Effects of Ce,La and Ce-rich MM on Microstructure and Mechanical Properties of AZ91D Alloy
摘 要
用SEM、XRD和EDS分析了添加0.5%,1.0%,1.5%铈、镧和富铈稀土的AZ91D合金的微观组织形貌和相组成:并测试了各合金的硬度以及不同温度下的拉伸性能.结果表明:铈、镧和富铈稀土的添加均能细化AZ91D合金α相,降低β相含量,同时形成针杆状Al11RE3化合物.添加同一稀土元素的合金中,当稀土含量为1.0%时,其常温和高温抗拉强度达到最大值.对比相同含量不同元素的作用,低含量时含铈合金抗拉强度较好,高含量时含镧合金常温和高温断后伸长率较高:铈、富铈混合稀土、镧提高合金硬度的作用依次减弱.
Abstract
Effects of adding 0.5%,1.0%,1.5%Ce,La and Ce-rich MM to AZ91D alloy were studied.The microstructure and components of these alloys were investigated by scanning electron microscopy (SEM),energy dispersion spectrum (EDS) and X-ray diffraction (XRD).The hardness and tensile mechanical properties of room temperature and elevated temperature were also tested.The results indicates that either of Ce,La and Ce-rich MM can reduce the α-phase grain size,reduce the β-phase content and form needle-like Al11RE3 phase.When addition content is 1.0%,the room temperature and elevated temperature tensile strength of alloy arrived at maximum.Compare the alloys with different element but the same addition amount:the tensile strength of alloy with Ce is higher in low addition amounts condition;the elongation of alloy with La is greater in high addition amounts condition;the rigidity of Ce addition alloy is the highest,the rigidity of La addition alloy is the lowest.
中图分类号 TG146.2
所属栏目
基金项目 航空科学基金资助项目(03G52047)
收稿日期 2007/2/11
修改稿日期 2007/5/28
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备注陈可(1980-),女,湖南衡阳人,博士研究生.
引用该论文: CHEN Ke,LI Zi-quan,YANG Bao-liang. Effects of Ce,La and Ce-rich MM on Microstructure and Mechanical Properties of AZ91D Alloy[J]. Materials for mechancial engineering, 2007, 31(11): 47~51
陈可,李子全,杨宝亮. 铈、镧及富铈混合稀土对AZ91D合金组织和力学性能的影响[J]. 机械工程材料, 2007, 31(11): 47~51
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参考文献
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【11】Ifeanyi A,Anyanwua.Effect of substituting cerium-rich mischmetal with lanthanum on high temperature properties of die-cast Mg-Zn-Al-Ca-RE alloys[J].Materials Science and Engineering A,2004(380):93-99.
【2】师昌绪,李恒德.加速我国金属镁工业发展的建议[J].材料导报,1994,10(1):1-16.
【3】Luo A,Pekguleryuz M O.Cast magnesium alloys for elevated temperature applications[J].J Mater Sci,1994(29):5259-5271.
【4】Lu Yizhen,Wang Qudong,Zeng Xiaoqin,et al.Effects of rare earths on the microstructure,properties and fracture behavior of Mg-Al alloys[J].Materials Science and Engineering A,2000(278):66-76.
【5】王立世,段汉桥,魏伯康,等.混合稀土对AZ91镁合金组织和性能的影响[J].东南大学学报(自然科学版),2002(3):12-14.
【6】张诗昌,魏伯康,陈渭臣.钇及混合稀土对AZ91镁合金流动性与凝固组织的影响[J].铸造,2004(12):118-121.
【7】杨宝亮,陈可,李子全.电磁搅拌对富Ce混合稀土合金化AZ91D组织结构的影响[J].材料开发与应用,2006,21(1):4-8.
【8】Von Buch F,Lietzau J,Mordike B L,et al.Development of Mg-Sc-Mn alloys[J].Materials Science and Engineering A,1999,263(1):1-7.
【9】黄正华,郭学锋,张忠明,等.铈对铸造镁合金AZ91D显微组织与力学性能的影响[J].稀有金属,2004,28(4):683-686.
【10】刘生发,黄尚宇,徐萍.Ce对AZ91镁合金铸态组织细化的影响[J].金属学报,2006,42(4):443-448.
【11】Ifeanyi A,Anyanwua.Effect of substituting cerium-rich mischmetal with lanthanum on high temperature properties of die-cast Mg-Zn-Al-Ca-RE alloys[J].Materials Science and Engineering A,2004(380):93-99.
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