Effect of Tungsten Content on Microstructure and Properties of New Type High Chromium, Manganese and Nitrogen Duplex Stainless Steels Cr29Mn12Ni2N0.6Wx
摘 要
研究了钨含量对新型高铬锰氮双相不锈钢Cr29Mn12Ni2N0.6Wx(x=1,2,3)显微组织、力学性能和耐腐蚀性能的影响。结果表明: Cr29Mn12Ni2N0.6Wx不锈钢固溶处理后具有典型的铁素体+奥氏体双相组织, 铁素体含量在45%~60%范围内; 随着钨含量的增加, 合金中σ相的析出倾向增强, 铁素体含量增加, 合金的耐腐蚀性能降低, 屈服强度和抗拉强度升高; 经1 050 ℃固溶处理30 min后, 该系列双相不锈钢中不再有σ相析出, 其屈服强度大于650 MPa, 抗拉强度大于900 MPa, 断后伸长率大于30%, 作为高强度资源节约型超级双相不锈钢具有潜在应用前景。
Abstract
Influence of tungsten content on the microstructure, mechanical properties and corrosion resistance of a new type high chromium, manganese and nitrogen duplex stainless steels with a composition of Fe-29Cr-12Mn-2Ni-0.6N-xW (x=1,2,3) was investigated. The results show that Fe-29Cr-12Mn-2Ni-0.6N-xW steels after solution treating had typical dual-phase microstructure of ferrite and austenite, and the ferrite content was in the range of 45%-60%. With the increase of tungsten content, precipitation tendency of σ phase and ferrite content in the alloy enhanced, corrosion resistance of the alloy reduced, and yield strength and ultimate tensile strength increased. When Fe-29Cr-12Mn-2Ni-0.6N-xW steels were solution treated at 1 050 ℃ for 30 min, there was no σ phase precipitation in the microstructure, yield strength, ultimate tensile strength and percentage elongation were beyond 650 MPa, 900 MPa and 30% respectively. So these type alloy has a bright future in application as high strength resource-saving super duplex stainless steels.
中图分类号 TG142.71
所属栏目 试验与研究
基金项目
收稿日期 2010/4/1
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备注丁铁锁(1983-),男, 博士研究生。
引用该论文: DING Tie-suo,WANG Tao,CUI Shi-yun,XIAO Xue-shan. Effect of Tungsten Content on Microstructure and Properties of New Type High Chromium, Manganese and Nitrogen Duplex Stainless Steels Cr29Mn12Ni2N0.6Wx[J]. Physical Testing and Chemical Analysis part A:Physical Testing, 2010, 46(10): 611~616
丁铁锁,王涛,崔世云,肖学山. 钨含量对新型高铬锰氮双相不锈钢Cr29Mn12Ni2N0.6Wx组织和性能的影响[J]. 理化检验-物理分册, 2010, 46(10): 611~616
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参考文献
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【2】CABRETRA J M,MATEO A,LIANES L,et al. Hot deformation of duplex stainless steels[J]. Journal of Materials Processing Technology,2003,143/144:321-325.
【3】WU Xin-qiang,FU Yao,HUANG Jun-bo,et al. Investigation on pitting corrosion of nickel-free and manganese-alloyed high-nitrogen stainless steels[J]. Journal of Materials Engineering and Performance,2009,18:287-298.
【4】PARK C J,KWON H S. Effects of aging at 475 ℃ on corrosion properties of tungsten-containing duplex stainless steels[J]. Corrosion Science,2002,44:2817-2830.
【5】PARK C J,AHN M K,KWON H S. Influences of Mo substitution by W on the precipitation kinetics of secondary phases and the associated localized corrosion and embrittlement in 29%Cr ferritic stainless steels[J]. Materials Science and Engineering A,2006,418:211-217.
【6】MAEHARA Y,FUJINO N,KUNITAKE T. Effects of plastic deformation and thermal history on σ phase precipitation in duplex phase stainless steels[J]. Transaction ISIJ,1983,23(3):247-255.
【7】MAEHARA Y,OHMORI Y,MURAYAMA J,et al. Effect s of alloying elements on σ phase precipitation in δ-γ duplex phase stainless steels[J]. Metal Science,1983,17(11):541-547.
【8】NILSSON J O. Super duplex stainless steels[J]. Materials Science and Technology,1992,8:685-700.
【9】OKAMOTO H. The Effect of Tungsten and Molybdenum on the Performance of Super Duplex Stainless Steels[C]//Proceedings of Application of Stainless Steel’92. Stockholm:[s.n.],1992:360.
【10】VANNEVIK H,NILSSON J O,FRODIGH J,et al. Effect of elemental partitioning on pitting resistance of high nitrogen duplex stainless steels[J]. ISIJ International,1996,36:807-812.
【11】WANG J,UGGOWITZER P J,MAGDOWSKI R. Nickel-free duplex stainless steels[J]. Scripta Materialia,1999,40:123-129.
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