production thereof, and trivalent chromate conversion film reduced in overall friction coefficient and method for production thereof[P]. US Pat:2007/0023104A1, 2007-02-01.
【24】Horie Hidekazu, Isozaki Satoyuki, Noto Naomi. Black film agent, and method of forming black film[P]. US Pat:2005/206872, 2005-08-04.
【25】Manabu Inoue. Aqueous treating solution for forming black trivalent-chromium chemical conversion coating on zinc or zinc alloy and method of forming black trivalent-chromium chemical conversion coating[P]. US, 2009/0020185A1, 2009-01-22.
【26】任艳萍, 陈锦虹. 镀锌层三价铬钝化工艺的研究[J]. 腐蚀与防护, 2007, 28(1):13-16, 19.
【27】闫磊, 张英杰, 范云鹰. 锌及锌合金镀层无铬钝化研究进展[J]. 电镀与环保, 2007, 27(5):1-5.
【28】肖鑫, 钟萍, 易翔. 一种新型镀锌层无铬钝化工艺[J]. 腐蚀与防护, 2007, 28(9):467-469.
【29】刘艳荣, 周婉秋, 赵强, 等. 镀锌板表面无铬钝化的研究进展[J]. 电镀与精饰, 2010, 32(4):22-26.
【2】沈品华, 屠振密著. 电镀锌及锌合金[M]. 北京: 机械工业出版社, 2002.
【3】Ernest John Wilhelm, Palmerton Pa. Method of coating zinc or cadmium base metals[P]. US Pat:2035380, 1936-03-24.
【4】Nabil Z. Trivalent chromate conversion coating for zinc and zinc alloys[C]//Metal Finishing Guidebook & Directory, New York, 2002: 492-501.
【5】沈品华. 镀锌三价铬钝化[J]. 电镀与环保, 2007, 27(3):27-30.
【6】王惠敏, 陈玫, 李基森. 镀锌层三价铬钝化剂的探讨[J]. 中国表面工程, 2008, 21(2):40-43.
【7】周元, 吕志, 周长虹. 浅谈三价铬钝化工艺[J]. 电镀与环保, 2007, 27(5):23-24.
【8】Huvar. Trivalent chromium passivation solution and process[P]. US Pat:4349392, 1982-09-14.
【9】Tang, Bhatia, Parkos, et al. Stability additive for trivalent chrome conversion coating bath solution[P]. US Pat:6648986, 2003-11-18.
【10】Matzdorf, Kane, Green. Post-treatment for metal coated substrates[P]. US Pat:6527841, 2003-03-04.
【11】Fred W Eppensteiner, Melvin R Jenkins. Chromate conversion coatings[J]. Metal Finishing, 2000, 98: 497-509.
【12】Gigandet M P, Faucheu J, Tachez M. Formation of black chromate conversion coatings on pure and zinc alloy electrolytic deposits role of the main constituents[J]. Surface and Coatings Technology, 1997(89):285-291.
【13】张晓明, 徐金来, 胡耀红, 等. 三价铬钝化工艺及其维护[J]. 电镀与涂饰, 2008, 27(11):32-33, 40.
【14】Bayati M R, Sharat M H, Janghorban K. Design of chemical composition and optimum working conditions for trivalent black chromium electroplating bath used for solar thermal collectors[J]. Renewable Energy, 2005, 30(14):2163-2178.
【15】Zaki Nabil. Producing Cr(Ⅵ)-free black finishing for automotive applications[C]//AESF SUR/FIN 2004 & Interfinsh 2004 Word Congress. Chicago:Dlinois, 2004:494.
【16】周保学, 李金花, 刘国琴. 三价铬黑色钝化剂及其制备方法[P]. 中国专利: 200710046935.3, 2008-02-27.
【17】毕四富, 李宁, 屠振密, 等. 镀锌层三价铬黑色钝化工艺的研究[J]. 电镀与环保, 2007, 27(4):17-20.
【18】尹刚强, 李尚德. 一种常温三价铬镀锌黑色钝化方法[J]. 广东微量元素科学, 2008, 15(6):67-69.
【19】惠怀兵, 刘立炳. 镀锌层三价铬黑色钝化工艺[J]. 电镀与精饰, 2009, 31(9):17-19.
【20】Roman L, Blidariu M, Cristescu C, et al. Study of conversion coating on zinc deposition obtained from low pollution solutions[J]. Transactions of the Institute of Metal Finishing, 1997, 75(5):171-174.
【21】Clifford, Biddulph F, Leonard L, et al. Black trivalent chromium chromate conversion coating[P]. US Pat:20040156999, 2004-08-12.
【22】Katsuhide Oshima, Shigemi Tanaka, Manabu Inoue, et al. Processing solution for forming hexavalent chromium free and corrosion resistant conversion film on zinc or zinc alloy plating layers, hexavalent chromium free and corrosion resistant conversion film, method for forming the same[P]. US Pat:6858098B2, 2005-02-22.
【23】Tomitaka Yamamoto, Michimasa Yoshida, Satoshi Shimamune. Agent for reducing conversion film overall friction coefficient for trivalent chromate treating solution, trivalent chromate treating solution and method for production thereof, and trivalent chromate conversion film reduced in overall friction coefficient and method for production thereof[P]. US Pat:2007/0023104A1, 2007-02-01.
【24】Horie Hidekazu, Isozaki Satoyuki, Noto Naomi. Black film agent, and method of forming black film[P]. US Pat:2005/206872, 2005-08-04.
【25】Manabu Inoue. Aqueous treating solution for forming black trivalent-chromium chemical conversion coating on zinc or zinc alloy and method of forming black trivalent-chromium chemical conversion coating[P]. US, 2009/0020185A1, 2009-01-22.
【26】任艳萍, 陈锦虹. 镀锌层三价铬钝化工艺的研究[J]. 腐蚀与防护, 2007, 28(1):13-16, 19.
【27】闫磊, 张英杰, 范云鹰. 锌及锌合金镀层无铬钝化研究进展[J]. 电镀与环保, 2007, 27(5):1-5.
【28】肖鑫, 钟萍, 易翔. 一种新型镀锌层无铬钝化工艺[J]. 腐蚀与防护, 2007, 28(9):467-469.
【29】刘艳荣, 周婉秋, 赵强, 等. 镀锌板表面无铬钝化的研究进展[J]. 电镀与精饰, 2010, 32(4):22-26.
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