Preparation and Mechanical Properties of Wheat Straw Fiber/Polypropylene Composites
摘 要
采用热磨提取法提取麦秸纤维,研究了硅烷偶联剂种类、麦秸纤维含量以及相容剂MAPP含量对麦秸纤维与废旧聚丙烯间的界面相容性以及制备的复合材料力学性能的影响;用扫描电镜和三维体视显微镜观察了麦秸纤维的分散性以及复合材料冲击断口形貌.结果表明:经3% KH550处理后,麦秸纤维与废旧聚丙烯间的相容性得到明显改善,提高了复合材料的力学性能;当麦秸纤维质量分数为20%左右时,其在废旧聚丙烯基体中分散均匀,增强效果最佳;且当MAPP质量分数为8%左右时,材料的抗拉、抗弯以及抗冲击强度均达到最大值,分别为61.14 MPa、68.25 MPa和11.25 kJ·m-2.
Abstract
Effects of the kinds of coupling agent,amount of wheat straw fibers obtained by thermal-mechanical extraction and compatibilizer MAPP on the interfacial compatibility between wheat straw fibers and waste polypropylene as well as the mechanical properties of the composites were studied.Dispersion of wheat straw fibers and surface morphology of impact fracture were observed by SEM and stereo-microscope.The results showed that after wheat straw fibers treated by 3% KH550,the mechanical properties of composites were significantly improved because of the good interfacial adhesion.When the amount of wheat strow fibers was about 20wt%,they dispersed evenly in waste polypropylene and the reinforced effect was the best.Tensile strength,flexile strength and impact strength of the composites with 8wt% MAPP were maximum,which were 61.14 MPa,68.25MPa and 1125 kJ·m-2 respectively.
中图分类号 TB332
所属栏目 新材料 新工艺
基金项目
收稿日期 2007/10/5
修改稿日期 2008/1/10
网络出版日期
作者单位点击查看
备注孟召辉(1982-),女,天津人,硕士研究生.
引用该论文: MENG Zhao-hui,YAO Zheng-jun,LIANG En-quan,ZHOU Jin-tang. Preparation and Mechanical Properties of Wheat Straw Fiber/Polypropylene Composites[J]. Materials for mechancial engineering, 2008, 32(10): 35~39
孟召辉,姚正军,梁恩泉,周金堂. 麦秸纤维/聚丙烯复合材料的制备与力学性能[J]. 机械工程材料, 2008, 32(10): 35~39
被引情况:
【1】梁恩泉,姚正军,周娟娟,周金堂, "Al(OH)3阻燃剂含量对麦秸纤维/废旧聚丙烯再生复合材料性能的影响",机械工程材料 34, 56-59(2010)
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参考文献
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【2】Panthapulakkal S,Zereshkian A,Sain M.Preparation and characterization of wheat straw fibers for reinforcing application in injection molded thermoplastic composites[J].Bioresource Technology,2006,97(2):265-272.
【3】Suhara Panthapulakkal,Mohini Sain.Injection molded wheat straw and corn stem filled polypropylene composites[J].Journal of Polymers and the Environment,2006,14(3):265-272.典平鸽,杜玲枝.废旧塑料的综合利用[J].浙江化工,2006,37(3):28-32.
【4】赵正湘.废塑料物品是值得开发利用的再生资源[J].中国资源综合利用,2006,24(2):36-38.
【5】吴自强,唐四丁,胡海.废旧聚丙烯回收利用技术的现状及发展趋势[J].再生资源研究,2002(1):25-27.
【6】李本贵.植物纤维与热塑性塑料复合界面相容性研究[J].企业技术开发,2006,25(1):24-26.
【7】郑玉涛,陈就记,曹德榕.改进植物纤维/热塑性塑料复合材料界面相容性的技术进展[J].纤维素科学与技术,2005,13(1):45-55.
【8】吴章康,周定国.稻草原料表面特性FTIR和XPS分析[J].木材工业,2003,17(6):6-8.
【9】鲁博,张林文,曾竟成.天然纤维复合材料[M].北京:化学工业出版社,2005.
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