Corrosion Characteristics of 20# Steel in Water Granulation Sulfur Solidification Process
摘 要
采用试片悬挂转动的方法模拟水造粒硫磺成型过程,通过腐蚀失重、扫描电镜观察、能谱分析和XRD分析,研究了温度和位置因素对20号钢在水造粒硫磺颗粒成型过程中的腐蚀特征。结果表明,20号钢在水造粒硫磺颗粒成型过程中腐蚀很严重,腐蚀速率介于1.111 4~5.962 3 mm/a之间,远远超过了含硫气田腐蚀控制标准0.075 mm/a。试片表面至少形成两层腐蚀产物膜,主要为氧化铁和硫化亚铁,高温和冲刷会加快腐蚀速率。建议现场硫磺成型过程中尽量避免使用20号钢,并定期进行检测。
Abstract
The method of rotating the suspended metal samples was used to simulate the water granulation sulfur solidification process. Corrosion weight loss method, scanning electron microscopy, EDS and X-ray diffraction(XRD) were used to study the corrosion characteristics of 20# steel in the process which was influenced by temperature and position. The results show that 20# steel corroded severely in the process, the corrosion rate was between 1.111 4 mm/a and 5.962 3 mm/a, and high temperature and erosion would accelerate the rate. Two layers of corrosion products were formed on the surface of 20# steel. The main components of the layers were Fe2O3 and FeS. 20# steel is not suitable for sulfur solidification process. So, to avoid using 20# steel in the process is necessary and the process should be inspected regularly.
中图分类号 TG174
所属栏目 试验研究
基金项目 国家科技重大专项(2011ZX05017); 国家自然科学基金(51174171)
收稿日期 2012/12/30
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备注龙德才,硕士研究生,
引用该论文: SHANG Jian-feng,LONG De-cai,TIAN Gang,LUO Bao-jun,LIU Yuan-zhi,XIAO Guo-qing. Corrosion Characteristics of 20# Steel in Water Granulation Sulfur Solidification Process[J]. Corrosion & Protection, 2013, 34(10): 879
被引情况:
【1】曾德智,商剑峰,龙德才,刘元直,崔文鹏,张恒伟, "四种钢在硫磺回收装置中的耐蚀性能及适用性",机械工程材料 39, 91-96(2015)
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参考文献
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