晶粒度对一些常用金属耐腐蚀性能的影响
Influence of Grain Size on Corrosion Resistant of Commonly Used Metals
摘 要
关于晶粒度对材料的力学性能影响的研究很多, 但是关于晶粒度对材料的耐腐蚀性能的研究并不常见。本文综述了几种常见钢材、有色金属及合金的晶粒大小与其耐腐蚀性能之间的关系: 某些钢和铝一般随着基体材料晶粒度的减小, 其耐腐蚀性能增强; 铜、镁一般随着基体材料晶粒度的减小, 其耐腐蚀性能减弱。分析并总结了相关的腐蚀机理。建议在获得大量腐蚀数据的前提下, 开展相关人工神经网络预测模型的研究, 这将有助于全面、准确的评价晶粒度对材料腐蚀性能的影响。
金属
耐腐蚀性能
grain size
metal
corrosion resistance
Abstract
Researches about grain size effect on the mechanical properties of materials are plenty. However, the effect of grain size on corrosion resistance of metals is not extensively and intensively studied. The relationship between corrosion resistance and grain size of several common steels, non-ferrous metals and alloys are demonstrated in this paper. The corrosion resistance of steels and aluminum are proportionally related to the grain size; the corrosion resistance of copper and magnesium are inversely related to the grain size. It was suggested that some artificial neural networks may be used predict the effect of grain size on corrosion behavior of materials.
中图分类号 TG172
所属栏目 专论
基金项目 教育部新世纪优秀人才支持计划(No.NCET-07-0536; 教育部创新团队计划(No.IRT0739))
收稿日期 2011/8/21
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备注钟庆东, 教授, 博士生导师,
引用该论文: LUO Jian,ZHANG Yong,ZHONG Qing-dong,ZHANG lei,ZHU Zhen-yu. Influence of Grain Size on Corrosion Resistant of Commonly Used Metals[J]. Corrosion & Protection, 2012, 33(4): 349
被引情况:
【1】吕臣凯,盛敏奇,钟庆东, "超声波作用下电沉积纳米晶Co-W合金镀层",腐蚀与防护 36, 192-196(2015)
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参考文献
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【2】K Al-Muhanna, K Habib. Corrosion behavior of different alloys exposed to continuous flowing seawater by electrochemical impedance spectroscopy (EIS)[J]. Desalination, 2010, 250:404-407.
【3】Li Y, Wang F, Liu G. Grain size effect on the electrochemical corrosion behavior of surface nanocrystallized low-carbon steel[J]. Corrosion, 2004, 60(10):891-896.
【4】Zou Y, Wang J, Zheng Y Y. Electrochemical techniques for determining corrosion rate of rusted steel in seawater[J]. Corrosion Science, 2011, 53:208-216.
【5】Kalmykov V V, Razdobreev V G. Effect of the structure of carbonsteel on its corrosion in 3% NaCl solution under alternating immersion[J]. Protection of Metals, 1999, 35(6):598-599.
【6】Ralston K D, Birbilis N, Davies C H J. Revealing the relationship between grain size and corrosion rate of metals[J]. Scripta Materialia, 2010, 63:1201-1204.
【7】邓永生, 黄桂桥. 海水环境中铸造不锈钢的腐蚀行为[J]. 装备环境工程, 2005(02):78-82.
【8】邹妍, 王佳, 郑莹莹. 海水中碳钢短期腐蚀行为的电化学研究方法[J]. 腐蚀科学与防护技术, 2010, 22(4):26-30.
【9】夏兰廷, 黄桂桥, 丁路平. 碳钢及低合金钢的海水腐蚀性能[J]. 铸造设备研究, 2002, 8(4):14-17.
【10】López H F, Cisneros M M, Mancha H, et al. Grain size effects on the SCC susceptibility of a nitrogen steel in hot NaCl solutions[J]. Corrosion Science, 2006, 48(4):913-924.
【11】Reynalda Beltrana, Maldonadoa J G, Murr L E, et al. Effects of strain and grain size on carbide precipitation and corrosion sensitization behavior in 304 stainless steel[J]. Acta Materialia, 1997, 45(10):4351-4360.
【12】汪兵, 刘清友. 晶粒尺寸对普碳钢耐工业环境下大气腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2007, 27(4):3-6.
【13】陈小平, 王向东, 汪社明, 等. 晶粒尺寸对耐候钢抗大气腐蚀性能的影响[J]. 材料保护, 2005, 38(07):21-24.
【14】王艳, 曹中秋, 付雅君, 等. 不同晶粒尺寸Cu-50Cr合金在酸性介质中的腐蚀电化学行为研究[J]. 腐蚀科学与防护技术, 2009(2):91-93.
【15】CAO Z Q, Bian J, Xue R, et al. Electrochemical corrosion behavior of Cu-40Ni-20Cr alloys with different grain sizes in solutions containing chloride ions[J]. Transactions of Nonferrous Metals Society of China, 2007, 17(6):1236-1241.
【16】余刚, 刘跃龙, 李瑛, 等. Mg合金的腐蚀与防护[J]. 中国有色金属学报, 2002(06):11-22.
【17】化学工业部化工机械研究院. 腐蚀与防护手册-耐蚀金属材料及防蚀技术(第1版)[M]. 北京:化学工业出版社, 1990:897-898.
【18】Mcintyre N S, Chen C. Role of impurities on Mg surfaces under ambient exposure conditions[J]. Corrosion Science, 1998, 40(10):1697-1709.
【19】Baril G, Pebere N. The corrosion of pure Magnesium in aerated and deaerated sodium sulphate solutions[J]. Corrosion Science, 2001, 43:471-484.
【20】Song D, Ma A B, Jiang J H, et al. Corrosion behaviour of bulk ultra-fine grained AZ91D magnesium alloy fabricated by equal-channel angular pressing[J]. Corrosion Science, 2011, 53(1):362-373.
【21】Hamu G B, Eliezer D, Wagner L. The relation between severe plastic deformation microstructure and corrosion behavior of AZ31 magnesium alloy[J]. Alloy Compd, 2009, 468:222-229.
【22】Ralston K D, Fabijanic D, Birbilis N. Effect of grain size on corrosion of high purity aluminium[J]. Electrochimica Acta, 2011, 56:1729-1736.
【23】陈渊, 尹志新, 樊新波. 5052铝合金表面晶粒超细化后腐蚀性能研究[J]. 热加工工艺, 2010(02):7-9.
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