石油生产中腐蚀的原因及缓蚀剂的应用
Causes of Corrosion and Application of Inhibitors in Oil Protection
摘 要
在石油工业中防腐蚀是一个非常重要的课题, 腐蚀是制约石油工业发展的一个重要因素, 因此, 腐蚀防护技术的研究和应用具有重大的意义。本文综述了石油生产中易被腐蚀环节产生腐蚀的原因以及影响腐蚀的因素, 概述了缓蚀剂作为重要的防腐蚀技术在石油生产中的应用现状, 展望了缓蚀剂的发展趋势。
腐蚀
石油工业
防护
corrosion inhibitor
corrosion
oil industry
protection
Abstract
Anti-corrosion is a very important subject in the oil industry, corrosion is an important factor restricting the oil industry development. So, research and application of corrosion protection technology have great significance. The causes of corrosion in oil production and the influence factors of corrosion are reviewed, the application status of corrosion inhibitors as an important anti-corrosion technology in oil production are summarized, and the development trend of corrosion inhibitors is outlooked in this paper.
中图分类号 TG174.42
所属栏目 专论
基金项目 广西高校优秀人才资助计划项目(No.RC2007021)
收稿日期 2011/9/21
修改稿日期
网络出版日期
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联系人作者刘峥(Lisa4.6@163.com)
备注刘峥, 教授, 博士,
引用该论文: LIU Jie,LIU Zheng,CHEN Shi-liang. Causes of Corrosion and Application of Inhibitors in Oil Protection[J]. Corrosion & Protection, 2012, 33(8): 657
被引情况:
【1】曾德智,李坛,雷正义,重兴成,张智,施太和, "承压状态下氟橡胶O型密封圈耐酸性介质腐蚀性能",机械工程材料 38, 88-92(2014)
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参考文献
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【29】王霞, 上官昌淮. 高含CO2气田缓蚀剂研究进展[J]. 油气田地面工程, 2010, 29(12): 35-37.
【30】Migahed M A, Farag A A, Elsaed S M. Synthesis of a new family of Schiff base nonionic surfactants and evaluation of their corrosion inhibition effect on X-65 type tubing steel in deep oil wells formation water[J]. Materials Chemistry and Physics, 2011, 125:125-135.
【31】Ismail Abdelrhman Aiad, Nabel A Negm. Some schiff base surfactants as steel-corrosion inhibitors[J]. J Surfact Deterg, 2009, 12:313-319.
【32】Govindaraju K M, Gopi D, Kavitha L. Inhibiting effects of 4-amino-antipyrine based schiff base derivatives on the corrosion of mild steel in hydrochloric acid[J]. J Appl Electrochem, 2009, 39:2345-2352.
【33】李瑾, 张大全. 缓蚀膜自组装技术的研究与发展[J]. 腐蚀与防护, 2010, 31(3):183-187.
【34】Cui Z D, Wu S L, Li C F, et al. Corrosion behavior of oil tube steels under conditions of multiphase flow saturated with super-critical carbon dioxide[J]. Materials Letters 2004, 58: 1035-1040.
【2】李林辉, 李 浩. 油气集输管线内防腐技术[J]. 上海涂料, 2011, 5(49):32-33.
【3】Migahed M A, Nassar I F. Corrosion inhibition of Tubing steel during acidization of oil and gas wells[J]. Electrochimica Acta, 2008, 53: 2877-2882.
【4】林玉珍, 杨德钧. 腐蚀和腐蚀控制原理[M]. 北京: 中国石化出版社, 2007: 288-295.
【5】杨光, 张洪虎, 刘婷. 石油工业中二氧化碳腐蚀及缓蚀实验研究[J]. 四川化工, 2008, 11(6): 24-25.
【6】Zhang G A, Cheng Y F. Localized corrosion of carbon steel in a CO2-saturated oilfield formation water[J]. Electrochimica Acta, 2011, 56:1676-1685.
【7】涂小华, 王修杰. 石油工业中管道的腐蚀与防腐[J]. 江西化工, 2006(4): 266-267.
【8】王慧, 李东胜. 缓蚀剂在石油化工领域的应用现状[J]. 广州化工, 2006(3):25-26.
【9】郑兴文, 龚敏, 曾宪光, 等. 天然绿色盐酸酸洗缓蚀剂研究进展[J]. 自然科学, 2008, 21(3):45-46.
【10】朱镭, 于萍, 罗运柏. 咪唑啉缓蚀剂的研究与应用进展[J]. 材料保护, 2003, 36(12):4-7.
【11】石顺存, 方茹苕, 唐胜利. 咪唑啉膦酰胺盐酸盐在油田水中的缓蚀性能研究[J]. 油田化学, 2008, 25(3): 35-37.
【12】Hu S Q, Hu J C, Fan C C. Corrosion inhibition of Q235 steel by a novel imidazoline compound under H2S and CO2 coexistence[J]. Acta Physica-Chimica Sinica, 2010, 26(8): 2163-2170.
