FAAS Determination of K and Na in Coke Ash with Microwave Assisted Sample Digestion
摘 要
0.1000g焦炭灰样品经氢氟酸-硝酸(1+3)溶液8 mL消解,用火焰原子吸收光谱法测定其中钾和钠的含量。钾和钠的质量浓度分别在4 mg·L-1及2 mg·L-1以内与其吸光度呈线性关系,检出限(3σ)分别为12 μg·L-1及6 μg·L-1。方法用于分析焦炭灰标准物质,测定值与认定值相符,钾和钠的相对标准偏差(n=11)依次在2.7%~3.8%和1.3%~3.1%之间。
Abstract
Sample of coke ash (0.100 0 g) was digested with 8 mL of mixed acid of HF and HNO3 (1+3), and the contents of K and Na in the sample solution were determined by FAAS. Linear relationships between values of absorbance and mass concentration of K and Na were obtained in the ranges within 4 mg·L-1 and 2 mg·L-1, with detection limits (3σ) of 12 μg·L-1 and 6 μg·L-1, respectively. The proposed method was applied to the analysis of CRM′s, giving results in consistency with the certified values. Values of RSD′s (n=11) found were in the ranges of 2.7%-3.8% for K and 1.3%-3.1% for Na.
中图分类号 O657.31
所属栏目 工作简报
基金项目 出入境检验检疫行业标准项目(2009B663)
收稿日期 2012/1/8
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联系人作者杨俊(yjzcgaaa@163.com)
备注杨俊(1981-),女,河北大厂人,博士,主要从事矿产品的检验及科研工作。
引用该论文: YANG Jun,CHEN Xue-lian,LIU Wen-xin,ZHAO Zhen-gang. FAAS Determination of K and Na in Coke Ash with Microwave Assisted Sample Digestion[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2013, 49(5): 529~530
杨俊,陈雪莲,刘文欣,赵振纲. 微波消解样品-火焰原子吸收光谱法测定焦炭灰中钾、钠含量[J]. 理化检验-化学分册, 2013, 49(5): 529~530
被引情况:
【1】李吉春, "火焰原子吸收光谱法测定偏钒酸钾中钠",理化检验-化学分册 51, 263-264(2015)
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参考文献
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【2】胡德生.灰成分对焦炭热性能的影响[J].钢铁, 2002,37(8):9-13.
【3】陈燕芹,刘红.微波消解试样-火焰原子吸收光谱法测定粉煤灰中重金属元素[J].理化检验-化学分册, 2010,46(9):1006-1007.
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