IC DETERMINATION OF ANIONS AND CATIONS IN SEA WATER WITH SUPPRESSION-CONDUCTIVITY DETECTION
摘 要
采用离子交换-抑制电导法测定海水中阴、阳离子.采用抑制电导可以降低淋洗液的背景电导,又可以增加被测离子的电导值,改善信噪比.采用的电化学自身再生抑制器,由连续电解水产生抑制淋洗液所需要的H+或者OH-,加上电场引力,能用于高容量分离柱所用的淋洗液浓度和梯度淋洗.在试验条件下,利用阴离子和阳离子分离柱,配合抑制电导检测,可以同时分离和测定海水中7种阴离子和6种阳离子.且都可以得到很好的线性和较低的检出限.
Abstract
Ion chromatography with suppression conductometric detection was applied to the determination of anions and cations in sea water.The use of suppression-conductometry showed the special features of lowering the background of the eluent,increasing the conductance of the detected ions and improving the S/N ratio.Amounts of H+ and OH- required to suppress the eluent were supplied by an electrochemical self-generating suppressor through continuous electrolysis of water.Anions and cations in sea water were separated and determined simultaneausly by the combining use of anion separation column (and/or cation separation column) with suppression-conductometric detection,and by the use of equi-grading and/or gradient elution.Data of linear regression equations and detection limits of 7 anions and 6 cations were given.
中图分类号 O657.7
所属栏目 工作简报
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收稿日期 2004/6/16
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备注郭莹莹(1979-),女,浙江新昌人,硕士,主要从事离子色谱分析工作.
引用该论文: GUO Ying-ying,YE Ming-li,SHI Qing-hong,ZHU Yan. IC DETERMINATION OF ANIONS AND CATIONS IN SEA WATER WITH SUPPRESSION-CONDUCTIVITY DETECTION[J]. Physical Testing and Chemical Analysis part B:Chemical Analysis, 2006, 42(3): 185~188
郭莹莹,叶明立,施青红,朱岩. 离子色谱-抑制电导法分别测定海水中阴离子和阳离子[J]. 理化检验-化学分册, 2006, 42(3): 185~188
被引情况:
【1】张媛媛,佘小林,贺行良,夏宁,朱志刚, "离子色谱法测定沉积物中氯",理化检验-化学分册 48, 664-666(2012)
【2】闫春辉,徐凌云,钱文虎,张勇,孙宏枚, "离子色谱法测定不同地区家庭饮用井水中的阴、阳离子",理化检验-化学分册 51, 211-214(2015)
【3】刘晓丹,杜韶娴,刘胜玉,林君铿,古正光, "离子色谱法测定珠江口半咸水中阴离子含量",理化检验-化学分册 48, 1066-1068(2012)
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参考文献
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