镀锌板无铬钝化技术进展
Progress of Chromium-free Passivation of Galvanized Steel Sheet
摘 要
本文综述了国内外镀锌板无铬钝化技术研究现状, 分别介绍了无机、有机、有机无机复合无铬钝化技术发展概况, 对比分析了不同技术的优缺点。展望了无铬钝化技术未来的发展趋势, 同时指出无机物与植酸的复合钝化技术, 有无毒无污染、钝化膜耐蚀性好的优点, 该技术将成为无铬钝化的主要发展方向之一。
六价铬
三价铬
耐蚀性
植酸
转化膜
chromate-free passivation
hexavalent chromium
trivalent chromium
corrosion resistance
phytic acid
conversion film
Abstract
In this paper, the developing status of the non-chrome passivation technology is reviewed, including the inorganic way, organic way and combined way of above two ways, and the differences among the above three ways is analyzed in detail. The development trend of non-chrome passivation technology is prospected. It is pointed out that the inorganic phytic acid compound passivation technology, characterized by its non-toxin, non-pollution and better resistance to corrosion, will be one of the mainstream development orientations of non-chrome possivation undoubtedly.
中图分类号 TG174.4
所属栏目 专论
基金项目 国家自然科学基金(51179182); 山东省青岛市市南区科技发展基金(P2010-1-ZH-005); 山东省博士后基金(BS2009HZ002); 香港王宽诚教育基金(20061231)
收稿日期 2012/2/21
修改稿日期
网络出版日期
作者单位点击查看
备注李伟华, 副研究员, 博士,
引用该论文: JIANG Qin2,LI Wei-hua,HOU Bao-rong,ZHANG Lu. Progress of Chromium-free Passivation of Galvanized Steel Sheet[J]. Corrosion & Protection, 2013, 34(2): 101
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参考文献
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【33】张洪生, 杨晓蕾, 陈熹.植酸用于金属防护的实用技术[J].腐蚀与防护, 2002, 23(9):403-407.
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【37】许哲峰, 梅东生, 刘常升, 等.热镀锌板表面单宁酸－H2 TiF6 /SiO2复合涂层的防腐性能研究[J].四川大学学报(工程科学版), 2011, 43(2):197-201.
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【46】Kartsonakis I A, Balaskas A C, Koumoulos E P, et al.Incorporation of ceramic nanocontainers into epoxy coatings for the corrosion protection of hot dip galvanized steel[J].Corrosion Science, 2012, 57(1):30-41.
【47】Bajat J B, Miskovic-Stankovic V B, Popic J P, et al.Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel[J].Progress in Organic Coatings, 2008, 63(2):201-208.
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【2】Kubrak O I, Lushchak O V, Lushchak J V, et al. Chromium effects on free radical processes in goldfish tissues:Comparison of Cr(III) and Cr(VI) exposures on oxidative stress markers, glutathione status andantioxidant enzymes[J].Comparative Biochemistry and Physiology, Part C, 2010, 152(2):360-370.
【3】柳长福, 涂元强, 郭玉华.镀锡板的无铬钝化[J].武钢技术, 2003, 41(5):47-49.
【4】王惠敏, 陈玫, 李基森.镀锌层三价铬钝化剂的探讨[J].中国表面工程, 2008, 21(2):40-43.
【5】吴剑胜.镀锌无铬钝化产品生产工艺优化[J].工艺装备, 2009, 3(1):29-32.
【6】云广平, 郭万振.铁基电镀锌层的无铬钝化处理研究[J].电子科技, 2011, 24(2):115-118.
【7】黄可坤.无铬钝化液[P].中国专利:2004100210311, 2004-12-22..
【8】Sakural H, Kishikawa S, Yamamoto T, et al. Solution and process for black chromating[P].EP Pat: 0805222, 1996-05-01.
【9】Tsai C Y, Liu J S, Chen P L, et al. A roll coating tungstate passivation treatment for hot-dip galvanized sheet steel[J].Surface & Coatings Technology, 2011, 205(12):5124-5129.
【10】董鹏, 张英杰.镀锌层硅酸盐钝化膜的耐腐蚀性能[J].材料保护, 2010, 43(10):4-6.
【11】刘文君, 张英杰, 章江洪, 等.工艺因素对硅酸盐无铬钝化中耐蚀性的影响[J].表面技术, 2007, 36(1):60-61.
【12】Yuan M R, Lu J T, Kong G, et al. Effect of silicate anion distribution in sodium silicate solution on silicate conversion coatings of hot-dip galvanized steels[J].Surface & Coatings Technology, 2011, 205(10):4466-4470.
【13】Min J, Park J H, Sohn H K, et al. Synergistic effect of potassium metal siliconate on silicate conversion coating for corrosion protection of galvanized steel[J].Journal of Industrial and Engineering Chemistry, 2012(18):655-660.
【14】卢琳, 李晓刚, 宫丽, 等.镀锌层无铬钝化的现状与发展趋向[J].轧钢, 2007, 24(5):41-45.
【15】刘洪锋, 何明奕, 王胜民, 等.热镀锌层钛盐钝化膜耐蚀性能的研究[J].材料热处理技术, 2011, 40(18):138-140.
【16】丁楠, 杨飞, 朱立群.钝化工艺参数对镀锌钛盐钝化膜色泽的影响[J].材料保护, 2008, 41(5):45-48.
【17】Berger R, Bexell U T, Grehk M, et al. A comparative study of the corrosion protective properties of chromium and chromium free passivation methods[J].Surface & Coatings Technology, 2007, 202(1):391-397.
