烧结钕-铁-硼永磁材料的研究进展
Research Progress of Sintered Nb-Fe-B Permanent Magnets
摘 要
钕-铁-硼磁体被称为第三代稀土永磁材料,烧结钕-铁-硼磁体是目前综合磁性能最高的永磁材料.介绍了烧结钕-铁-硼磁体的研究现状、应用领域,阐述了烧结钕-铁-硼磁体的有关理论及先进生产工艺的特点,重点分析了低氧湿压、片铸、放电等离子烧结等工艺的特点,指出了目前国内烧结钕-铁-硼磁体存在的主要问题及今后的研究方向.
钕-铁-硼永磁材料
磁性能
制备工艺
sintering
Nd-Fe-B permanent magnet material
magnetic property
preparation technology
Abstract
As the third generation of rare earth permanent magnet material,the sintered Nd-Fe-B magnets possess the best integrated magnetic properties by now.Research status and application fields of the sintered Nd-Fe-B magnets were reviewed.Related theories about Nd-Fe-B permanent alloy and advanced production technologies of the sintered Nd-Fe-B magnets were introduced,and the technical characteristics of HILOP(Hitach low oxygen process),SC(strip casting),SPS(spark plasma sintering) etc were emphasized.The present existing problems and future research interests in our country were pointed out.
中图分类号 TM273
所属栏目 综述
基金项目 国家自然科学基金资助项目(50074014);湖北省自然科学基金资助项目(2003ABA092)
收稿日期 2007/11/15
修改稿日期 2008/3/29
网络出版日期
作者单位点击查看
备注张修海(1978-),男,河南南阳人,博士研究生.
引用该论文: ZHANG Xiu-hai,XIONG Wei-hao,LI Yan-fang,SONG Ni. Research Progress of Sintered Nb-Fe-B Permanent Magnets[J]. Materials for mechancial engineering, 2008, 32(11): 5～9
张修海,熊惟皓,李燕芳,宋妮. 烧结钕-铁-硼永磁材料的研究进展[J]. 机械工程材料, 2008, 32(11): 5～9
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参考文献
【1】Gabay A M,Zhang Y,Hadjipanayis G C.Effect of very small additions on the coercivity of Dy-free Nd-Fe-(Co)-B sintered magnets[J].Journal of Magnetism and Magnetic Materials,2002,238:226-232.
【2】Brown David,Ma Bao-Min,Chen Zhongmin.Developments in the processing and properties of NdFeB-type permanent magnets[J].Journal of Magnetism and Magnetic Materials,2002,248:432-440.
【3】Yutaka Matsuura.Recent development of Nd-Fe-B sintered magnets and their applications[J].Journal of Magnetism and Magnetic Materials,2006,303:344-347.
【4】周寿增.超强永磁体-稀土铁系永磁材料[M].北京:冶金工业出版社,2004.
【5】Yuji Kaneko.Highest performance of Nd-Fe-B magnet over 55 MGOe[J].IEEE Transactions on Magnetics,2000,36:3275-3278.
【6】Yuji Kaneko,Futoshi Kuniyoshi,Naoyuki Ishigaki.Proven technologies on high-performance Nd-Fe-B sintered magnets[J].Journal of Alloys and Compounds,2006,408/412:1344-1349.
【7】杨仕清,王豪才,张万里,等.纳米晶交换耦合稀土永磁α-Fe/NdFeB的居里温度及磁性能随温度变化关系研究[J].原子与分子物理学报,1999,16(1):111-115.
【8】姜寿亭.铁磁性理论[M].北京:科学出版社,1993.
【9】何叶青,熊科.具有高综合永磁性能的烧结Nd-Fe-B磁体[J].磁性材料及器件,2000,31(4):1-3.
【10】Liu Z W,Davies H A.The practical limits for enchancing magnetic property combinations for bulk nanocrystalline NdFeB alloys through Pr,Co,and Dy substitutions[J].Journal of Magnetism and Magnetic Materials,2007,313:337-341.
【11】Bai G,Gao R W,Sun Y,et al.Study of high-coercivity sintered NdFeB magnets[J].Journal of Magnetism and Magnetic Materials,2007,308:20-23.
【12】Vial F,Joly F,Nevalainen E,et al.Impro- vement of coercivity of sintered NdFeB permanent magnets by heat treatment[J].Journal of Magnetism and Magnetic Materials,2002,242/245:1329-1334.
【13】顾正飞,刘正义,罗承萍,等.烧结Nd-Fe-B稀土永磁合金的界面结构与矫顽力[J].电工合金,1999(3):7-17.
【14】高汝伟,王标,刘汉强,等.高性能烧结钕铁硼磁体的研究与开发(一)[J].磁性材料及器件,2004(12):1-5.
【15】高汝伟,王标,刘汉强,等.高性能烧结钕铁硼磁体的研究与开发(二)[J].磁性材料及器件,2005(2):1-5.
