Eu3+:SnO2微晶玻璃的显微结构与光致发光性能
Microstructure and Photoluminescent Properties of Eu3+:SnO2 Glass Ceramics
摘 要
采用溶胶-凝胶法制备了Eu3+:SnO2微晶玻璃, 研究了它的显微结构和光致发光性能。结果表明: 干凝胶在高于400 ℃热处理后可得到含金红石结构SnO2纳米晶的微晶玻璃; 随着热处理温度升高, SnO2的特征峰出现了红移; 在280 nm紫外光激发下, 800 ℃热处理得到的微晶玻璃的发射光谱中出现了Stack分裂, 表明Eu3+进入到SnO2晶体中。
微晶玻璃
光致发光性能
铕离子
SnO2
glass ceramics
photoluminescent property
Eu3+
Abstract
Eu3+:SnO2 glass ceramics was prepared by sol-gel method, and its microstructure and photoluminescent properties were studied. The results show that the glass ceramics with rutile SnO2 nano-crystals were obtained after dry gel was heat-treated at over 400 ℃. The characteristics peak of SnO2 nano-crystals showed red-shift with the increase of heat treatment temperature. Stack split appeared in the emission spectrum of the glass ceramics obtained at 800 ℃ when it was excited by UV-light with wavelength of 280 nm, this indicated that Eu3+ entered into the SnO2 crystal.
中图分类号 TB321 TB35 DOI 10.11973/jxgccl201509014
所属栏目 材料性能及其应用
基金项目 福建省教育厅基金资助项目(JA14223); 福建工程学院科研启动项目(GY-Z15008)
收稿日期 2014/2/10
修改稿日期 2014/3/20
网络出版日期
作者单位点击查看
备注李巍(1981-), 男, 福建连城人, 副教授, 博士。
引用该论文: LI Wei,CHEN Wen-zhe,ZHENG Chan. Microstructure and Photoluminescent Properties of Eu3+:SnO2 Glass Ceramics[J]. Materials for mechancial engineering, 2015, 39(9): 60～63
李巍,陈文哲,郑婵. Eu3+:SnO2微晶玻璃的显微结构与光致发光性能[J]. 机械工程材料, 2015, 39(9): 60～63
共有人对该论文发表了看法，其中：
人认为该论文很差
人认为该论文较差
人认为该论文一般
人认为该论文较好
人认为该论文很好
参考文献
【1】倪自丰. SnO2纳米线的制备及其光致发光特性[J].机械工程材料, 2011, 35(10):95-97.
【2】DUAN X, HUANG Y, CUI Y, et al. Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices[J]. Nature, 2001, 409(6816): 66-69.
【3】PANG A, SUN X, RUAN H C, et al. Highly efficient dye-sensitized solar cells composed of TiO2@SnO2 core-shell microspheres[J]. Nano Energy,2014,5:82-90.
【4】KOROTCENKOV G, CHO B K. Bulk doping influence on the response of conductometric SnO2 gas sensors: understanding through cathodoluminescence study [J]. Sensors and Actuators B: Chemical,2014,196:80-98.
【5】AYESHAMARIAM A, RAMALINGAM S, BOUOUDINA M, et al. Preparation and characterizations of SnO2 nanopowder and spectroscopic (FT-IR, FT-Raman, UV-Visible and NMR) analysis using HF and DFT calculations[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,2014,118:1135-1143.
【6】THARSIKA T, HASEEB A S M A, AKBAR S A, et al. Catalyst free single-step fabrication of SnO2/ZnO core-shell nanostructures[J]. Ceramics International,2014,40(5):7601-7605.
【7】刘春明, 方丽梅, 祖小涛. 钴掺杂二氧化锡纳米粉的光致发光和磁学性质[J].物理学报, 2009,58(2): 936- 940.
【8】计峰, 马瑾, 马洪磊. 锑掺杂对二氧化锡薄膜结构及发光性质的影响[J].功能材料, 2009,39(9):1423-1424.
【9】王冰, 徐平. 二氧化锡纳米结构的光致发光及生长机制研究[J].电子元件与材料, 2008,27(8):52-54.
