16MnR系列材料在油田H2S-CO2-Cl-环境下的耐蚀性
Corrosion Resistance of 16MnR Serial Materials in Oil Field Environment with H2S-CO2-Cl-
摘 要
通过应力腐蚀试验及全面腐蚀试验,系统地研究了16MnR系列压力容器用钢在油气田高含H2S-CO2-Cl-环境下的抗腐蚀性能,分析了16MnR系列钢在这种工况条件下作为压力容器用材的适用性.结果表明,16MnR(HIC)母材和焊接接头满足抗硫化物应力开裂(SSC)的基本要求,可以在pH值6以上、50 ℃以下的介质中任意H2S、CO2和Cl-含量下安全使用,其他16MnR材料对硫化物应力开裂(SSC)和氢诱导开裂(HIC)较敏感.在选材时还应在实际模拟工况条件下进行全浸腐蚀试验,以确定其腐蚀速率.
压力容器
H2S-CO2-Cl-腐蚀
选材
16MnR
pressure vessel
H2S-CO2-Cl- corrosion
material selection
Abstract
The corrosion characteristics and applicability of 16MnR series materials used to make pressure vessel in oil field environment with high concentration of H2S-CO2-Cl- were studied by means of stress corrosion test and general corrosion test.The results showed that 16MnR(HIC) and welded joint could resist the H2S stress corrosion under the condition of pH ＜ 6 and temperature ＜50 ℃,and other 16MnR materials were sensitive to SSC(sulfide stress cracking) and HIC(hydrogen induced cracking).Immersion test should be carried out in the environment of simulating practical working condition for material selection.
中图分类号 TG172
所属栏目 试验研究
基金项目
收稿日期 2010/1/10
修改稿日期 2010/3/30
网络出版日期
作者单位点击查看
引用该论文: GUO Zhi-jun,ZHOU Jian-jun,TAO Xiao-juan,WANG Ke-dong,XIE Shen. Corrosion Resistance of 16MnR Serial Materials in Oil Field Environment with H2S-CO2-Cl-[J]. Corrosion & Protection, 2010, 31(11): 863～867
被引情况:
【1】燕修良, "饱和H2S/CO2溶液中Cl-对2Cr13钢腐蚀行为的影响",腐蚀与防护 32, 892-895(2011)
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】巴玺立,孙铁民,何军,等.国内外气田地面工程技术研究进展[J].石油规划设计,2006,17(2):6-10.
【2】冯星安,黄柏宗,高光第.对四川罗家寨气田高含H2S、CO2腐蚀的分析及防腐设计初探[J].石油工程建设,2004,30(1):10-14.
【3】张蕴强.户部寨气田腐蚀分析及腐蚀防护[J].石油与天然气化工,2003,32(3):173-175.
【4】李循迹,张权,杜洪莲.牙哈凝析气田地面设备腐蚀检查及措施[J].石油矿场机械,2003,32(6):64-65.
【5】左兴凯.雅克拉凝析气田腐蚀状况与分析[J].石油钻探技术,2005,33(4):60-62.
【6】王维宗,贾鹏林,许适群.湿H2S环境中腐蚀失效实例及对策[J].石油化工腐蚀与防护,2001,18(2):7-13.
【7】李永健,吴学纲,谢申,等.异构化装置腐蚀原因分析及对策[J].石油化工设备,2007,36(5):98-101.
【8】Al-Anezi M A,Frankel G S,Agrawal A K.Investigation of the susceptibility of conventional ASTM A516-70 pressure vessel steel to HIC and SOHIC in H2S-containing DGA solutions[J].Corrosion,1999,55:1101-1109.
【9】NACE MR0175/ISO 15156-2001.Petroleum and natural gas industries-Materials for use in H2S-containing Environments in oil and gas production[S].
【10】HG 20581-1998.钢制化工容器材料选用规定[S].
【11】杜军毅,孙嫘,鞠庆红.冷高压分离器16MnR(HIC)抗氢钢超大型筒体研制[J].压力容器,2005,22(2):25-29.
【12】胡洋,李晓刚,李明,等.16Mn(HIC)钢在D405设备环境下的腐蚀行为研究[J].化工腐蚀与防护,2006,23(1):13-16.
【13】GB 6654-1996.压力容器用钢板[S].
【14】GB 3531-1996.低温压力容器用低合金钢板[S].
【15】WYJ 221-2007.抗H2S腐蚀用16MnR(HIC)/16MnR(R-HIC)钢板供货技术条件[S].舞阳钢铁公司.
【16】ASTM SA 516/SA 516M-2006.Standard specification for pressure vessel plates,carbon steel,for moderate-and-lower-temperature service[S].
【17】GB 5313-1985.厚度方向性能钢板[S].
【18】《油气田腐蚀与防护技术手册》编委会.油气田腐蚀与防护技术手册[M].北京:石油工业出版社,1999.
【19】NACE TM 0177-2005.Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in H2S environments[S].
【20】NACE MR0175/ISO 15156-2001.Petroleum and natural gas industries-materials for use in H2S-containing environments in Oil and gas production[S].
【21】NACE TM0284-2003.Evaluation of pipeline and pressure vessel steels for resistance to hydrogen-induced cracking[S].
【22】GB/T 15970.6-2007.金属和合金的腐蚀 应力腐蚀试验 第6部分:恒载荷或恒位移下的预裂纹试样的制备和应用[S].
