钢的碳分配热处理工艺与热力学研究现状
Research Status of Heat Treatment Process and Thermodynamics of Carbon Partitioning of Steels
摘 要
综述了淬火-碳分配(Q-P)及淬火-碳分配-回火(Q-P-T)工艺;介绍了在线热处理(HOP)碳分配工艺在抗大变形管线钢生产中的应用;阐述了碳分配的限制条件碳准平衡态热力学的主要研究成果,并与正平衡态热力学进行了比较;并指出了现有理论研究存在的不足,对碳分配工艺与机理研究的新方向进行了展望.
淬火
奥氏体
马氏体
carbon partitioning
quenching
austenite
martensite
Abstract
The quenching partitioning (Q-P) and the quenching partitioning tempering (Q-P-T) processes are summarized.The application of the carbon partitioning process with heat treatment on-line process (HOP) to high deformability pipeline steels is introduced.Thermodynamics of the constrained carbon paraequilibrium (CCE) of the carbon partitioning is expounded and compared with that of the orthoequilibrium.The deficiencies of the existing theoretical research are pointed out,and the new research directions about the process and the mechanism of carbon partitioning are looked forward.
中图分类号 TG156.1
所属栏目 综述
基金项目 “十一五”国家科技支撑计划资助项目(2006BAE03A06);国家青年科学基金资助项目(50804005)
收稿日期 2009/9/1
修改稿日期 2010/6/28
网络出版日期
作者单位点击查看
备注王立军(1981-),男,安徽六安人,博士研究生.
引用该论文: WANG Li-jun,CAI Qing-wu,YU Wei,WU Hui-bin. Research Status of Heat Treatment Process and Thermodynamics of Carbon Partitioning of Steels[J]. Materials for mechancial engineering, 2010, 34(10): 1～4
王立军,蔡庆伍,余伟,武会宾. 钢的碳分配热处理工艺与热力学研究现状[J]. 机械工程材料, 2010, 34(10): 1～4
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参考文献
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【25】ZHONG N,WANG X D,RONG Y H,et al.Interface migration between martenstie and austenite during quenching and partitioning(Q&P) process[J].J Mater Sci Technol,2006,22:751-754.
【26】SPEER J G,HACKENBERG R E,DECOOMAN B C,et al.Influence of interface migration during annealing of martensite / austenite mixtures[J].Phil Mag Lett,2007,87:379-382.
【27】徐祖耀.贝氏体相变简介[J].热处理,2006,21(2):1-20.
【2】YAKUBTSOV I A,PORUKS P,BOYD J D.Microstructure and mechanical properties of bainitic low carbon high strength plate steels[J].Mater Sci Eng A,2008,481:109-116.
【3】康沫狂,朱明,陈大明,等.硅合金钢淬火组织中残留奥氏体的力学稳定性与力学性能[J].金属热处理,2005,30(1):14-19.
【4】SCOTT C P,DRILLET J.A study of the carbon distribution in retained austenite[J].Scripta Mater,2007,56:489-492.
【5】YASO M,MORITO S,OHBA T,et al.Microstructure of martensite in Fe-C-Cr steel[J].Mater Sci Eng A,2008,481/482:770-773.
【6】徐祖耀.马氏体相变与马氏体[M].北京:科学出版社,1999:84-89,63.
【7】SPEER J G,MATLOCK D K,DECOOMAN B C,et al.Carbon partitioning into austenite after martensite transformation[J].Acta Mater,2003,51:2611-2622.
【8】SPEER J G,EDMONDS D V,RIZZO F C,et al.Partitioning of carbon from supersaturated plates of ferrite,with application to steel processing and fundamentals of the bainite transformation[J].Current Opinion in Solid State and Mater Sci,2004,8:219-237.
【9】MATLOCK D K,BRAUTIGAM V E,SPEER J G.Application of the quenching and partitioning (Q&P) process to a medium-carbon high Si microalloyed bar steel[J].Mater Sci Forum,2003,426/432:1089-1094.
【10】徐祖耀.用于超高强度钢的淬火-碳分配-回火(沉淀) ( Q-P-T)工艺[J].热处理,2008,23(2):1-5.
【11】徐祖耀.淬火-碳分配-回火( Q-P-T)工艺浅介[J].金属热处理,2009,34(6):1-8.
【12】徐祖耀.钢热处理的新工艺[J].热处理,2007,22(1):1-11.
【13】EDMONDS D V,HE K,RIZZO F C,et al.Quenching and partitioning martensite-A novel steel heat treatment[J].Mater Sci Eng A,2006,438/440:25-34.
【14】GERDEMANN F L H.Microstructure and hardness of 9260 steel heat-treated by the quenching and partitioning process[D].Aachen :Aachen University of Technology,2004.
【15】MOOR E D,LACROIX S,Clarke A J,et al.Effect of retained austenite stabilized via quench and partitioning on the strain hardening of martensitic steels[J].Metallurgical and Materials Transactions A,2008,39:2586-2595.
【16】SEUNG C H,JAE C A,SAUG Y N,et al.Mechanical properties of high-Si plate steel produced by the quenching-partitioning process[J].Metals and Materials Inter,2007,13(6):439-445.
【17】NAYAK S S,ANUMOLU R,MISRA R D K,et al.Microstructure-hardness relationship in quenched and partitioned medium-carbon and high-carbon steels containing silicon[J].Mater Sci Eng A,2008,498:442-456.
【18】HILLERT M,AGREN J.‘Reply to Comments on “On the definition of paraequilibrium and orthoequilibrium” by J.G.Speer et al[J].Scripta Mater,2005,52:87-88.
【19】郑磊,傅俊岩.高等级管线钢的发展现状钢铁[J].钢铁,2006,41(10):1-10.
【20】郝士明.材料热力学[M].北京:化学工业出版社,2004:317-320.
【21】HILLERT M,AGREN J.On the definitions of paraequilibrium and orthoequilibrium[J].Scripta Mater,2004,50:697-699.
【22】SPEER J G,MATLOCK D K,DECOOMAN B C,et al.Comments on “On the definitions of paraequilibrium and orthoequilibrium” by M.Hillert and J.Agren[J].Scripta Mater,2005,52:83-85.
【23】LOBO J A,GEIGER G H.Thermodynamics and solubility of carbon in ferrite and ferritic Fe-Mo alloys[J].Metall Trans A,1976,7:1347-1357.
【24】LOBO J A,GEIGER G H.Thermodynamics of carbon in austenite and Fe-Mo austenite[J].Metall Trans A,1976,7:1359-1364.
【25】ZHONG N,WANG X D,RONG Y H,et al.Interface migration between martenstie and austenite during quenching and partitioning(Q&P) process[J].J Mater Sci Technol,2006,22:751-754.
【26】SPEER J G,HACKENBERG R E,DECOOMAN B C,et al.Influence of interface migration during annealing of martensite / austenite mixtures[J].Phil Mag Lett,2007,87:379-382.
【27】徐祖耀.贝氏体相变简介[J].热处理,2006,21(2):1-20.
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