金属腐蚀微区电化学研究进展(3)扫描振动电极技术
Development of Microzone Electrochemical Studies of Metallic Corrosion (3) Scanning Vibrating Electrode Technique
摘 要
近年来,随着微区电化学理论与测试技术的发展,微区电化学技术在腐蚀领域已作为一种重要的测试方法被广泛应用,本文概括了扫描振动电极的基本原理,重点对该技术在金属腐蚀研究领域的应用进行了阐述.
局部腐蚀
微区
scanning vibrating electrode technique(SVET)
localized corrosion
microzone
Abstract
In recent years,with the development of microzone electrochemical theory and measurement & testing technology,microzone techniques are very important measure mentmethods that can be widely used in corrosion areas.In this paper,the basic principle of scanning vibrating electrode technique is described.Especially the application of this technique in the studies of metallic corrosion is illustrated.
中图分类号 TG174.3
所属栏目 专论
基金项目 国家基础条件平台建设项目(No.2005DKA10400);国家自然科学基金项目(50771020和50871021)
收稿日期 2009/2/17
修改稿日期 2009/3/5
网络出版日期
作者单位点击查看
备注骆鸿,硕士研究生.
引用该论文: LUO Hong,DONG Chao-fang,XIAO Kui,LI Xiao-gang,WEI Dan. Development of Microzone Electrochemical Studies of Metallic Corrosion (3) Scanning Vibrating Electrode Technique[J]. Corrosion & Protection, 2009, 30(9): 631～635
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参考文献
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【2】Oltra R,Maurice V,Akid R,et al.Local probe techniques for corrosion research[M].Woodhead Publishing Limited,Cambridge England,2007:23-25.
【3】Bhm S,McMurray H N,Powell S M,et al.Photoelectrochemical investigation of corrosion using scanning electrochemical techniques[J].Electrochimica Acta,2000(45):2165-2174.
【4】Souto R M,González-García Y,Bastos A C,et al.Investigating corrosion processes in the micrometric range: A SVET study of the galvanic corrosion of zinc coupled with iron[J].Corrosion Science,2007(49):4568-4580.
【5】Vuillemin B,Philippe X,Oltra R,et al.SVET,AFM and AES study of pitting corrosion initiated on MnS inclusions by microinjection[J].Corrosion Science,2003(45):1143-1159.
【6】Vignal V,Krawiec H,Heintz O,et al.The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels[J].Electrochimica Acta,2007(52):4994-5001.
【7】Iken H,Basseguy R,Guenbour A,et al.Classic and local analysis of corrosion behaviour of graphite and stainless steels in polluted phosphoric acid[J].Electrochimica Acta,2007(52):2580-2587.
【8】Alda Simes,Dante Battocchi,Dennis Tallman.Assessment of the corrosion protection of aluminium substrates by a Mg-rich primer: EIS,SVET and SECM study[J].Progress in Organic Coatings,2008(63):260-266.
【9】David J Penney,James H Sullivan,David A.Worsley Investigation into the effects of metallic coating thickness on the corrosion properties of Zn-Al alloy galvanising coatings[J].Corrosion Science,2007(49):1321-1339.
【10】Worsley D A,Williams D,Ling J S G.Mechanistic changes in cut-edge corrosion induced by variation of organic coating porosity[J].Corrosion Science,2001(43):2335-2348.
【11】Bastos A C,Ferreira M G,Simes A M.Corrosion inhibition by chromate and phosphate extracts for iron substrates studied by EIS and SVET[J].Corrosion Science,2006(48):1500-1512.
【12】Khobaib M,Rensi A,Matakis T,et al.Real time mapping of corrosion activity under coatings[J].Progress in Organic Coatings,2001(41):266-272.
【13】Gordon Bierwagen,Dante Battocchi,Alda Simes,et al.The use of multiple electrochemical techniques to characterize Mg-rich primers for Al alloys[J].Progress in Organic Coatings,2007(59):172-178.
【14】He J,Gelling V J,ETallman D,et al.Conducting polymers and corrosion III.A scanning vibrating electrode study of poly(3-octyl pyrrole) on steel and aluminum[J].Journal of The Electrochemical Society,2000,147(10):3667-3672.
【15】Zheludkevich M L,Yasakau K A,Bastos A C,et al.On the application of electrochemical impedance spectroscopy to study the self-healing properties of protective coatings[J].Electrochemistry Communications,2007(9):2622-2628.
【16】Zin I M,Lyon S B,Hussain A.Under-film corrosion of epoxy-coated galvanised steel An EIS and SVET study of the effect of inhibition at defects[J].Progress in Organic Coatings,2005(52):126-135.
【17】Montemor M F,Trabelsi W,Lamaka S V,et al.The synergistic combination of bis-silane and CeO2·ZrO2 nanoparticles on the electrochemical behaviour of galvanised steel in NaCl solutions[J].Electrochimica Acta,2008(53):5913-5922.
【18】Montemor M F,Ferreira M G S.Cerium salt activated nanoparticles as fillers for silane films: Evaluation of the corrosion inhibition performance on galvanised steel substrates[J].Electrochimica Acta,2007(52):6976-6987.
【19】Montemor M F,Simes A M,Carmezim M J.Characterization of rare-earth conversion films formed on the AZ31 magnesium alloy and its relation with corrosion protection[J].Applied Surface Science,2007(253):6922-6931.
