固体超强酸NiO-ZrO2/SO42-的合成及其对葡萄糖电催化氧化的研究
Synthesis of Solid Superacid NiO-ZrO2/SO42- and Its Electrocatalytic Activity for Glucose Oxidation
摘 要
制备了固体超强酸NiO-ZrO2/SO42-,并研究了其对葡萄糖的电催化氧化性能.利用X射线衍射、扫描电镜以及傅里叶变换红外光谱法对其进行表征,同时研究了其对葡萄糖的电催化氧化性能.结果表明:起主要催化作用的为NiO-ZrO2/SO42-中镍的活性物质,而ZrO2/SO42-上的缺电子金属中心加速了反应过程中电子的转移速率,使得NiO-ZrO2/SO42-相比于NiO/SO42-有更低的峰电位,并且表现出更好的稳定性.
固体超强酸
葡萄糖
氧化
Electrocatalysis
Solid superacid
Glucose
Oxidation
Abstract
Solid superacid NiO-ZrO2/SO42- was synthesized and its electrocatalytic activity for glucose oxidation were studied.The nanostructure was characterized by X-ray diffraction,scanning electron microscope and Fourier transform infrared spectroscopy.Its electrocatalytic activity for glucose oxidation was studied.It was shown that the catalytic effect was mainly caused by the active material of Ni in NiO-ZrO2/SO42-,and the electro-deficient metal centers of ZrO2/SO42- accelerated electron transfer rate during reaction process.Therefore,comparing with NiO/SO42-,the NiO-ZrO2/SO42- possessed lower peak potential and more satisfactory stability.
中图分类号 O657
所属栏目 试验与研究
基金项目 上海高校青年教师培养资助计划(51-14-341-106)
收稿日期 2014/10/16
修改稿日期
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备注顾颖颖(1976-),女,上海人,博士,主要从事燃料电池研究工作.
引用该论文: GU Ying-ying,LIU Yi-cheng,YANG Hai-hong,LI Ben-qiang,AN Ya-rui,ZHOU Shi-lin. Synthesis of Solid Superacid NiO-ZrO2/SO42- and Its Electrocatalytic Activity for Glucose Oxidation[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2015, 51(5): 586～590
顾颖颖,刘易成,杨海宏,李奔强,安雅睿,周仕林. 固体超强酸NiO-ZrO2/SO42-的合成及其对葡萄糖电催化氧化的研究[J]. 理化检验－化学分册, 2015, 51(5): 586～590
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参考文献
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【3】周亚樵,林培华.定量测定葡萄糖方法的研究[J].理化检验-化学分册,2000,36(9):415-415.
【4】LIU Xian-hua,HAO Miao-qing,FENG Meng-nan,et al.A one-compartment direct glucose alkaline fuel cell with methyl viologen as electron mediator[J].Applied Energy,2013,106:176-183.
【5】SATHIYANATHAN F,PRATAP K,RAGHUPATHY BALA P C,et al.Electrocatalytic activity of Cu2O nanocubes based electrode for glucose oxidation[J].Journal of Chemical Sciences,2014,126:25-32.
【6】ALEKSANDER C,IZABELA S.Nanoparticles of Ni(OH)2 embedded in chitosan membrane as electrocatalyst for non-enzymatic oxidation of glucose[J].Electrochimica Acta,2013,111:185-191.
【7】CONGHAILE P O,SASCHA P,DOMHNALL M,et al.Coupling osmium complexes to epoxy-functionalised polymers to provide mediated enzyme electrodes for glucose oxidation[J].Biosensors and Bioelectronics,2013,43:30-37.
【8】AYAKO T,SHO T,TAKASHI T,et al.Reprint of “Synergetic combination of an enzyme and gold catalysts for glucose oxidation in neutral aqueous solution”[J].Applied Catalysis A: General,2014,474:257-262.
【9】CHEN Chao,XIE Qing-ji,YANG Da-wei,et al.Recent advances in electrochemical glucose biosensors: a review[J].RSC Advances,2013,3:4473-4491.
【10】GAO Shan,CHEN Xiong-bo,WANG Hai-qiang,et al.Ceria supported on sulfated zirconia as a superacid catalyst for selective catalytic reduction of NO with NH3[J].Journal of Colloid and Interface Science,2013,394:515-521.
【11】CHEN Peng-fei,DU Ming-xing,LEI He,et al.SO42-/ZrO2- titania nanotubes as efficient solid superacid catalysts for selective mononitration of toluene[J].Catalysis Communications,2012,18:47-50.
【12】EL-REFAEI S M,AWAD M I,EL-ANADOULI B E,et al.Electrocatalytic glucose oxidation at binary catalyst of nickel and manganese oxides nanoparticles modified glassy carbon electrode: optimization of the loading level and order of deposition[J].Electrochimica Acta,2013,92:460-467.
【13】CHEN Peng-fei,DU Ming-xing,LEI He,et al.SO42-/ZrO2-titania nanotubes as efficient solid superacid catalysts for selective mononitration of toluene[J].Catalysis Communications,2012,18:47-50.
【14】MAO Wei,MA Hong-zhu,WANG Bo.A clean method for solvent-free nitration of toluene over sulfated titania promoted by ceria catalysts[J].Journal of Hazardous Materials,2009,167:707-712.
【15】SOHN J R,KIM H J.High catalytic activity of NiO-TiO2/SO42- for ethylene dimerization[J].Journal of Catalysis,1986,101:428-433.
【16】LI Xiao-ling,YAO Jian-yu,LIU Fei-la,et al.Nickel/Copper nanoparticles modified TiO2 nanotubes for non-enzymatic glucose biosensors[J].Sensors and Actuators B: Chemical,2013,181:501-508.
【17】KIBRIA M F,MRIHDAM S.Elecrtochemical studies of the nick elelecrtode for the oxygen evolution reaction[J].International Journal of Hydrogen Energy,1996,21:179-182.
【18】王超群,刑政良,王宁,等.氢氧化镍电极材料γ-NiOOH的定量相分析[J].电源技术,1999,23(6):328-331.
【19】刘澧浦,周震涛.羟基氧化镍的研究进展[J].电源技术,2004,28(8):520-524.
【20】KUNG C W,LIN C Y,LAI Y H,et al.Cobalt oxide acicular nanorods with high sensitivity for the non-enzymatic detection of glucose[J].Biosensors and Bioelectronics,2011,27:125-131.
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