【16】姚云甫,姚燕.橡皮模等静压取向磁场的改进[J].磁性材料及器件,2006(2):46-47.
【17】罗阳,陈虞才.新技术、新设备在NdFeB稀土磁体生产中的应用之三——磁场取向成形技术和设备[J].磁性材料及器件,2007(2):1-6.
【18】Zhu Minggang,Fang Yikun,Guo Yongquan,et al.Study of magnetic microstructures of Nd-Fe-B casting strips by using magnetic force microscope[J].Journal of Magnetism and Magnetic Materials,2004,282:180-185.
【19】Liu H Q,Wang B,Han G B,et al.Grain alignment and microstructure of (Nd,Dy)12.8(Fe,M)80.7B6.5 by strip casting[J].Journal of Magnetism and Magnetic Materials,2005,285:23-27.
【20】Li Chengdong,Zhu Xuexin,Shi Likai.Microstructural characterization of novel Ni-containing Nd-Fe-B strips by strip casting[J].Journal of Rare Earth,2006,24:85-88.
【21】Turek K,Liszkowshi P,Figiel H.The influence of the kinetics of the hydrogenation of Nd-Fe-B alloys on hydrogen distribution in the alloy phases[J].Journal of Alloys and Compounds,2000,309:239-243.
【22】罗阳,陈虞才.新技术、新设备在NdFeB稀土磁体生产中的应用之二——合金的氢爆及气流磨粉碎[J].磁性材料及器件,2006(12):1-7.
【23】Wang H J,Li A H,Zhu M G,et al.Sintered Nd-Fe-B magnets with improved impact stability[J].Journal of Magnetism and Magnetic materials,2006,307:268-272.
【24】樊东黎.真空热处理的发展和展望[J].机械工人(热加工),2002(4):1-4.
【25】阎承沛.真空热处理技术的新近进展及其发展趋势[J].热处理,2006(2):7-13.
【26】Mo Wenjian,Zhang Lanting,Shan Aidang,et al.Microstructure and magnetic properties of NdFeB magnet prepared by spark plasma sintering[J].Intermetallics,2007,15:1483-1488.
【27】张久兴,刘科高,周美玲.放电等离子烧结技术的发展和应用[J].粉末冶金技术,2002,20(3):129-134.
【28】Ono Hideaki,Shimada,Munekatsu.Magnetic properties on bulk exchange-spring magnets in Nd-Fe-Co-V-B system formed by Spark Plasma Sintering[J].Journal of the Japan Society of Power and Powder Metallurgy,2000,47(6):667-673.
【29】谭春林,包大新,严密.高工作温度烧结钕铁硼磁体的研究现状[J].材料导报,2005(4):97-102.
【30】Zheng Jingwu,Jiang Liqiang,Chen Qiaoling.Electrochemical corrosion bebavior of Nd-Fe-B sintered magnets in different acid solutions[J].Journal of Rare Earth,2006,24:218-224.
【31】谢发勤,郜涛.NdFeB永磁合金电化学腐蚀行为研究[J].腐蚀与防护,2001,22(9):381-383.
【32】谢发勤,关丽.NdFeB合金表面激光非晶化的改性技术[J].材料导报,2003,17(3):16-19.
【33】吴向清,谢发勤,张能,等.NdFeB合金表面激光熔凝层的组织和耐腐性能研究[J].兰州理工大学学报,2005,31(5):29-31.
【34】张然,刘颖,马毅龙,等.纳米晶复合NdFeB永磁材料的研究进展[J].电子元件与材料,2007,26(6):8-12.
【2】Brown David,Ma Bao-Min,Chen Zhongmin.Developments in the processing and properties of NdFeB-type permanent magnets[J].Journal of Magnetism and Magnetic Materials,2002,248:432-440.
【3】Yutaka Matsuura.Recent development of Nd-Fe-B sintered magnets and their applications[J].Journal of Magnetism and Magnetic Materials,2006,303:344-347.
【4】周寿增.超强永磁体-稀土铁系永磁材料[M].北京:冶金工业出版社,2004.
【5】Yuji Kaneko.Highest performance of Nd-Fe-B magnet over 55 MGOe[J].IEEE Transactions on Magnetics,2000,36:3275-3278.
【6】Yuji Kaneko,Futoshi Kuniyoshi,Naoyuki Ishigaki.Proven technologies on high-performance Nd-Fe-B sintered magnets[J].Journal of Alloys and Compounds,2006,408/412:1344-1349.
【7】杨仕清,王豪才,张万里,等.纳米晶交换耦合稀土永磁α-Fe/NdFeB的居里温度及磁性能随温度变化关系研究[J].原子与分子物理学报,1999,16(1):111-115.
【8】姜寿亭.铁磁性理论[M].北京:科学出版社,1993.
