钛基金属氧化物阳极的耐用性研究进展
Progress of Study on Durabilities of Ti Based Metal Oxide Anodes
摘 要
本文较全面地介绍了钛基金属氧化物阳极失效的几个主要原因: 涂层溶蚀、涂层剥落、钛基体钝化、涂层“毒化”、机械损坏、不合理的工况条件等; 并根据目前国内外采取的措施进行归纳和总结, 提出了提高钛基金属氧化物阳极寿命的对策, 为电化学稳定性更高的新型金属氧化物阳极的研制提供思路。
电极失效
阳极寿命
Ti based metal oxide anode
electrode degradation
anode lifetime
Abstract
This paper introduces the main reasons for Ti based metal oxide anodes’ degradation including dissolution and desquamation of coating, passivation of Ti substrate, “poisoning”of coating, mechanical damage, unreasonable working conditions and so on. According to the recent measures taken by domestic and international researchers, the countermeasures to increase the life of Ti based metal oxide anodes were summarized and proposed and some ideas for preparing new-style metal oxide anodes with higher electrochemical stability are provided.
中图分类号 TG174
所属栏目 试验研究
基金项目 国家自然科学基金(No.51078012/E0804)
收稿日期 2011/4/29
修改稿日期
网络出版日期
作者单位点击查看
联系人作者王晶晶(ji_1118@163.com)
备注王晶晶, 硕士研究生,
引用该论文: WANG Jing-jing,QIN Guo-tong,WEI Wei. Progress of Study on Durabilities of Ti Based Metal Oxide Anodes[J]. Corrosion & Protection, 2012, 33(2): 144
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参考文献
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【2】张招贤,赵国鹏,罗峰,等. 钛电极学导论[M]. 北京:冶金工业出版社,2008.
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【6】张招贤. IrTa氧化物涂层钛阳极恶化原因分析[J]. 氯碱工业,2005(1):14.
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【21】李辉, 吴建华, 齐公台,等. 涂覆量对RuTiSnMn/Ti阳极电化学性能的影响[J]. 腐蚀与防护,2003,26(12):518-524.
【22】康新婷, 鞠鹤, 武宏让. 土壤介质中阴极保护用混合金属氧化物涂层钛阳极的研究[J]. 腐蚀与防护,2006,27(4):168-170.
【23】张玉萍, 武志红, 鞠鹤,等. 铱涂覆量对IrO2-Ta2O5钛阳极性能的影响[J].表面技术,2010,39(4):33-35.
【24】Terezo A J, Pereira E C. Fractional factorial design applied to investigate properties of Ti/IrO2-Nb2O5 electrodes[J]. Electrochem Acta,2000,45:4351-4358.
【25】Kim K W, Lee E H, Kim J S,et al. Material and organic destruction characteristics of high temperature-sintered RuO2 and IrO2 electrodes[J]. Electrochem Soc,2002,149:187.
【26】Kim K W, Lee E H, Kim J S,et al. A study on performance improvement of Ir oxide-coated titanium electrode for organic destruction[J]. Electrochim Acta,2002,47:2525.
【27】Xin Y L, Xu L K, Wang J T,et al. Effect of sintering temperature on microstructure and electrocatalytic properties of Ti/IrO2-Ta2O5 Anodes by pechini method[J]. Rare Metal Materials and Engineering,2010,39(11):1903-1907.
【28】Aicheng Chen, Daniel J La Russa, Brad Miller. Effect of the iridium oxide thin film on the electrochemical activity of platinum nanoparticles[J]. Langmuir,2004,20(22):9695-9702.
【29】Mario H P, Santana, Luiz A,et al. Effect of preparation procedure of IrO2-Nb2O5 anodes on surface and electrocatalytic properties[ J]. J Appl Electrochem,2005,35:915-924.
【30】陶自春,罗启富,潘建跃.铱系涂层钛阳极的研究进展[J].材料科学与工程学报,2003,21(1):138-142.
【31】陶自春,潘建跃,罗启富.铂中间层的制备及对铱钽涂层钛阳极性能的影响[J].材料科学与工程学报,2004,22(2):240-244.
【32】蔡天晓, 陈航, 鞠鹤,等. 钢筋混凝土阴极保护用高性能涂层钛阳极[J].腐蚀与防护,2006,27(10):522-525.
【33】孟惠民, 石锗元, 王旭东,等. 抗有机物劣化的贵金属氧化物涂层电极的开发[J]. 中国有色金属学报,2004,14(3):371-375.
【34】但建明, 陈康宁, 刘志勇,等. 梯度功能氧化物电极的电性能研究[J]. 氯碱工业,2000(3):15-20.
【35】邹忠, 李劼, 丁凤其. 梯度功能型金属氧化物涂层阳极(DSA)的制备[J]. 功能材料,2001,32(4):431-433.
【2】张招贤,赵国鹏,罗峰,等. 钛电极学导论[M]. 北京:冶金工业出版社,2008.
【3】胡吉明. Ti基IrO2+Ta2O5涂层阳极析氧电催化与失效机制研究[D]. 北京:北京科技大学博士论文,2000.
【4】Krysa J, Kule L, Mraz R,et al. Effect of coating thickness and surface treatment of titanium on the properties of IrO2-Ta2O5 anodes[J]. J Appl Electrochem,1996,26:999-1005.
【5】Kristor J, Szilagyi T, Horvaht E,et al. Investigation of IrO2/Ta2O5 thin film evolution[J]. Thermochemical Acta,2004,413:93-99.
【6】张招贤. IrTa氧化物涂层钛阳极恶化原因分析[J]. 氯碱工业,2005(1):14.
