Influence of Microstructure on Tendency to Pitting Corrosion of G3 Alloy
摘 要
针对HastelloyG-3型镍基合金(G3合金)油套管腐蚀问题, 通过动电位扫描, 结合现代微观分析方法分析腐蚀产物等, 研究显微组织结构对G3合金点蚀倾向的影响。结果表明, 通过1170 ℃×60 min(水冷)处理可以使组织均匀化并获得很好的室温γ相单相组织从而提高G3合金耐点蚀倾向; 蚀孔易产生于晶界处、夹杂物处或基体析出相处, 蚀孔底部产生的闭塞电池促使Fe、Cr、Ni溶解而生成含O、S的团状化合物, 从而促使点蚀的发生。
Abstract
The influence of microstructure on the tendency to pitting of G3 alloy used for casing was studied by potentiodynamic scan and modern microscopic analysis methods. The results show that the γ phase was obtained by treatment of 1170 ℃×60 min (water), which made the microstructure homogeneous and thus improved the pitting resistance of G3 alloy. Pitting occured at the grain boundaries, inclusions and matrix precipitates easily. The occluded cells generated at the pitting bottom made Fe, Cr, Ni dissolved and group-like compounds generated.
中图分类号 TG172
所属栏目 试验研究
基金项目
收稿日期 2011/4/12
修改稿日期
网络出版日期
作者单位点击查看
备注李春福, 教授, 博导,
引用该论文: MA Han-yue,LI Chun-fu,FENG Peng-fei,YANG Yang,SUN Yan-an. Influence of Microstructure on Tendency to Pitting Corrosion of G3 Alloy[J]. Corrosion & Protection, 2012, 33(3): 193
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】刘道新.材料的腐蚀与防护[M].西安: 西北工业大学出版社, 2006: 119-128.
【2】林玉珍, 杨德钧.腐蚀和腐蚀控制原理[M].北京: 中国石化出版社, 2007: 138-146.
【3】Gegde G. Corrosion of cast iron in potable water service. Proc corrosion and related aspects of materials for potable water supplies[C]//Proceedings of the Institute of Materials Conference. Londong, 1992.
【4】杨武. 金属的局部腐蚀[M].北京: 化学工业出版社, 1995: 102-106.
【5】植田昌克.合金元素和显微结构对CO2/H2S环境中腐蚀产物稳定性的影响[J].石油天然气化工, 2005, 34(1): 43-52.
【6】Edward L, Hibner, Curtis S. Tassen. Corrosion resistant OCTGs for a range of sour gas service conditions[C]//Corrosion 2000, Paper No.00149.
【7】Hibner E L, Tassen C S. Corrosion resistant OCTGs and matching age-hardenable bar products for a range of sour gas service conditions[C]//Corrosion 2001, Paper No.01102.
【8】Hibner E L, Brett C. Puckett.Comparison of corrosion resistance of nickel-base alloy for OCTGs and mechanical tubing in severe sour service conditions [C].Corrosion 2004, Paper No.04110.
【9】崔世华, 李春福, 荣金仿, 等. 镍基合金G3在高含H2S/CO2环境中的影响因素研究[J].材料科学与工程学报, 2009(04):29-31.
【2】林玉珍, 杨德钧.腐蚀和腐蚀控制原理[M].北京: 中国石化出版社, 2007: 138-146.
【3】Gegde G. Corrosion of cast iron in potable water service. Proc corrosion and related aspects of materials for potable water supplies[C]//Proceedings of the Institute of Materials Conference. Londong, 1992.
【4】杨武. 金属的局部腐蚀[M].北京: 化学工业出版社, 1995: 102-106.
【5】植田昌克.合金元素和显微结构对CO2/H2S环境中腐蚀产物稳定性的影响[J].石油天然气化工, 2005, 34(1): 43-52.
【6】Edward L, Hibner, Curtis S. Tassen. Corrosion resistant OCTGs for a range of sour gas service conditions[C]//Corrosion 2000, Paper No.00149.
【7】Hibner E L, Tassen C S. Corrosion resistant OCTGs and matching age-hardenable bar products for a range of sour gas service conditions[C]//Corrosion 2001, Paper No.01102.
【8】Hibner E L, Brett C. Puckett.Comparison of corrosion resistance of nickel-base alloy for OCTGs and mechanical tubing in severe sour service conditions [C].Corrosion 2004, Paper No.04110.
【9】崔世华, 李春福, 荣金仿, 等. 镍基合金G3在高含H2S/CO2环境中的影响因素研究[J].材料科学与工程学报, 2009(04):29-31.
相关信息