【23】GB/T 15970.7－2000.金属和合金的腐蚀 应力腐蚀试验 第7部分:慢应变速率试验[S].
【24】ASTM G 31-72 (Reapproved 2004).Standard practice for laboratory immersion corrosion testing of metals[S].
【25】卢志明,童永光,方德明,等.16MnR钢在含H2S介质中慢拉伸应力腐蚀试验研究[J].化工机械,2001,28(3):138-140.
【26】严焱诚,陈大钧.油气井中CO2的腐蚀防护与综合利用[J].全面腐蚀控制,2003,17(6):22-24.
【27】刘生,王晓刚.夹杂物对16MnR(HIC)抗氢致裂纹的影响[J].宽厚板,1999,5(2):9-12.
【28】李明.湿硫化氢环境中16Mn(HIC)钢的腐蚀行为和机理研究[D].北京:北京科技大学博士论文,2007.
【29】EFC Publications No.16.Guidelineson materials requirements for carbonand low alloy steels for H2S-containing environmentsin oil and gas production[M].[s.l.]:[s.n.],1998.
【30】国家质量监督检验检疫总局.压力容器定期检验规则(TSG R7001-2004)[S].
【2】冯星安,黄柏宗,高光第.对四川罗家寨气田高含H2S、CO2腐蚀的分析及防腐设计初探[J].石油工程建设,2004,30(1):10-14.
【3】张蕴强.户部寨气田腐蚀分析及腐蚀防护[J].石油与天然气化工,2003,32(3):173-175.
【4】李循迹,张权,杜洪莲.牙哈凝析气田地面设备腐蚀检查及措施[J].石油矿场机械,2003,32(6):64-65.
【5】左兴凯.雅克拉凝析气田腐蚀状况与分析[J].石油钻探技术,2005,33(4):60-62.
【6】王维宗,贾鹏林,许适群.湿H2S环境中腐蚀失效实例及对策[J].石油化工腐蚀与防护,2001,18(2):7-13.
【7】李永健,吴学纲,谢申,等.异构化装置腐蚀原因分析及对策[J].石油化工设备,2007,36(5):98-101.
【8】Al-Anezi M A,Frankel G S,Agrawal A K.Investigation of the susceptibility of conventional ASTM A516-70 pressure vessel steel to HIC and SOHIC in H2S-containing DGA solutions[J].Corrosion,1999,55:1101-1109.
【9】NACE MR0175/ISO 15156-2001.Petroleum and natural gas industries-Materials for use in H2S-containing Environments in oil and gas production[S].
【10】HG 20581-1998.钢制化工容器材料选用规定[S].
【11】杜军毅,孙嫘,鞠庆红.冷高压分离器16MnR(HIC)抗氢钢超大型筒体研制[J].压力容器,2005,22(2):25-29.
【12】胡洋,李晓刚,李明,等.16Mn(HIC)钢在D405设备环境下的腐蚀行为研究[J].化工腐蚀与防护,2006,23(1):13-16.
【13】GB 6654-1996.压力容器用钢板[S].
【14】GB 3531-1996.低温压力容器用低合金钢板[S].
【15】WYJ 221-2007.抗H2S腐蚀用16MnR(HIC)/16MnR(R-HIC)钢板供货技术条件[S].舞阳钢铁公司.
【16】ASTM SA 516/SA 516M-2006.Standard specification for pressure vessel plates,carbon steel,for moderate-and-lower-temperature service[S].
【17】GB 5313-1985.厚度方向性能钢板[S].
【18】《油气田腐蚀与防护技术手册》编委会.油气田腐蚀与防护技术手册[M].北京:石油工业出版社,1999.
【19】NACE TM 0177-2005.Laboratory testing of metals for resistance to sulfide stress cracking and stress corrosion cracking in H2S environments[S].
【20】NACE MR0175/ISO 15156-2001.Petroleum and natural gas industries-materials for use in H2S-containing environments in Oil and gas production[S].
【21】NACE TM0284-2003.Evaluation of pipeline and pressure vessel steels for resistance to hydrogen-induced cracking[S].
【22】GB/T 15970.6-2007.金属和合金的腐蚀 应力腐蚀试验 第6部分:恒载荷或恒位移下的预裂纹试样的制备和应用[S].
【23】GB/T 15970.7－2000.金属和合金的腐蚀 应力腐蚀试验 第7部分:慢应变速率试验[S].
【24】ASTM G 31-72 (Reapproved 2004).Standard practice for laboratory immersion corrosion testing of metals[S].
【25】卢志明,童永光,方德明,等.16MnR钢在含H2S介质中慢拉伸应力腐蚀试验研究[J].化工机械,2001,28(3):138-140.
【26】严焱诚,陈大钧.油气井中CO2的腐蚀防护与综合利用[J].全面腐蚀控制,2003,17(6):22-24.
【27】刘生,王晓刚.夹杂物对16MnR(HIC)抗氢致裂纹的影响[J].宽厚板,1999,5(2):9-12.
【28】李明.湿硫化氢环境中16Mn(HIC)钢的腐蚀行为和机理研究[D].北京:北京科技大学博士论文,2007.
【29】EFC Publications No.16.Guidelineson materials requirements for carbonand low alloy steels for H2S-containing environmentsin oil and gas production[M].[s.l.]:[s.n.],1998.
【30】国家质量监督检验检疫总局.压力容器定期检验规则(TSG R7001-2004)[S].
相关信息