【7】张琼, 彭俊华, 蔡传荣. 钛阳极涂层剥落失效机理初探[J].电子显微学报,2001,20(4):410-411.
【8】Kotz R, Stucki S, Career B. Electrochemical waste water treatment using high over voltage anodes. Part Ⅰ: Physical and electrochemical properties of SnO2 anodes[J].Appl Electrochem,1991,21:14-18.
【9】Hoseinien S M, Ashrafizadeh F, Maddahi M H. A comparative investigation of the corrosion behavior of RuO2-IrO2-TiO2 coated titanium anodes in chloride solutions[J]. J Electrochem Soc,2010,157(4):50-56.
【10】王晓梅. Ti/IrO2阳极在氯酚水溶液中的电化学行为与失活 [D].杭州: 浙江大学硕士论文,2007.
【11】Morimitsu M, Tamura H, Matsunag M A,et al. Polarization behaviour and life time of IrO2-Ta2O5-SnO2/Ti anodes in P-phenolsulfonic acid solutions for tin Plating[J]. J Appl Electrochem,2000,30:511-514.
【12】Kamegaya Y, Sasaki K, Oguri M,et al. Improved durability of iridium oxide coated titanium anode with interlayers for oxygen evolution at high current densities[J]. Electrochem Acta,1995(40):889-895.
【13】张招贤, 郑团. 涂层钛阳极强化寿命试验电解因素的选择[J]. 氯碱工业,2004(5):10-11.
【14】Vercesi G P, Rolewicza J, Comninellis Ch,et al. Characterization of dsa-type oxygen evolving electrodes:Choice of base metal[J]. Thermochem Acta,1991,176:31.
【15】Cardarelli F, Taxil P, Savall A,et al. Preparation of oxygen evolving electrodes with long service life under extreme conditions[J]. J Appl Electrochem,1998,28(3):245-250.
【16】Ouattara L, Diaco T, Duo I,et al. Dimensionally stable anode-type anode based on conductive p-silicon substrate[J]. Electrochemi Soc,2003,150(2):41-45.
【17】范亚卓, 鞠鹤, 蔡天晓,等. 多孔钛基贱金属阳极的制备[J]. 表面技术,2009,38(3):13-14.
【18】胡吉明, 孟惠民, 张鉴清,等. 制备条件对钛基IrO2·Ta2O5涂层阳极性能的影响[J]. 金属学报,2002,38(1):69-73.
【19】姜俊峰, 孟惠民, 孙冬柏. 喷砂工艺对钛阳极表面形貌、电催化活性和寿命的影响[J].中国有色金属学报,2010,20(6):1162-1168.
【20】王科, 韩严, 王均涛,等. 涂液浓度对Ru-Ti-Ir氧化物阳极涂层性能的影响[J].电化学,2006,12(1):74-79.
【21】李辉, 吴建华, 齐公台,等. 涂覆量对RuTiSnMn/Ti阳极电化学性能的影响[J]. 腐蚀与防护,2003,26(12):518-524.
【22】康新婷, 鞠鹤, 武宏让. 土壤介质中阴极保护用混合金属氧化物涂层钛阳极的研究[J]. 腐蚀与防护,2006,27(4):168-170.
【23】张玉萍, 武志红, 鞠鹤,等. 铱涂覆量对IrO2-Ta2O5钛阳极性能的影响[J].表面技术,2010,39(4):33-35.
【24】Terezo A J, Pereira E C. Fractional factorial design applied to investigate properties of Ti/IrO2-Nb2O5 electrodes[J]. Electrochem Acta,2000,45:4351-4358.
【25】Kim K W, Lee E H, Kim J S,et al. Material and organic destruction characteristics of high temperature-sintered RuO2 and IrO2 electrodes[J]. Electrochem Soc,2002,149:187.
【26】Kim K W, Lee E H, Kim J S,et al. A study on performance improvement of Ir oxide-coated titanium electrode for organic destruction[J]. Electrochim Acta,2002,47:2525.
【27】Xin Y L, Xu L K, Wang J T,et al. Effect of sintering temperature on microstructure and electrocatalytic properties of Ti/IrO2-Ta2O5 Anodes by pechini method[J]. Rare Metal Materials and Engineering,2010,39(11):1903-1907.
【28】Aicheng Chen, Daniel J La Russa, Brad Miller. Effect of the iridium oxide thin film on the electrochemical activity of platinum nanoparticles[J]. Langmuir,2004,20(22):9695-9702.
【29】Mario H P, Santana, Luiz A,et al. Effect of preparation procedure of IrO2-Nb2O5 anodes on surface and electrocatalytic properties[ J]. J Appl Electrochem,2005,35:915-924.
【30】陶自春,罗启富,潘建跃.铱系涂层钛阳极的研究进展[J].材料科学与工程学报,2003,21(1):138-142.
【31】陶自春,潘建跃,罗启富.铂中间层的制备及对铱钽涂层钛阳极性能的影响[J].材料科学与工程学报,2004,22(2):240-244.
【32】蔡天晓, 陈航, 鞠鹤,等. 钢筋混凝土阴极保护用高性能涂层钛阳极[J].腐蚀与防护,2006,27(10):522-525.
【33】孟惠民, 石锗元, 王旭东,等. 抗有机物劣化的贵金属氧化物涂层电极的开发[J]. 中国有色金属学报,2004,14(3):371-375.
【34】但建明, 陈康宁, 刘志勇,等. 梯度功能氧化物电极的电性能研究[J]. 氯碱工业,2000(3):15-20.
【35】邹忠, 李劼, 丁凤其. 梯度功能型金属氧化物涂层阳极(DSA)的制备[J]. 功能材料,2001,32(4):431-433.
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