【18】郭崇武, 赖奂汶.镀锌层无铬钝化技术研究进展[J].全面腐蚀控制, 2011, 25(7):13-16.
【19】左正忠, 崔萍, 宋文超, 等.镀锌层钛盐钝化的研究[J].电镀与精饰, 2010, 32(11):9-12.
【20】郭瑞光, 耿志良.无铬转化膜技术研究的几点建议[J].电镀与涂饰.2008, 27(5):38-40.
【21】刘艳荣, 周婉秋, 赵强, 等.镀锌板表面无铬钝化的研究进展[J].电镀与精饰, 2010, 32(4):22-26.
【22】刘小风, 曹晓燕, 满瑞林.镀锌钢板稀土镧盐钝化工艺[J].腐蚀与防护, 2011, 32(6):483-485.
【23】Ping H K, Kui W J. Decorative and protective coatings on zinc using rare erths[J].Trans Metal Fin(India), 1996, 5(2):83.
【24】龚利华, 朱玉巧.稀土盐钝化镀锌板工艺研究[J].稀土, 2011, 32(4):25-29.
【25】柳长福, 涂元强, 郭玉华, 等.钴盐在镀锡板无铬钝化中的应用研究[J].钢铁研究, 2009, 37(5):34-36.
【26】Schriever M P. Non-chromated oxide coating for aluminum substrates[P].USPat:5468307, 1995-11-21.
【27】Shigekuni T, Nakakoij K, Lwasa H. Development of phosphate based new passivation treatment[C]//8th International Tinplate Conference.Paris, 2004-10-25.
【28】朱玉巧.镀锌板绿色钝化及其性能研究[D].镇江: 江苏科技大学硕士学位论文, 2009.
【29】Montemor M F, Simes A M, Ferreira M G S. Composition and behaviour of cerium films on galvanized steel[J].Progress in Organic Coatings, 2001, 43(4):274-281..
【30】成信刚, 李宁, 黎德育.镀锡板无铬钝化的现状与发展前景[J].电镀与环保, 2006, 26(3):5-9.
【31】Shimakura, Toshiak I, Sasak I, et al. Non-chromate metallic surface-treating agent method for surface treatment and treated steel material[P].US Pat:647530, 2002.
【32】Shimakura, Toshiak I, Sasak I. Method for treating metallic surfaces[P].US Pat:6572983, 2003.
【33】张洪生, 杨晓蕾, 陈熹.植酸用于金属防护的实用技术[J].腐蚀与防护, 2002, 23(9):403-407.
【34】Daniel F. Surface treatment of metal sheet[P].US Pat:5925417, 1999..
【35】周金宝.镀锌层无铬钝化工艺的新进展[J].电镀与环保, 1991, 11(5):7-10.
【36】张安富.镀锌系钢板表面处理新工艺[J].表面技术, 1991, 20(5):29-33.
【37】许哲峰, 梅东生, 刘常升, 等.热镀锌板表面单宁酸－H2 TiF6 /SiO2复合涂层的防腐性能研究[J].四川大学学报(工程科学版), 2011, 43(2):197-201.
【38】易徳莲, 王静, 李宇鹏, 等.镀锌板的复合钝化[J].腐蚀与防护, 2010, 31(2):142-145.
【39】吴海江, 杨飞英.热镀锌钢表面硅烷膜的腐蚀电化学性能[J].中国表面工程, 2009, 22(5):66-69.
【40】Kim H J, Zhang J M, Yoon R H, et al. Development of environmentally friendly nonchrome conversion coating for electrogalvanized steel[J].Surface & Coatings Technology 2004, 189(2):762-767.
【41】刘劼, 胡士幸, 杨召辉.马钢无铬钝化热镀锌产品的研制[J].上海金属, 2007, 29(5):193-195.
【42】徐斌, 满瑞林, 彭天兰, 等.镀锌钢板的硅烷复合膜表面改性[J].腐蚀科学与防护技术, 2008, 20(2):135-139.
【43】张伟, 王永刚, 胡汉国.有机-无机复合铬钝化技术研究进展[J].用油全方位, 2011(2):34-38.
【44】Jiang B, Ou Y.Non-chromium method for galvanized metal surfaces[P].US Pat:5662967, 1997.
【45】Hager H E, Blohowiak K Y.Chromium-free protective coatings[P].EP Pat:0792922, 1997.
【46】Kartsonakis I A, Balaskas A C, Koumoulos E P, et al.Incorporation of ceramic nanocontainers into epoxy coatings for the corrosion protection of hot dip galvanized steel[J].Corrosion Science, 2012, 57(1):30-41.
【47】Bajat J B, Miskovic-Stankovic V B, Popic J P, et al.Adhesion characteristics and corrosion stability of epoxy coatings electrodeposited on phosphated hot-dip galvanized steel[J].Progress in Organic Coatings, 2008, 63(2):201-208.
【48】Wippermann K, Schuitze J W, Kesse R, et al. The inhibition of zinc corrosion by bis-aminotriazole and other triazole derivatives[J].Corrosion Science, 1991, 32(2):205.
【49】刘朴, 魏宇, 谢贤龙.宝钢热镀锌无铬钝化钢板的生产[J].宝钢技术, 2008, 25(1):77-80.
【50】王雷, 刘常升, 安成强.镀锌层无机物与有机物复合无铬钝化研究进展[J].电镀与涂饰, 2011, 33 (3):22-26.
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