金属腐蚀微区电化学研究进展(1)扫描电化学显微镜技术
Development of Electrochemical Studies in Microzone of Metallic Corrosion (1) Scanning Electrochemical Microscopy
摘 要
近年来,随着微区电化学理论与测试技术的发展,微区电化学技术在腐蚀领域已作为一种重要的测试方法被广泛应用,本文概括了扫描电化学显微镜基本原理,重点对该微区电化学技术在金属腐蚀研究中的应用进行了阐述.
局部腐蚀
微区
scanning electrochemical microscopy(SECM)
localized corrosion
microzone
Abstract
In the recent years,with the development of electrochemical theory as well as measurement and testing technology for microzones,microzone techniques are very important measurement methods widely used in corrosion areas.In this paper,the basic principle of scanning electrochemical microscopy is describe.Especially the application of this technique in the studies of metallic corrosion is illustrated.
中图分类号 TG174.3
所属栏目 专论
基金项目 国家基础条件平台建设项目(No.2005DKA10400)和国家自然科学基金项目(50771020和50871021)的资助
收稿日期 2009/2/17
修改稿日期 2009/3/5
网络出版日期
作者单位点击查看
备注骆鸿,硕士研究生.
引用该论文: LUO Hong,WEI Dan,DONG Chao-fang,XIAO Kui,LI Xiao-gang,LIN Chun-fang. Development of Electrochemical Studies in Microzone of Metallic Corrosion (1) Scanning Electrochemical Microscopy[J]. Corrosion & Protection, 2009, 30(7): 437～441
被引情况:
【1】张俊良,赵启亮,钟庆东,郭 炜, "镀锌层表面钝化膜在5% NaCl溶液中的腐蚀降解过程和半导体行为",腐蚀与防护 37, 973-978(2016)
【2】张明明,孟君,黄晓义,路遥, "利用SECM技术研究304不锈钢的点蚀行为",腐蚀与防护 33, 482-485(2012)
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参考文献
【1】A J Bard,F F Fan,J Kwak,et al.Scanning electrochemical microscopy introduction and principal[J].Analytica Chimica Acta,1989,61(2):132-138.
【2】J Kwak,A J Bard.Scanning electrochemical microscopy theory of the feedback mode[J].Analytica Chimica Acta,1989(61):1221-1227.
【3】Michael V Mirkin,Benjamin R Horrocks.Electroanalytical measurements using the scanning electrochemical microscope[J].Analytica Chimica Acta,2000(406):119-146.
【4】N Casillas,S J Charlebois,W H Smyrl,et al.Scanning electrochemical microscopy of precursor sites for pitting corrosion on titanium[J].Journal of the Electrochemical Society,1993,140(9):L142-L145.
【5】Y Zhu,D E Williams.Scanning electrochemical microscopic observation of a precursor state to pitting corrosion of stainless-steel[J].Journal of the Electrochemical Society,1997(144):L43-L45.
【6】D E Williams,T F Mohiuddin,Y Zhu.Elucidation of a trigger mechanism for pitting corrosion of stainless-steels using submicron resolution scanning electrochemical and photoelectrochemical microscopy[J].Journal of the Electrochemical Society,1998(145):2664-2672.
【7】Y Gonzalez-Garcia,G T Burstein,S Gonzalez,et al.Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential[J].Electrochemistry Communications,2004(6):637-642.
【8】A Schulte,S Belger,M Etienne,et al.Imaging localised corrosion of NiTi shape memory alloys by means of alternating current scanning electrochemical microscopy (AC-SECM)[J].Materials Science and Engineering,2004,(A378):523-526.
【9】C Gabrielli,S Joiret,M Keddam,et al. A SECM assisted EQCM study of iron pitting[J].Electrochimica Acta,2007(52):7706-7714.
【10】Kathrin Eckhard,Mathieu Etienne,Albert Schulte,et al.Constant-distance mode AC-SECM for the visualization of corrosion pits[J].Electrochemistry Communications,2007(9):1793-1797.
【11】C Gabrielli,S Joiret,M Keddam,et al.Single pit on iron generated by SECM An electrochemical impedance spectroscopy investigation[J].Electrochimica Acta,2008(53):7539-7548.
【12】A C Bastos,A M Simes.Application of the scanning electrochemical microscope to the examination of organic coatings on:metallic substrates[J].Progress in Organic Coatings,2005(53):177-182.
【13】A M Simes,D Battocchi,D E Tallman,et al.SVET and SECM imaging of cathodic protection of aluminum by a Mg-rich coating[J].Corrosion Science,2007(49):3838-3849.
【14】R M Souto,Y González-García,S González.Evaluation of the corrosion performance of coil-coated steel sheet as studied by scanning electrochemical microscopy[J].Corrosion Science,2008(50):1637-1643.
【15】Bernardo Ballesteros Katemann,Carlota González Inchauspe.Precursor sites for localised corrosion on lacquered tinplates visualised by means of alternating current scanning electrochemical microscopy[J].Electrochimica Acta,2003(48):1151-1121.
【16】R M Souto,Y González-García,S González.In situ monitoring of electroactive species by using the scanning electrochemical microscope.Application to the investigation of degradation processes at defective coated metals[J].Corrosion Science,2005(47):3312-3323.