【20】Trabelsi W,Cecílio P,Ferreira M G S,et al.Surface evaluation and electrochemical behaviour of doped silane pre-treatments on galvanised steel substrates[J].Progress in Organic Coatings,2007(59):214-223.
【21】Montemor M F,Ferreira M G S.Electrochemical study of modified bis-［triethoxysilylpropyl］ tetrasulfide silane films applied on the AZ31 Mg alloy[J].Electrochimica Acta,2007(52):7486-7495.
【22】Franois Berger,Joseph Delhalle,Zineb Mekhalif.Hybrid coating on steel: ZnNi electrodeposition and surface modification with organothiols and diazonium salts[J].Electrochimica Acta,2008(53):2852-2861.
【2】Oltra R,Maurice V,Akid R,et al.Local probe techniques for corrosion research[M].Woodhead Publishing Limited,Cambridge England,2007:23-25.
【3】Bhm S,McMurray H N,Powell S M,et al.Photoelectrochemical investigation of corrosion using scanning electrochemical techniques[J].Electrochimica Acta,2000(45):2165-2174.
【4】Souto R M,González-García Y,Bastos A C,et al.Investigating corrosion processes in the micrometric range: A SVET study of the galvanic corrosion of zinc coupled with iron[J].Corrosion Science,2007(49):4568-4580.
【5】Vuillemin B,Philippe X,Oltra R,et al.SVET,AFM and AES study of pitting corrosion initiated on MnS inclusions by microinjection[J].Corrosion Science,2003(45):1143-1159.
【6】Vignal V,Krawiec H,Heintz O,et al.The use of local electrochemical probes and surface analysis methods to study the electrochemical behaviour and pitting corrosion of stainless steels[J].Electrochimica Acta,2007(52):4994-5001.
【7】Iken H,Basseguy R,Guenbour A,et al.Classic and local analysis of corrosion behaviour of graphite and stainless steels in polluted phosphoric acid[J].Electrochimica Acta,2007(52):2580-2587.
【8】Alda Simes,Dante Battocchi,Dennis Tallman.Assessment of the corrosion protection of aluminium substrates by a Mg-rich primer: EIS,SVET and SECM study[J].Progress in Organic Coatings,2008(63):260-266.
【9】David J Penney,James H Sullivan,David A.Worsley Investigation into the effects of metallic coating thickness on the corrosion properties of Zn-Al alloy galvanising coatings[J].Corrosion Science,2007(49):1321-1339.
【10】Worsley D A,Williams D,Ling J S G.Mechanistic changes in cut-edge corrosion induced by variation of organic coating porosity[J].Corrosion Science,2001(43):2335-2348.
【11】Bastos A C,Ferreira M G,Simes A M.Corrosion inhibition by chromate and phosphate extracts for iron substrates studied by EIS and SVET[J].Corrosion Science,2006(48):1500-1512.
【12】Khobaib M,Rensi A,Matakis T,et al.Real time mapping of corrosion activity under coatings[J].Progress in Organic Coatings,2001(41):266-272.
【13】Gordon Bierwagen,Dante Battocchi,Alda Simes,et al.The use of multiple electrochemical techniques to characterize Mg-rich primers for Al alloys[J].Progress in Organic Coatings,2007(59):172-178.
【14】He J,Gelling V J,ETallman D,et al.Conducting polymers and corrosion III.A scanning vibrating electrode study of poly(3-octyl pyrrole) on steel and aluminum[J].Journal of The Electrochemical Society,2000,147(10):3667-3672.
【15】Zheludkevich M L,Yasakau K A,Bastos A C,et al.On the application of electrochemical impedance spectroscopy to study the self-healing properties of protective coatings[J].Electrochemistry Communications,2007(9):2622-2628.
【16】Zin I M,Lyon S B,Hussain A.Under-film corrosion of epoxy-coated galvanised steel An EIS and SVET study of the effect of inhibition at defects[J].Progress in Organic Coatings,2005(52):126-135.
【17】Montemor M F,Trabelsi W,Lamaka S V,et al.The synergistic combination of bis-silane and CeO2·ZrO2 nanoparticles on the electrochemical behaviour of galvanised steel in NaCl solutions[J].Electrochimica Acta,2008(53):5913-5922.
【18】Montemor M F,Ferreira M G S.Cerium salt activated nanoparticles as fillers for silane films: Evaluation of the corrosion inhibition performance on galvanised steel substrates[J].Electrochimica Acta,2007(52):6976-6987.
【19】Montemor M F,Simes A M,Carmezim M J.Characterization of rare-earth conversion films formed on the AZ31 magnesium alloy and its relation with corrosion protection[J].Applied Surface Science,2007(253):6922-6931.
【20】Trabelsi W,Cecílio P,Ferreira M G S,et al.Surface evaluation and electrochemical behaviour of doped silane pre-treatments on galvanised steel substrates[J].Progress in Organic Coatings,2007(59):214-223.
【21】Montemor M F,Ferreira M G S.Electrochemical study of modified bis-［triethoxysilylpropyl］ tetrasulfide silane films applied on the AZ31 Mg alloy[J].Electrochimica Acta,2007(52):7486-7495.
【22】Franois Berger,Joseph Delhalle,Zineb Mekhalif.Hybrid coating on steel: ZnNi electrodeposition and surface modification with organothiols and diazonium salts[J].Electrochimica Acta,2008(53):2852-2861.
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