【13】常艳兵, 王为民, 魏显达. 新型咪唑啉类缓蚀剂PF99对20钢的缓蚀性能研究[J]. 北京石油化工学院学报, 2011, 19(6): 50-51.
【14】Wang Bin, Du Min, Zhang Jing. Inhibition performance of an imidazoline derivative as a gas-liquid two-phase inhibitor for Q235 steel against CO2 corrosion[J]. Acta Physica-Chimica Sinica, 2011, 27(1): 120-126.
【15】闫杰, 李茜璐, 杨洪烈, 等. 油田用咪唑啉季铵盐缓蚀剂的合成及性能评价[J]. 精细石油化工进展, 2009, 10(10):9-12.
【16】Ortega-Sotelo D M, Gonzalez-Rodriguez J G, Neri-Flores M A, et al. CO2 corrosion inhibition of X-70 pipeline steel by carboxyamido imidazoline[J]. J Solid State Electrochem, 2011(15):1997-2004.
【17】Lucio-Garcia M A, Gonzalez-Rodriguez J G. A study of hydroxyethyl imidazoline as H2S corrosion inhibitor using electrochemical noise and electrochemical impedance spectroscopy[J]. J Appl Electrochem, 2010(40):393-399.
【18】Okafor P C, Liu C B, Liu X, et al. Inhibition of CO2 corrosion of N80 carbon steel by carboxylic quaternary imidazoline and halide ions additives[J]. J Appl Electrochem, 2009(39):2535-2543.
【19】鞠虹, 李焰. 杂环化合物对热浸镀锌铝合金镀层在稀盐酸中的缓蚀作用[J]. 中国有色金属报, 2008, 18(1): 178-186.
【20】姜德成, 刘福国, 武素茹. 新型三唑衍生物缓蚀剂对Q235-A钢H2SO4酸洗的缓蚀作用[J]. 材料保护, 2010, 43(3):23-26.
【21】Ksenija Babic′-Samardzija, Norman Hackerman. Triazole, benzotriazole and substituted benzotriazoles as corrosion inhibitors of iron in aerated acidic media[J]. J Solid State Electrochem, 2005(9):483-497.
【22】Li W H, He Q, Pei C L, et al. Experimental and theoretical investigation of the adsorption behaviour of new triazole derivatives as inhibitors for mild steel corrosion in acid media[J]. Electrochimica Acta, 2007, 52:6386-6394.
【23】梁丽. 季铵盐型缓蚀剂的合成及性能评价[J]. 化学工程, 2010, 38(10):236-237.
【24】潘成松, 王霞, 李刚, 等. 油气田酸化用缓蚀剂双咪哇琳季按盐的合成及评价[J]. 精细石油化工进展, 2008, 9(11):4-7.
【25】李谦定, 李恒娟, 卢永斌. 咪唑啉季铵盐缓蚀剂的合成及应用性能评价[J]. 西安石油大学学报, 2011, 26(2):77-79.
【26】Fuchs-Godec R. The adsorption, CMC determination and corrosion inhibition of some N-alkyl quaternary ammonium salts on carbon steel surface in 2M H2SO4[J]. Colloids and Surfaces A, 2006, 280:130-139.
【27】Gao B J, Zhang X, Sheng Y L. Studies on preparing and corrosion inhibition behaviour of quaternized polyethyleneimine for low carbon steel in sulfuric acid[J]. Materials Chemistry and Physics, 2008, 108:375-381.
【28】Badawi A M, Hegazy M A, El-Sawy A A, et al. Novel quaternary ammonium hydroxide cationic surfactants as corrosion inhibitors for carbon steel and as biocides for sulfate reducing bacteria (SRB)[J]. Materials Chemistry and Physics, 2010, 124:458-465.
【29】王霞, 上官昌淮. 高含CO2气田缓蚀剂研究进展[J]. 油气田地面工程, 2010, 29(12): 35-37.
【30】Migahed M A, Farag A A, Elsaed S M. Synthesis of a new family of Schiff base nonionic surfactants and evaluation of their corrosion inhibition effect on X-65 type tubing steel in deep oil wells formation water[J]. Materials Chemistry and Physics, 2011, 125:125-135.
【31】Ismail Abdelrhman Aiad, Nabel A Negm. Some schiff base surfactants as steel-corrosion inhibitors[J]. J Surfact Deterg, 2009, 12:313-319.
【32】Govindaraju K M, Gopi D, Kavitha L. Inhibiting effects of 4-amino-antipyrine based schiff base derivatives on the corrosion of mild steel in hydrochloric acid[J]. J Appl Electrochem, 2009, 39:2345-2352.
【33】李瑾, 张大全. 缓蚀膜自组装技术的研究与发展[J]. 腐蚀与防护, 2010, 31(3):183-187.
【34】Cui Z D, Wu S L, Li C F, et al. Corrosion behavior of oil tube steels under conditions of multiphase flow saturated with super-critical carbon dioxide[J]. Materials Letters 2004, 58: 1035-1040.
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