【17】Koji Fushimi,Kirsten A Lill,Hiroki Habazaki.Heterogeneous hydrogen evolution on corroding at Fe-3 % Si surface observed by scanning electrochemical microscopy[J].Electrochimica Acta,2007(52):4246-4253.
【18】A M Simes,A C Bastos.Use of SVET and SECM to study the galvanic corrosion of an iron-zinc cell[J].Corrosion Science,2007(49):726-739.
【19】Edgar Vlker,Carlota González Inchauspe,Ernesto J Calvo.Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel[J].Electrochemistry Communications,2006(8):179-183.
【20】T E Lister,P J Pinhero,T L Trowbridge,et al.Localized attack of a two-phase metal,scanning electrochemical microscopy studies of NiCrMoGd alloys[J].Journal of Electroanalytical Chemistry,2005(579):291-298.
【21】A Davoodi,J Pan,C Leygraf,et al.Probing of local dissolution of Al-alloys in chloride solutions by AFM and SECM[J].Applied Surface Science,2006(252):5499-5503.
【2】J Kwak,A J Bard.Scanning electrochemical microscopy theory of the feedback mode[J].Analytica Chimica Acta,1989(61):1221-1227.
【3】Michael V Mirkin,Benjamin R Horrocks.Electroanalytical measurements using the scanning electrochemical microscope[J].Analytica Chimica Acta,2000(406):119-146.
【4】N Casillas,S J Charlebois,W H Smyrl,et al.Scanning electrochemical microscopy of precursor sites for pitting corrosion on titanium[J].Journal of the Electrochemical Society,1993,140(9):L142-L145.
【5】Y Zhu,D E Williams.Scanning electrochemical microscopic observation of a precursor state to pitting corrosion of stainless-steel[J].Journal of the Electrochemical Society,1997(144):L43-L45.
【6】D E Williams,T F Mohiuddin,Y Zhu.Elucidation of a trigger mechanism for pitting corrosion of stainless-steels using submicron resolution scanning electrochemical and photoelectrochemical microscopy[J].Journal of the Electrochemical Society,1998(145):2664-2672.
【7】Y Gonzalez-Garcia,G T Burstein,S Gonzalez,et al.Imaging metastable pits on austenitic stainless steel in situ at the open-circuit corrosion potential[J].Electrochemistry Communications,2004(6):637-642.
【8】A Schulte,S Belger,M Etienne,et al.Imaging localised corrosion of NiTi shape memory alloys by means of alternating current scanning electrochemical microscopy (AC-SECM)[J].Materials Science and Engineering,2004,(A378):523-526.
【9】C Gabrielli,S Joiret,M Keddam,et al. A SECM assisted EQCM study of iron pitting[J].Electrochimica Acta,2007(52):7706-7714.
【10】Kathrin Eckhard,Mathieu Etienne,Albert Schulte,et al.Constant-distance mode AC-SECM for the visualization of corrosion pits[J].Electrochemistry Communications,2007(9):1793-1797.
【11】C Gabrielli,S Joiret,M Keddam,et al.Single pit on iron generated by SECM An electrochemical impedance spectroscopy investigation[J].Electrochimica Acta,2008(53):7539-7548.
【12】A C Bastos,A M Simes.Application of the scanning electrochemical microscope to the examination of organic coatings on:metallic substrates[J].Progress in Organic Coatings,2005(53):177-182.
【13】A M Simes,D Battocchi,D E Tallman,et al.SVET and SECM imaging of cathodic protection of aluminum by a Mg-rich coating[J].Corrosion Science,2007(49):3838-3849.
【14】R M Souto,Y González-García,S González.Evaluation of the corrosion performance of coil-coated steel sheet as studied by scanning electrochemical microscopy[J].Corrosion Science,2008(50):1637-1643.
【15】Bernardo Ballesteros Katemann,Carlota González Inchauspe.Precursor sites for localised corrosion on lacquered tinplates visualised by means of alternating current scanning electrochemical microscopy[J].Electrochimica Acta,2003(48):1151-1121.
【16】R M Souto,Y González-García,S González.In situ monitoring of electroactive species by using the scanning electrochemical microscope.Application to the investigation of degradation processes at defective coated metals[J].Corrosion Science,2005(47):3312-3323.
【17】Koji Fushimi,Kirsten A Lill,Hiroki Habazaki.Heterogeneous hydrogen evolution on corroding at Fe-3 % Si surface observed by scanning electrochemical microscopy[J].Electrochimica Acta,2007(52):4246-4253.
【18】A M Simes,A C Bastos.Use of SVET and SECM to study the galvanic corrosion of an iron-zinc cell[J].Corrosion Science,2007(49):726-739.
【19】Edgar Vlker,Carlota González Inchauspe,Ernesto J Calvo.Scanning electrochemical microscopy measurement of ferrous ion fluxes during localized corrosion of steel[J].Electrochemistry Communications,2006(8):179-183.
【20】T E Lister,P J Pinhero,T L Trowbridge,et al.Localized attack of a two-phase metal,scanning electrochemical microscopy studies of NiCrMoGd alloys[J].Journal of Electroanalytical Chemistry,2005(579):291-298.
【21】A Davoodi,J Pan,C Leygraf,et al.Probing of local dissolution of Al-alloys in chloride solutions by AFM and SECM[J].Applied Surface Science,2006(252):5499-5503.
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