Comparison of Tribological Properties of Manganese Phosphate Conversion Coating and Ferrous Sulfide Coating
摘 要
为了在重载蜗杆传动中以钢蜗轮替代青铜蜗轮,在20Cr钢表面分别制备了超微细磷酸锰转化涂层和硫化亚铁涂层,在摩擦磨损试验机上对两种涂层的摩擦学性能进行了对比;用SEM和EDX分析了涂层表面、磨损面的形貌与成分,采用XRD分析了涂层的相结构.结果表明:在载荷低于300 N时,两种涂层均具有良好的减摩耐磨性能;当载荷大于500 N时,硫化亚铁涂层的减摩耐磨效果不明显,而超微细磷酸锰转化涂层具有持续的减摩耐磨特性.
Abstract
To achieve the target of replacing bronze to steel in worm transmission,superfine manganese phosphate conversion coating and ferrous sulfide coating were prepared on the surface of 20Cr steel.The tribological properties of the coatings were compared using a friction and wear tester.SEM and EDX were adopted to analyze the morphology and compositions of the original and worn surfaces of the coatings.The phase structure of the coating was studies by XRD.The results show that two coatings had good antifriction and antiwear performance under the load less than 300 N.When the load was larger than 500 N,superfine manganese phosphate coating had good ability of antifriction and antiwear,and performance of the ferrous sulfide coating was low.
中图分类号 TG156.8
所属栏目 材料性能及其应用
基金项目 国家自然科学基金资助项目(50575234)
收稿日期 2008/7/17
修改稿日期 2009/5/25
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备注石万凯(1968-),男,重庆人,副教授,博士.
引用该论文: SHI Wan-kai,JIANG Hong-wei,QIN Da-tong,CHEN Yong. Comparison of Tribological Properties of Manganese Phosphate Conversion Coating and Ferrous Sulfide Coating[J]. Materials for mechancial engineering, 2009, 33(11): 82~85
石万凯,姜宏伟,秦大同,陈勇. 磷酸锰转化涂层和硫化亚铁涂层的摩擦学性能对比[J]. 机械工程材料, 2009, 33(11): 82~85
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参考文献
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【2】KHALEGHI M,GADE D R,RICHARDSON M W.Characteristics of manganese phosphate coatings for wear-resistance applications[J].Wear,1979,55(2):277-287.
【3】HIVART P,HAUW J,CRAMPON J,et al.Annealing improvement of tribological properties of manganese phosphate coatings[J].Wear,1998,219(2):195-204.
【4】WENG D,JOKIEL P,UEBLEIS A,et al.Corrosion and protection characteristics of zinc and manganese phosphate coatings[J].Surface & Coatings Technology,1996,88(1/3):147-156.
【5】TOTIK Y.The corrosion behaviour of manganese phosphate coatings applied to AISI 4140 steel subjected to different heat treatments[J].Surface & Coatings Technology,2006,200(5):2711-2717.
【6】朱丽娜,李国禄,王海斗,等.硫化亚铁固体润滑涂层的制备方法与摩擦学性能研究[J].润滑与密封,2007,32(1):181-184.
【7】ZHUANG D M,LIU Y R,LIU J J,et al.Microstructure and tribological properties of sulphide coating produced by ion sulphuration[J].Wear,1999,225/229:799-805.
【8】KOBAYASHI N,MORIYAMA A,YOSHIDA M.Electrolytic phosphating process for the steel wire drawing[J].Nihon Parkerizing Technical Report,2005,17:3-9.
【9】BARROS M I,BOUCHET J,RAOULT I,et al.Friction reduction by metal sulfides in boundary lubrication studied by XPS and XANES analyses[J].Wear,2003,254:863-870.
【10】王海斗,庄大明,王昆林,等.几种钢表面离子渗硫层在油润滑条件下的摩擦磨损性能研究[J].摩擦学学报,2002,22(6):439-443.
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