Influence of Cl- on Development Behavior from Pitting Corrosion to Stress Corrosion Cracking of 304L Stainless Steel
摘 要
普查了国内某海滨核电站核燃料厂房(K厂房)不锈钢管道的腐蚀情况和Cl-浓度, 发现K厂房不锈钢管道存在普遍的腐蚀问题, 腐蚀主要发生在弯管和焊缝部位, 以点蚀为主, K厂房大气中Cl-含量是现场大气环境中的18倍左右。采用自行设计的装置预制点蚀坑, 用恒载荷法研究了溶液中304L不锈钢由点蚀扩展为应力腐蚀的行为过程; 结果表明, 304L不锈钢发生应力腐蚀门槛应力在80% Rp0.2左右, 1级椭圆形点蚀坑扩展为SCC的Cl-临界浓度在5~10 mg/L之间。根据现场调查和试验结果推断, K厂房奥氏体不锈钢管道在含有氯离子的大气中应力腐蚀开裂(SCC)过程可分为两个阶段, 先是金属表面钝化膜被破坏而发生点蚀, 以后以蚀坑底部的敏感点为裂纹源, 扩展为SCC。
Abstract
Corrosion conditions and Cl- concentrations were generally surveyed in K factory of a nuclear power plant. The results indicated that corrosion problems, especially pitting corrosion, occured the surface of stainless steel pipeline in K factory and mainly occured in elbow pipe and weld pipe. And, the Cl- concentration in the atmosphere of K factory was about 18 times of that of the surrounding atmospheric environment. A new instrument was designed to make corrosion pit. Constant stress method was applied to study the development behavior from pitting corrosion (PC) to stress corrosion cracking (SCC) of 304L stainless steel. The results showed that the sensitivity stress of SCC for 304L was around 80% Rp0.2. The critical Cl- concentrations of expansion behavior from PC with an oval pit to SCC was 5~10 mg/L. SCC of stainless steel pipeline in K factory in Cl- atmosphere could be divided into two stages. The first stage was PC, then SCC.
中图分类号 TG172
所属栏目 试验研究
基金项目 大型先进压水堆核电站重大专项(2011ZX06004-009-0902)
收稿日期 2012/8/26
修改稿日期
网络出版日期
作者单位点击查看
备注方可伟, 工程师, 硕士,
引用该论文: LI Yan,FANG Ke-wei,LIU Fei-hua. Influence of Cl- on Development Behavior from Pitting Corrosion to Stress Corrosion Cracking of 304L Stainless Steel[J]. Corrosion & Protection, 2012, 33(11): 955
被引情况:
【1】黄晓英,樊艳丽, "电热水器Incoloy800和840合金加热管爆管失效分析",腐蚀与防护 36, 497-501(2015)
【2】马新朝,刘璐,洪源平,李世伟,步伟东, "夹杂物对压水堆核电站用Z2CN19-10不锈钢应力腐蚀开裂的影响",机械工程材料 40, 10-14(2016)
共有人对该论文发表了看法,其中:
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】Osama M Alyousif, Rokuro Nishimura. The stress corrosion cracking behavior of austenitic stainless steels in boiling magnesium chloride solutions[J]. Corrosion Science, 2007, 49:3040-3051.
【2】Katsumi Yamamoto, Keizo Hosoya. Corrosivity of Br- and Cl- on duplex stainless steels[J]. Materials Science and Engineering, 1995, 198:239-24.
【3】王正樵, 吴幼林. 腐蚀与防护全书-不锈钢[M]. 北京: 化学工业出版社, 1991.
【4】赵万祥, 任爱, 刘飞华, 等. 核电站燃料厂房氯离子致不锈钢管道腐蚀问题探讨[C]//核电站寿命评价与管理技术研讨会论文集. 苏州:2011:728-736.
【5】Masayuki Kamaya, Takumi haruna. Influence of local stress on initiation behavior of stress corrosion cracking for sensitized 304 stainless steel[J]. Corrosion Science, 2007, 49(8):3303-3324.
【6】Osama M Alyousif, Rokuro Nishimura. The effect of test temperature on SCC behavior of austenitic stainless steels in boiling saturated magnesium chloride solution[J]. Corrosion Science, 2006, 48(12):4283-4293.
【7】Monika Gomez-Duran, Digby D Macdonald. Stress corrosion craking of sensitized type 304 stainless steels in thiosulphate solution(Ⅱ). Dynamics of fracture[J]. Corrosion Science, 2006, 48(7):1608-1622.
【8】陈孝渝, 杨德模, 凌勇, 等. 核电站地区大气腐蚀性污染物检测与分析[J]. 核科学与工程, 2005, 25(3): 193-195.
【9】约翰 赛德赖克斯 A. 不锈钢的腐蚀[M]. 北京: 机械工业出版社, 1986:196-200.
【2】Katsumi Yamamoto, Keizo Hosoya. Corrosivity of Br- and Cl- on duplex stainless steels[J]. Materials Science and Engineering, 1995, 198:239-24.
【3】王正樵, 吴幼林. 腐蚀与防护全书-不锈钢[M]. 北京: 化学工业出版社, 1991.
【4】赵万祥, 任爱, 刘飞华, 等. 核电站燃料厂房氯离子致不锈钢管道腐蚀问题探讨[C]//核电站寿命评价与管理技术研讨会论文集. 苏州:2011:728-736.
【5】Masayuki Kamaya, Takumi haruna. Influence of local stress on initiation behavior of stress corrosion cracking for sensitized 304 stainless steel[J]. Corrosion Science, 2007, 49(8):3303-3324.
【6】Osama M Alyousif, Rokuro Nishimura. The effect of test temperature on SCC behavior of austenitic stainless steels in boiling saturated magnesium chloride solution[J]. Corrosion Science, 2006, 48(12):4283-4293.
【7】Monika Gomez-Duran, Digby D Macdonald. Stress corrosion craking of sensitized type 304 stainless steels in thiosulphate solution(Ⅱ). Dynamics of fracture[J]. Corrosion Science, 2006, 48(7):1608-1622.
【8】陈孝渝, 杨德模, 凌勇, 等. 核电站地区大气腐蚀性污染物检测与分析[J]. 核科学与工程, 2005, 25(3): 193-195.
【9】约翰 赛德赖克斯 A. 不锈钢的腐蚀[M]. 北京: 机械工业出版社, 1986:196-200.
相关信息