【9】何叶青,熊科.具有高综合永磁性能的烧结Nd-Fe-B磁体[J].磁性材料及器件,2000,31(4):1-3.
【10】Liu Z W,Davies H A.The practical limits for enchancing magnetic property combinations for bulk nanocrystalline NdFeB alloys through Pr,Co,and Dy substitutions[J].Journal of Magnetism and Magnetic Materials,2007,313:337-341.
【11】Bai G,Gao R W,Sun Y,et al.Study of high-coercivity sintered NdFeB magnets[J].Journal of Magnetism and Magnetic Materials,2007,308:20-23.
【12】Vial F,Joly F,Nevalainen E,et al.Impro- vement of coercivity of sintered NdFeB permanent magnets by heat treatment[J].Journal of Magnetism and Magnetic Materials,2002,242/245:1329-1334.
【13】顾正飞,刘正义,罗承萍,等.烧结Nd-Fe-B稀土永磁合金的界面结构与矫顽力[J].电工合金,1999(3):7-17.
【14】高汝伟,王标,刘汉强,等.高性能烧结钕铁硼磁体的研究与开发(一)[J].磁性材料及器件,2004(12):1-5.
【15】高汝伟,王标,刘汉强,等.高性能烧结钕铁硼磁体的研究与开发(二)[J].磁性材料及器件,2005(2):1-5.
【16】姚云甫,姚燕.橡皮模等静压取向磁场的改进[J].磁性材料及器件,2006(2):46-47.
【17】罗阳,陈虞才.新技术、新设备在NdFeB稀土磁体生产中的应用之三——磁场取向成形技术和设备[J].磁性材料及器件,2007(2):1-6.
【18】Zhu Minggang,Fang Yikun,Guo Yongquan,et al.Study of magnetic microstructures of Nd-Fe-B casting strips by using magnetic force microscope[J].Journal of Magnetism and Magnetic Materials,2004,282:180-185.
【19】Liu H Q,Wang B,Han G B,et al.Grain alignment and microstructure of (Nd,Dy)12.8(Fe,M)80.7B6.5 by strip casting[J].Journal of Magnetism and Magnetic Materials,2005,285:23-27.
【20】Li Chengdong,Zhu Xuexin,Shi Likai.Microstructural characterization of novel Ni-containing Nd-Fe-B strips by strip casting[J].Journal of Rare Earth,2006,24:85-88.
【21】Turek K,Liszkowshi P,Figiel H.The influence of the kinetics of the hydrogenation of Nd-Fe-B alloys on hydrogen distribution in the alloy phases[J].Journal of Alloys and Compounds,2000,309:239-243.
【22】罗阳,陈虞才.新技术、新设备在NdFeB稀土磁体生产中的应用之二——合金的氢爆及气流磨粉碎[J].磁性材料及器件,2006(12):1-7.
【23】Wang H J,Li A H,Zhu M G,et al.Sintered Nd-Fe-B magnets with improved impact stability[J].Journal of Magnetism and Magnetic materials,2006,307:268-272.
【24】樊东黎.真空热处理的发展和展望[J].机械工人(热加工),2002(4):1-4.
【25】阎承沛.真空热处理技术的新近进展及其发展趋势[J].热处理,2006(2):7-13.
【26】Mo Wenjian,Zhang Lanting,Shan Aidang,et al.Microstructure and magnetic properties of NdFeB magnet prepared by spark plasma sintering[J].Intermetallics,2007,15:1483-1488.
【27】张久兴,刘科高,周美玲.放电等离子烧结技术的发展和应用[J].粉末冶金技术,2002,20(3):129-134.
【28】Ono Hideaki,Shimada,Munekatsu.Magnetic properties on bulk exchange-spring magnets in Nd-Fe-Co-V-B system formed by Spark Plasma Sintering[J].Journal of the Japan Society of Power and Powder Metallurgy,2000,47(6):667-673.
【29】谭春林,包大新,严密.高工作温度烧结钕铁硼磁体的研究现状[J].材料导报,2005(4):97-102.
【30】Zheng Jingwu,Jiang Liqiang,Chen Qiaoling.Electrochemical corrosion bebavior of Nd-Fe-B sintered magnets in different acid solutions[J].Journal of Rare Earth,2006,24:218-224.
【31】谢发勤,郜涛.NdFeB永磁合金电化学腐蚀行为研究[J].腐蚀与防护,2001,22(9):381-383.
【32】谢发勤,关丽.NdFeB合金表面激光非晶化的改性技术[J].材料导报,2003,17(3):16-19.
【33】吴向清,谢发勤,张能,等.NdFeB合金表面激光熔凝层的组织和耐腐性能研究[J].兰州理工大学学报,2005,31(5):29-31.
【34】张然,刘颖,马毅龙,等.纳米晶复合NdFeB永磁材料的研究进展[J].电子元件与材料,2007,26(6):8-12.
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