镁合金无铬化学转化处理的发展现状
Progress in Research on Non-chromate Chemical Conversion Treatment for Magnesium Alloys
摘 要
概述了镁合金无铬化学转化处理的发展现状,重点介绍了磷酸盐处理、磷酸盐-高锰酸盐处理、锡酸盐处理、有机物处理、稀土转化处理等几种化学转化处理方法,对不同处理方法的优点及存在问题进行了简述.
无铬
化学转化处理
magnesium alloy
non-chromate
chemical conversion treatment
Abstract
The recent process in research on non-chromate chemical conversion treatments for magnesium alloys was reviewed.Non-chromate chemical conversion treatments for magnesium alloys such as phosphate conversion treatment,phosphate-permanganate conversion treatment,stannate conversion treatment,organic substance conversion treatment and rare earth conversion treatment were introduced,and the advantages and problems of existing treatments were discussed briefly.
中图分类号 TG178 TG146.2+2
所属栏目 专论
基金项目
收稿日期 2009/7/10
修改稿日期 2009/8/6
网络出版日期
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引用该论文: SUN Feng-xian,JI Hong,LI Yong-feng. Progress in Research on Non-chromate Chemical Conversion Treatment for Magnesium Alloys[J]. Corrosion & Protection, 2010, 31(5): 402～406
被引情况:
【1】蒋晓军,陈昌国,刘渝萍,尹玲,张丁非, "稀土强化镁合金耐蚀性能的研究进展",腐蚀与防护 33, 46-50(2012)
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参考文献
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【2】罗小萍,夏兰廷,臧东勉.镁合金表面化学转化处理研究现状[J].铸造设备研究,2007,4(2):44-47.
【3】王桂香,张密林,董国军,等.镁合金表面化学转化膜的研究进展[J].材料保护,2008,41(1):46-50.
【4】赵明,吴树森,罗吉荣,等.镁合金无铬表面处理现状和前景[J].铸造,2003,52(7),462-465.
【5】赵明,吴树森,安萍,等.AZ91D镁合金表面无铬化转化膜的研究[J].中国腐蚀与防护学报,2007,27(1):17-22.
【6】Zhou Wanqiu,Shan Dayong,Han Enhou,et al.Structure and formation mechanism of phosphate conversion coating on die-cast AZ91D magnesium alloy[J].Corrosion Science,2008,50(2):329-337.
【7】Niu L Y,Jiang Z H,Li G Y,et al.A study and application of zinc phosphate coating on AZ91D magnesium alloy[J].Surface and Coatings Technology,2006,200(9):3021-3026.
【8】Zhao Ming,Wu Shusen,Luo Jirong,et al.A chromium-free conversion coating of magnesium alloy by a phosphate-permanganate solution[J].Surface and Coatings Technology,2006,200(18/19):5407-5412.
【9】Zhang Hua,Yao Guangchun,Wang Shulan,et al.A chrome-free conversion coating for magnesium-lithium alloy by a phosphate-permanganate solution[J].Surface and Coatings Technology,2008,202(9):1825-1830.
【10】Kwo Zong Chong,Teng Shih Shih.Conversion-coating treatment for magnesium alloys by a permanganate-phosphate solution[J].Materials Chemistry and Physics,2003,80(1):191-200.
【11】Lin C S,Lin H C,Lin K M,et al.Formation and properties of stannate conversion coatings on AZ61 magnesium alloys[J].Corrosion Science,2006,48(1):93-109.
【12】Gonzalez-Nunez M A,Nunez-Lopez C A,Skeldon P,et al.A non-chromate conversion coating for magnesium alloys and magnesium-based metal matrix composites[J].Corrosion Science,1995,37(11):1763-1772.
【13】Hassan H Elsentriecy,Kazuhisa Azumi,Hidetaka Konno.Improvement in stannate chemical conversion coatings on AZ91 D magnesium alloy using the potentiostatic technique[J].Electrochimica Acta,2007,53(2):1006-1012.
【14】Hassan H Elsentriecy,Kazuhisa Azumi,Hidetaka Konno.Effects of pH and temperature on the deposition properties of stannate chemical conversion coatings formed by the potentiostatic technique on AZ91 D magnesium alloy[J].Electrochimica Acta,2008,53(12):4267-4275.
【15】崔秀芳,李庆芬.镁合金表面植酸转化膜研究Ⅱ:pH值对镁合金植酸转化膜的影响[J].腐蚀科学与防护技术,2007,19(4):275-277.
【16】张华云,李华伦,郭伊娜.镁合金化学转化膜的耐腐蚀性研究[J].材料保护,2007,40(1):10-13.
【17】Liu Jianrui,Guo Yina,Huang Weidong.Study on the corrosion resistance of phytic acid conversion coating for magnesium alloys[J].Surface and Coatings Technology,2006,201(3/4):1536-1541.
【18】Khramov A N,Balbyshev V N,Kasten L S,et al.Sol-gel coatings with phosphonate functionalities for surface modification of magnesium alloys[J].Thin Solid Films,2006,514(1/2):174-181.
【19】Zucchi F,Grassi V,Frignani A,et al.Influence of a silane treatment on the corrosion resistance of a WE43 magnesium alloy[J].Surface and Coatings Technology,2006,200(12/13):4136-4143.
【20】付蓉.金属铬酸盐化学转化处理的替代技术[J].汽车工艺与材料,2004(7):71-73.
【21】Toshihide Takenaka,Takami Ono,Yuji Narazaki,et al.Improvement of corrosion resistance of magnesium metal by rare earth elements[J].Electrochimica Acta,2007,53(1):117-121.
【22】Katya Brunelli,Manuele Dabalà,Irene Calliari,et al.Effect of HCl pre-treatment on corrosion resistance of cerium-based conversion coatings on magnesium and magnesium alloys[J].Corrosion Science,2005,47(4):989-1000.
【23】Manuele Dabalà,Katya Brunelli,Enrico Napolitani,et al.Cerium-based chemical conversion coating on AZ63 magnesium alloy[J].Surface and Coatings Technology,2003,172(2/3):227-232.
【24】Amy L Rudd,Carmel B Breslin,Florian Mansfeld.The corrosion protection afforded by rare earth conversion coatings applied to magnesium[J].Corrosion Science,2000,42(2):275-288.
【25】Lin J K,Hsia C L,Uan J Y.Characterization of Mg,Al-hydrotalcite conversion film on Mg alloy and Cl- and anion-exchangeability of the film in a corrosive environment[J].Scripta Materialia,2007,56(11):927-930.
【26】Yang K H,Ger M D,Hwu W H,et al.Study of vanadium-based chemical conversion coating on the corrosion resistance of magnesium alloy[J].Materials Chemistry and Physics,2007,101(2/3):480-485.
【27】Chiu K Y,Wong M H,Cheng F T,et al.Characterization and corrosion studies of fluoride conversion coating on degradable Mg implants[J].Surface and Coatings Technology,2007,202(3):590-598.
【28】Mclntyre N S,Chen C.Role of impurities on Mg surfaces under ambient exposure conditions[J].Corrosion Science,1998,40(10):1697-1709.
【29】贺慧彤.镁合金的环保型表面处理法[J].轻合金加工技术,2002,30(1):39-41.
【30】卫中领,沈钰,李春梅,等.SIMOXIDE镁合金无铬化学转化工艺[J].电镀与涂饰,2008,27(5):34-37.
【31】Tomlinson C E.Conversion coatings for metals using group IV-A metals in the presence of little or no fluoride and little or no chromium.US Pat,5952049.1999-09-14.
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