Effects of Electrode Potential and Strain Rate on Stress Corrosion Cracking Behavior of Dissimilar Metal Weld 16MND5/309L/308L in High Temperature Water Environments
摘 要
采用慢应变速率试验(SSRT)方法, 研究了电极电位和应变速率对低合金钢-不锈钢异材焊接件16MND5/309L/308L在模拟压水堆一回路高温水环境中应力腐蚀破裂(SCC)的影响。结果表明: 在5×10-7 s-1应变速率条件下, 在-720~+100 mV(相对于标准氢电极SHE, 下同)的低电位区, 所有SSRT试样均在远离界面的308L焊缝金属区发生纯力学韧性断裂, 与在氮气中的试验结果类似; 当外加电位提高到+200 mV后, 试样在16MND5/309L界面发生SCC脆断, 界面附近的16MND5侧发生穿晶SCC, 309L侧发生沿晶SCC。该异材焊接件在该高温水环境中存在一个临界破裂电位, 高于此电位发生SCC, 在5×10-7s-1的应变速率下, 该临界破裂电位处于+100~+200 mV; 降低速应变率至1×10-7s-1, 临界破裂电位仍处于+100~+200 mV; 提高应变速率至1×10-6s-1后, 在+200~+300 mV电位区也没有显示出SCC。
Abstract
Effects of electrode potential and strain rate on the stress corrosion cracking (SCC) behavior of dissimilar metal weld 16MND5/309L/308L in simulated primary water environment of pressurized water reactor (PWR) were investigated by means of slow strain rate testing (SSRT). Results showed that at strain rate of 5×10-7s-1, the SSRT specimens always failed in the bulk zone of stainless steel 308L weld metal with ductile appearance when tested in the potential range from -720 mV to +100 mV (vs. SHE). When electrode potential was raised to +200 mV, SCC happened in the 16MND5/309L interface area, with transgranular SCC in low alloy steel 16MND5 zone close to the interface, intergranular SCC in the 309L weld metal close to the interface. There was a critical cracking potential above which SCC occurred, within the range from +100 mV to +200 mV for the dissimilar metal weld when tested at the strain rate of 5×10-7s-1 in simulated primary water environment of PWR. When strain rate was decreased to 1×10-7s-1, the critical cracking potential was still within the range from +100 mV to +200 mV although the test time increased significantly. When strain rate was raised to 1×10-6s-1, SCC was not observed even at the potentials +200 mV and +300 mV.
中图分类号 TG172 DOI 10.11973/fsyfh-201510005
所属栏目 试验研究
基金项目 国家重点基础研究发展计划(2011CB610506)
收稿日期 2015/5/25
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备注李光福(1962-), 教授级高工, 博士, 从事金属腐蚀断裂与可靠性相关研究,
引用该论文: LU Xu,YUAN Yi-fan,LI Run,LI Guang-fu. Effects of Electrode Potential and Strain Rate on Stress Corrosion Cracking Behavior of Dissimilar Metal Weld 16MND5/309L/308L in High Temperature Water Environments[J]. Corrosion & Protection, 2015, 36(10): 923
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参考文献
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【2】李光福, 杨武. 异材焊接件在水堆动力系统中的破裂问题与应力腐蚀破裂评价方法[J]. 核安全, 2003, 12: 37-40.
【3】JANG C. Mechanical property variation within Inconel 82/182 dissimilar metal weld between low alloy steel and 316 stainless steel[J]. International Journal of Pressure and Piping, 2008, 85: 635-646.
【4】JENSSEN A, NORRGARD K, LAGERSTROM J, et al. Assessment of cracking in dissimilar metal welds[C]//Proceedings of Tenth International Symposium on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors.Lake Tahoe: NACE 2001.
【5】李光福. 压水堆压力容器接管-主管安全端焊接件在高温水中失效案例和相关研究[J]. 核技术, 2013, 36(4): 40-44.
【6】YOUNG G A, CAPOBIANCO T E, ETIEN R A III, et al. Development of a highly weldable and corrosion resistant nickel-chorimium filler metal[C]//Proceedings of Thirteenth International Conference on Environmental Degradation of Materials in Nuclear Power Systems-Water Reactors.Canada: Canadian Nuclear Society, 2007.
【7】FRANCOIS V, JEAN-MARIE B, LAUTRNT L, et al. A review of weldability and SCC behaviors of Ni-base weld metals in laboratory PWR environment[C]//Proceedings of Thirteenth International Conference on Environmetal Degradation of Materials in Nuclear Power Systems-Water Reactors.Canada: Canadian Nuclear Society, 2007.
【8】李光福, 李冠军, 方可伟, 等. 异材焊接件A508-52M-316L在高温水环境中的应力腐蚀破裂[J]. 金属学报, 2011, 47(7): 797-803.
【9】袁义帆, 卢煦, 杨星红, 等. 16MND5.309L/308L/Z2CND18-12N异材焊接件的组织和性能[J]. 理化检验(物理分册), 2014, 50(6): 404-413.
【10】王光辉, 彭君, 袁义帆, 等. 硫酸根离子和电极电位对异材焊接件A508/52M在高温水中应力腐蚀破裂的影响[J]. 理化检验(物理分册), 2013, 49(6): 357-360.
【11】彭君, 王光辉, 李冠军, 等. 水中杂质和电极电位对国产SA-508Ⅲ低合金钢在模拟一回路高温水环境中应力腐蚀破裂的影响[J]. 腐蚀与防护, 2013, 34(1): 1-4.
【12】李冠军, 彭君, 李光福, 等. 国产SA-508Ⅲ低合金钢在模拟核电高温水服役环境中的应力腐蚀破裂及力学行为[J]. 腐蚀与防护, 2011, 32(9): 673-676.
【13】FORD P. Quantitative prediction of environmentally assisted cracking[J]. Corrosion, 1996, 52(5): 375-395.
【14】ANDREESEN P L, YOUNG L M. Crack tip micro-sampling and growth rate measurements in low-alloy steel in high temperature water[J]. Corrosion, 1995, 51(3): 223-233.
【15】PENG Q J, LI G F, SHOJI T. The crack tip solution chemistry in sensitized stainless steel in simulated boiling water reactor water studied using a micro-sampling technique[J]. Journal of Nuclear Science and Technology, 2003, 40(6): 397-404.
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