【10】PSUJA P, STREK W. Influence of concentration and sintering temperature on luminescence properties of Eu3+:SnO2 nanocrystallites [J]. Journal of Rare Earths,2012,30(7):627-631.
【11】BEALL G H, PINCKNEY L R. Nanophase glass-ceramics[J]. J Am Ceram Soc,1999, 82(1):5-16.
【12】王元生, 陈大钦.光功能透明玻璃陶瓷研究[J].激光与光电子学进展,2009(3):13-20.
【13】LI W, CHEN W Z, GUO Q H, et al. The microstructure and photoluminescence properties of Eu3+-doped SiO2-ZnO-Ga2O3 composite[J]. Phys Status Solidi A, 2013, 210(11):2369-2373.
【14】张勇, 廖莉玲, 杜莹, 等. 镧掺杂铕发光材料的合成、结构及光学性能[J].机械工程材料,2013,37(7):43-47.
【15】REISFELD R. Spectra and energy transfer of rare earths in inorganic glasses[M]. Rare Earths,[S.l]:Springer Berlin Heidelberg,1973: 53-98.
【16】YOU H, NOGAMI M. Local structure and persistent spectral hole burning of the Eu3+ ion in SnO2-SiO2 glass containing SnO2 nanocrystals[J]. Journal of Applied Physics,2004,95(5):2781-2785.
【2】DUAN X, HUANG Y, CUI Y, et al. Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices[J]. Nature, 2001, 409(6816): 66-69.
【3】PANG A, SUN X, RUAN H C, et al. Highly efficient dye-sensitized solar cells composed of TiO2@SnO2 core-shell microspheres[J]. Nano Energy,2014,5:82-90.
【4】KOROTCENKOV G, CHO B K. Bulk doping influence on the response of conductometric SnO2 gas sensors: understanding through cathodoluminescence study [J]. Sensors and Actuators B: Chemical,2014,196:80-98.
【5】AYESHAMARIAM A, RAMALINGAM S, BOUOUDINA M, et al. Preparation and characterizations of SnO2 nanopowder and spectroscopic (FT-IR, FT-Raman, UV-Visible and NMR) analysis using HF and DFT calculations[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy,2014,118:1135-1143.
【6】THARSIKA T, HASEEB A S M A, AKBAR S A, et al. Catalyst free single-step fabrication of SnO2/ZnO core-shell nanostructures[J]. Ceramics International,2014,40(5):7601-7605.
【7】刘春明, 方丽梅, 祖小涛. 钴掺杂二氧化锡纳米粉的光致发光和磁学性质[J].物理学报, 2009,58(2): 936- 940.
【8】计峰, 马瑾, 马洪磊. 锑掺杂对二氧化锡薄膜结构及发光性质的影响[J].功能材料, 2009,39(9):1423-1424.
【9】王冰, 徐平. 二氧化锡纳米结构的光致发光及生长机制研究[J].电子元件与材料, 2008,27(8):52-54.
【10】PSUJA P, STREK W. Influence of concentration and sintering temperature on luminescence properties of Eu3+:SnO2 nanocrystallites [J]. Journal of Rare Earths,2012,30(7):627-631.
【11】BEALL G H, PINCKNEY L R. Nanophase glass-ceramics[J]. J Am Ceram Soc,1999, 82(1):5-16.
【12】王元生, 陈大钦.光功能透明玻璃陶瓷研究[J].激光与光电子学进展,2009(3):13-20.
【13】LI W, CHEN W Z, GUO Q H, et al. The microstructure and photoluminescence properties of Eu3+-doped SiO2-ZnO-Ga2O3 composite[J]. Phys Status Solidi A, 2013, 210(11):2369-2373.
【14】张勇, 廖莉玲, 杜莹, 等. 镧掺杂铕发光材料的合成、结构及光学性能[J].机械工程材料,2013,37(7):43-47.
【15】REISFELD R. Spectra and energy transfer of rare earths in inorganic glasses[M]. Rare Earths,[S.l]:Springer Berlin Heidelberg,1973: 53-98.
【16】YOU H, NOGAMI M. Local structure and persistent spectral hole burning of the Eu3+ ion in SnO2-SiO2 glass containing SnO2 nanocrystals[J]. Journal of Applied Physics,2004,95(5):2781-2785.
相关信息
